244926
P5622579
2023
items
1
american-chemical-society-with-titles-sentence-case-doi
0
date
asc
year
6
https://www.mces.titech.ac.jp/authors/matsuishi/wp-content/plugins/zotpress/
244926
P5622579
2022
items
1
american-chemical-society-with-titles-sentence-case-doi
0
date
asc
year
6
https://www.mces.titech.ac.jp/authors/matsuishi/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-61c889ddf14fa27457e45dcee5ed629d%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22VYIVFT3S%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Maeda%20et%20al.%22%2C%22parsedDate%22%3A%222022-01-15%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMaeda%2C%20K.%3B%20Takeiri%2C%20F.%3B%20Kobayashi%2C%20G.%3B%20Matsuishi%2C%20S.%3B%20Ogino%2C%20H.%3B%20Ida%2C%20S.%3B%20Mori%2C%20T.%3B%20Uchimoto%2C%20Y.%3B%20Tanabe%2C%20S.%3B%20Hasegawa%2C%20T.%3B%20Imanaka%2C%20N.%3B%20Kageyama%2C%20H.%20Recent%20Progress%20on%20Mixed-Anion%20Materials%20for%20Energy%20Applications.%20%3Ci%3EBCSJ%3C%5C%2Fi%3E%20%3Cb%3E2022%3C%5C%2Fb%3E%2C%20%3Ci%3E95%3C%5C%2Fi%3E%20%281%29%2C%2026%26%23x2013%3B37.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1246%5C%2Fbcsj.20210351%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1246%5C%2Fbcsj.20210351%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Recent%20Progress%20on%20Mixed-Anion%20Materials%20for%20Energy%20Applications%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazuhiko%22%2C%22lastName%22%3A%22Maeda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fumitaka%22%2C%22lastName%22%3A%22Takeiri%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Genki%22%2C%22lastName%22%3A%22Kobayashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiraku%22%2C%22lastName%22%3A%22Ogino%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shintaro%22%2C%22lastName%22%3A%22Ida%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takao%22%2C%22lastName%22%3A%22Mori%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshiharu%22%2C%22lastName%22%3A%22Uchimoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Setsuhisa%22%2C%22lastName%22%3A%22Tanabe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tetsuya%22%2C%22lastName%22%3A%22Hasegawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nobuhito%22%2C%22lastName%22%3A%22Imanaka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Kageyama%22%7D%5D%2C%22abstractNote%22%3A%22Mixed-anion%20compounds%2C%20in%20which%20multiple%20anions%20such%20as%20O2%5Cu2212%2C%20N3%5Cu2212%2C%20and%20H%5Cu2212%20are%20contained%20in%20the%20same%20compound%2C%20have%20recently%20attracted%20attention.%20Because%20mixed-anion%20compounds%20have%20a%20unique%20crystal%20structure%20with%20multiple%20anions%20coordinated%20to%20cations%2C%20materials%20with%20fundamentally%20new%20and%20innovative%20functions%20are%20expected%20to%20be%20developed%20for%20various%20chemistry%20and%20physics%20applications%2C%20including%20catalysts%2C%20batteries%2C%20and%20superconductors.%20In%20this%20Account%2C%20recent%20progress%20in%20the%20development%20of%20new%20mixed-anion%20compounds%20by%20the%20MEXT%20mixed-anion%20project%20is%20described%2C%20with%20emphasis%20on%20results%20related%20to%20the%20development%20of%20materials%20used%20as%20photocatalysts%5C%2Fphotoelectrodes%2C%20phosphors%2C%20secondary%20battery%20components%2C%20conductors%2C%20and%20thermoelectric%20materials.%22%2C%22date%22%3A%222022-01-15%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1246%5C%2Fbcsj.20210351%22%2C%22ISSN%22%3A%220009-2673%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.journal.csj.jp%5C%2Fdoi%5C%2F10.1246%5C%2Fbcsj.20210351%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-10-03T01%3A39%3A28Z%22%7D%7D%2C%7B%22key%22%3A%22HPHPRRMZ%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hayashi%20et%20al.%22%2C%22parsedDate%22%3A%222022-02-01%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHayashi%2C%20K.%3B%20Shimizu%2C%20T.%3B%20Matsuishi%2C%20S.%3B%20Hiramatsu%2C%20H.%3B%20Saitoh%2C%20A.%20Effect%20of%20Fluorine%20Doping%20on%20the%20Optical%20and%20Mechanical%20Properties%20of%20Bismuth-Containing%20Silicate%20and%20Borate%20Glasses.%20%3Ci%3EJ%20Mater%20Sci%3A%20Mater%20Electron%3C%5C%2Fi%3E%20%3Cb%3E2022%3C%5C%2Fb%3E%2C%20%3Ci%3E33%3C%5C%2Fi%3E%20%284%29%2C%202242%26%23x2013%3B2256.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs10854-021-07508-8%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs10854-021-07508-8%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Effect%20of%20fluorine%20doping%20on%20the%20optical%20and%20mechanical%20properties%20of%20bismuth-containing%20silicate%20and%20borate%20glasses%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katsuki%22%2C%22lastName%22%3A%22Hayashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tatsuki%22%2C%22lastName%22%3A%22Shimizu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hidenori%22%2C%22lastName%22%3A%22Hiramatsu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Akira%22%2C%22lastName%22%3A%22Saitoh%22%7D%5D%2C%22abstractNote%22%3A%22We%20investigate%20the%20effect%20of%20fluorine%20doping%20on%20the%20optical%20bandgap%20and%20Young%5Cu2019s%20modulus%20of%20binary%20Bi2O3%5Cu2013SiO2%20and%20Bi2O3%5Cu2013B2O3%20glasses.%20Colorless%20Bi2O3%5Cu2013BiF3%5Cu2013SiO2%20and%20Bi2O3%5Cu2013BiF3%5Cu2013B2O3%20glasses%2C%20with%20very%20small%20photoelasticity%20and%20elastic%20constants%20compared%20with%20pure%20silica%20glass%2C%20are%20potential%20alternatives%20to%20lead-containing%20oxide%20glass%20in%20the%20development%20of%20optical%20components%20using%20polarization%20control%20in%20the%20visible%20wavelength%20range.%20The%20effects%20of%20fluorine%20doping%20are%20summarized%20for%20blueshifts%20in%20the%20optical%20bandgaps%20of%20up%20to%5Cu2009~%5Cu20090.3%5Cu00a0eV%20from%5Cu2009~%5Cu20093.6%5Cu00a0eV.%20The%20applied%20photoelastic%20constants%20remained%20small%20at%5Cu2009%5Cu00b1%5Cu2009%280.02%5Cu20130.07%29%5Cu2009%5Cu00d7%5Cu200910%5Cu221212%5Cu00a0Pa%5Cu22121%2C%20and%20the%20Young%5Cu2019s%20moduli%20were%5Cu2009~%5Cu200970%20GPa%20after%20doping.%20However%2C%20no%20conclusive%20connection%20to%20the%20structural%20effect%20of%20fluorine%20doping%2C%20as%20examined%20by%20Fourier-transform%20infrared%20and%20Raman%20scattering%20spectroscopies%2C%20was%20made%2C%20although%20there%20is%20clear%20evidence%20of%20the%20compatible%20properties%20of%20wide%20optical%20bandgap%2C%20very%20small%20photoelastic%20constant%2C%20and%20large%20elastic%20constant.%22%2C%22date%22%3A%222022-02-01%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1007%5C%2Fs10854-021-07508-8%22%2C%22ISSN%22%3A%221573-482X%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs10854-021-07508-8%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-10-04T00%3A49%3A30Z%22%7D%7D%2C%7B%22key%22%3A%22YA55IE2P%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Wu%20et%20al.%22%2C%22parsedDate%22%3A%222022-08-28%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EWu%2C%20T.%3B%20Hua%2C%20H.%3B%20Ueda%2C%20J.%3B%20Tanabe%2C%20S.%3B%20Matsuishi%2C%20S.%20Pressure-Dependent%20Photoluminescence%20of%20Eu-Activated%20Aluminate%20Hydride%20Sr%3Csub%3E3%26%23x2212%3Bx%3C%5C%2Fsub%3EA%3Csub%3Ex%3C%5C%2Fsub%3EAlO%3Csub%3E4%3C%5C%2Fsub%3EH%3AEu%3Csup%3E2%2B%3C%5C%2Fsup%3E%20%28A%26%23x2009%3B%3D%26%23x2009%3BCa%2C%20Ba%3B%20x%26%23x2009%3B%3D%26%23x2009%3B0%2C%201%29%3A%20Application%20of%20Advanced%20U-Determination%20Technique%20for%20Luminescence%20Wavelength%20Prediction.%20%3Ci%3EJournal%20of%20Applied%20Physics%3C%5C%2Fi%3E%20%3Cb%3E2022%3C%5C%2Fb%3E%2C%20%3Ci%3E132%3C%5C%2Fi%3E%20%288%29%2C%20083104.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0102219%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0102219%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Pressure-dependent%20photoluminescence%20of%20Eu-activated%20aluminate%20hydride%20Sr%3Csub%3E3%5Cu2212x%3C%5C%2Fsub%3EA%3Csub%3Ex%3C%5C%2Fsub%3EAlO%3Csub%3E4%3C%5C%2Fsub%3EH%3AEu%3Csup%3E2%2B%3C%5C%2Fsup%3E%20%28A%5Cu2009%3D%5Cu2009Ca%2C%20Ba%3B%20x%5Cu2009%3D%5Cu20090%2C%201%29%3A%20Application%20of%20advanced%20U-determination%20technique%20for%20luminescence%20wavelength%20prediction%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tong%22%2C%22lastName%22%3A%22Wu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hansen%22%2C%22lastName%22%3A%22Hua%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jumpei%22%2C%22lastName%22%3A%22Ueda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Setsuhisa%22%2C%22lastName%22%3A%22Tanabe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%5D%2C%22abstractNote%22%3A%22The%20increasing%20attention%20on%20the%20unique%20properties%20of%20oxyhydride%20materials%20motivates%20the%20exploration%20of%20their%20potential%20applications%20in%20optical%20fields%2C%20and%20the%20theoretical%20studies%20of%20their%20luminescence%20properties%20are%20still%20under%20progress.%20Here%2C%20we%20report%20the%20experimental%20and%20theoretical%20high-pressure%20photoluminescence%20%28PL%29%20studies%20on%20Eu-activated%20Sr3%5Cu2013xAxAlO4H%20%28A%5Cu2009%3D%5Cu2009Ca%20and%20Ba%3B%20x%5Cu2009%3D%5Cu20090%20and%201%29%20oxyhydride%20materials.%20Under%20hydrostatic%20pressures%20from%20ambient%20pressure%20up%20to%206.41%5Cu2009GPa%2C%20the%20luminescence%20band%20in%20all%20the%20samples%20exhibits%20redshift%20with%20increasing%20pressure%20and%20the%20highest%20energy-shift%20rate%20of%20%5Cu2212101.85%5Cu2009cm%5Cu22121%5C%2FGPa%20was%20observed%20in%20Sr3AlO4H%3AEu2%2B.%20The%20asymmetric%20bands%20were%20deconvoluted%20into%20two%20peaks%20corresponding%20to%20the%20two%20Eu%20sites%20with%20different%20coordination%20environments.%20Although%20the%20shift%20rates%20of%20Eu2%2B%20centers%20in%20Sr3AlO4H%20are%20not%20remarkable%20as%20expected%20for%20the%20large%20compressibility%20of%20hydride%20ion%20ligands%2C%20their%20pressure-dependences%20in%20opposite%20directions%20were%20successfully%20reproduced%20by%20constrained%20density%20functional%20theory%20calculations%20using%20the%20advanced%20on-site%20Coulomb%20interaction%20parameter%20%28U%29%20determination%20method.%20The%20lower%20shift%20rate%20as%20seen%20in%20conventional%20oxide%20phosphors%20indicates%20that%20Eu-4f%20and%205d%20level%20positions%20are%20determined%20by%20the%20interaction%20with%20less%20compressive%20oxide%20ion%20ligands.%20Therefore%2C%20the%20high%20shift%20rate%20required%20for%20pressure%20sensing%20applications%20is%20expected%20in%20more%20hydrogen-rich%20oxyhydrides%20and%20related%20hydride%20compounds.%22%2C%22date%22%3A%222022-08-28%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F5.0102219%22%2C%22ISSN%22%3A%220021-8979%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Faip.scitation.org%5C%2Fdoi%5C%2F10.1063%5C%2F5.0102219%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22ZITQFSDI%22%5D%2C%22dateModified%22%3A%222023-08-25T02%3A45%3A30Z%22%7D%7D%2C%7B%22key%22%3A%2235V74N3I%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Matsuishi%20et%20al.%22%2C%22parsedDate%22%3A%222022-11-01%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMatsuishi%2C%20S.%3B%20Iwasaki%2C%20D.%3B%20Hosono%2C%20H.%20Synthesis%20of%20Perovskite-Type%20LaWN3%20by%20High-Pressure%20Solid-State%20Metathesis%20Reaction.%20%3Ci%3EJournal%20of%20Solid%20State%20Chemistry%3C%5C%2Fi%3E%20%3Cb%3E2022%3C%5C%2Fb%3E%2C%20%3Ci%3E315%3C%5C%2Fi%3E%2C%20123508.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jssc.2022.123508%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jssc.2022.123508%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Synthesis%20of%20perovskite-type%20LaWN3%20by%20high-pressure%20solid-state%20metathesis%20reaction%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daiki%22%2C%22lastName%22%3A%22Iwasaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Perovskite-type%20LaWN3%20was%20synthesized%20by%20the%20solid-state%20metathesis%20reaction%20of%20LaCl3%2C%20WCl6%2C%20and%20Li3N%20under%20a%20pressure%20of%205%5Cu00a0%5Cu200bGPa%20and%20a%20temperature%20of%201573%5Cu00a0%5Cu200bK.%20The%20amount%20of%20oxygen%20in%20the%20synthesized%20sample%20is%20smaller%20than%20that%20in%20the%20sample%20prepared%20by%20the%20conventional%20ammonolysis%20of%20La2W2O9.%20The%20x-ray%20diffraction%20pattern%20of%20resulting%20phase%20can%20be%20fitted%20by%20either%20the%20meta-stable%20cubic%20structure%20with%20a%20Pm3%5Cu00afm%20space%20group%20or%20the%20ground-state%20rhombohedral%20structure%20with%20an%20R3c%20space%20group.%20The%20indirect%20bandgap%20of%20%5Cu223c1.2%5Cu00a0%5Cu200beV%20and%20the%20direct%20band%20gap%20of%20%5Cu223c2.2%5Cu00a0%5Cu200beV%20are%20consistent%20with%20those%20of%20the%20rhombohedral%20structure%20calculated%20by%20the%20density%20functional%20theory%20calculation%20with%20the%20HSE06%20hybrid%20functional.%22%2C%22date%22%3A%222022-11-01%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jssc.2022.123508%22%2C%22ISSN%22%3A%220022-4596%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS0022459622006338%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-09-07T01%3A38%3A19Z%22%7D%7D%2C%7B%22key%22%3A%22BUUWPE6B%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Iimura%20et%20al.%22%2C%22parsedDate%22%3A%222022-11-01%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EIimura%2C%20S.%3B%20Sasaki%2C%20T.%3B%20Hanzawa%2C%20K.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20High%20Pressure%20Synthesis%2C%20Physical%20Properties%20and%20Electronic%20Structure%20of%20Monovalent%20Iron%20Compound%20LaFePH.%20%3Ci%3EJournal%20of%20Solid%20State%20Chemistry%3C%5C%2Fi%3E%20%3Cb%3E2022%3C%5C%2Fb%3E%2C%20%3Ci%3E315%3C%5C%2Fi%3E%2C%20123546.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jssc.2022.123546%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jssc.2022.123546%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22High%20pressure%20synthesis%2C%20physical%20properties%20and%20electronic%20structure%20of%20monovalent%20iron%20compound%20LaFePH%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takashi%22%2C%22lastName%22%3A%22Sasaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kota%22%2C%22lastName%22%3A%22Hanzawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Using%20high%20pressure%20synthesis%20under%20high%20hydrogen%20partial%20pressure%20condition%2C%20we%20synthesized%20a%20new%20analogue%20of%20iron-based%20superconductors%20LaFePH%20with%20a%20formal%20iron%20charge%20of%201%2B%20and%20new%20oxyhydrides%20LaFePO1%5Cu2212xHx%20with%20x%20ranging%200%5Cu00a0%5Cu200b%3C%5Cu00a0%5Cu200bx%5Cu00a0%5Cu200b%3C%5Cu00a0%5Cu200b1.%20In%20contrast%20to%20the%20analogous%20arsenides%20LaFeAsO1%5Cu2212xHx%20and%20isoelectronic%20Co-oxyphosphide%20LaCoPO%2C%20neither%20superconducting%2C%20magnetic%20nor%20structural%20transitions%20were%20observed%20in%20LaFePO1%5Cu2212xHx%20except%20the%20already%20known%20superconducting%20transition%20in%20x%5Cu00a0%5Cu200b%3D%5Cu00a0%5Cu200b0.%20DFT%20calculations%20reveal%20that%20the%20hydride%20ion%20substitution%20for%20the%20oxygen%20site%20dopes%20electrons%20into%20the%20Fe-3d%20and%20raises%20the%20Fermi%20level%2C%20leading%20to%20a%20partial%20electron%20transfer%20from%20the%20Fe-3d%20to%20La-5d.%20We%20attribute%20the%20absence%20of%20magnetism%20in%20LaFePH%20to%20the%20reduced%20onsite%20Coulomb%20interaction%20in%20the%20Fe-3d%20orbitals%20due%20to%20the%20expansion%20of%20the%203d%20orbital%20and%20the%20shielding%20effect%20of%20La-5d%20electrons.%22%2C%22date%22%3A%222022-11-01%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jssc.2022.123546%22%2C%22ISSN%22%3A%220022-4596%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS0022459622006715%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-10-04T10%3A43%3A54Z%22%7D%7D%5D%7D
(1)
Maeda, K.; Takeiri, F.; Kobayashi, G.; Matsuishi, S.; Ogino, H.; Ida, S.; Mori, T.; Uchimoto, Y.; Tanabe, S.; Hasegawa, T.; Imanaka, N.; Kageyama, H. Recent Progress on Mixed-Anion Materials for Energy Applications. BCSJ 2022, 95 (1), 26–37. https://doi.org/10.1246/bcsj.20210351.
(1)
Hayashi, K.; Shimizu, T.; Matsuishi, S.; Hiramatsu, H.; Saitoh, A. Effect of Fluorine Doping on the Optical and Mechanical Properties of Bismuth-Containing Silicate and Borate Glasses. J Mater Sci: Mater Electron 2022, 33 (4), 2242–2256. https://doi.org/10.1007/s10854-021-07508-8.
(1)
Wu, T.; Hua, H.; Ueda, J.; Tanabe, S.; Matsuishi, S. Pressure-Dependent Photoluminescence of Eu-Activated Aluminate Hydride Sr3−xAxAlO4H:Eu2+ (A = Ca, Ba; x = 0, 1): Application of Advanced U-Determination Technique for Luminescence Wavelength Prediction. Journal of Applied Physics 2022, 132 (8), 083104. https://doi.org/10.1063/5.0102219.
(1)
Matsuishi, S.; Iwasaki, D.; Hosono, H. Synthesis of Perovskite-Type LaWN3 by High-Pressure Solid-State Metathesis Reaction. Journal of Solid State Chemistry 2022, 315, 123508. https://doi.org/10.1016/j.jssc.2022.123508.
(1)
Iimura, S.; Sasaki, T.; Hanzawa, K.; Matsuishi, S.; Hosono, H. High Pressure Synthesis, Physical Properties and Electronic Structure of Monovalent Iron Compound LaFePH. Journal of Solid State Chemistry 2022, 315, 123546. https://doi.org/10.1016/j.jssc.2022.123546.
244926
P5622579
2021
items
1
american-chemical-society-with-titles-sentence-case-doi
0
date
asc
year
6
https://www.mces.titech.ac.jp/authors/matsuishi/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-84dc727263e28c43aafd694497cea9b4%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22SPNDHES8%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Nakao%20et%20al.%22%2C%22parsedDate%22%3A%222021-02-04%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ENakao%2C%20T.%3B%20Ogasawara%2C%20K.%3B%20Kitano%2C%20M.%3B%20Matsuishi%2C%20S.%3B%20Sushko%2C%20P.%20V.%3B%20Hosono%2C%20H.%20Ship-in-a-Bottle%20Synthesis%20of%20High%20Concentration%20of%20N2%20Molecules%20in%20a%20Cage-Structured%20Electride.%20%3Ci%3EJ.%20Phys.%20Chem.%20Lett.%3C%5C%2Fi%3E%20%3Cb%3E2021%3C%5C%2Fb%3E%2C%20%3Ci%3E12%3C%5C%2Fi%3E%20%284%29%2C%201295%26%23x2013%3B1299.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpclett.0c03800%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpclett.0c03800%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ship-in-a-Bottle%20Synthesis%20of%20High%20Concentration%20of%20N2%20Molecules%20in%20a%20Cage-Structured%20Electride%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takuya%22%2C%22lastName%22%3A%22Nakao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kiya%22%2C%22lastName%22%3A%22Ogasawara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masaaki%22%2C%22lastName%22%3A%22Kitano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Peter%20V.%22%2C%22lastName%22%3A%22Sushko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20the%20formation%20of%20neutral%20nitrogen%20molecules%20in%20the%20cages%20of%20%5BCa12Al14O32%5D2%2B%20%28C12A7%29%20framework%20compensated%20by%20extra-framework%20anions.%20NH3%20treatment%20of%20C12A7%20electride%20%28C12A7%3Ae%5Cu2013%29%20at%20800%20%5Cu00b0C%20leads%20to%20the%20formation%20of%20N2%20and%20NH2%5Cu2013%20species%20in%20the%20C12A7%20cages.%20N2%20and%20NHx%20species%20in%20the%20cages%20are%20identified%20using%20the%20Raman%20spectroscopy%20of%2014NH3%20and%2015NH3-treated%20C12A7%3Ae%5Cu2013.%20The%20concentration%20of%20H%20and%20N%20in%20the%20C12A7%20cages%20after%20NH3%20treatment%20is%20%5Cu223c1021%20cm%5Cu20133.%20We%20propose%20a%20two-step%20mechanism%2C%20supported%20by%20density%20functional%20theory%20%28DFT%29%20modeling%2C%20of%20N2%20incorporation%20into%20the%20C12A7%20cages%2C%20i.e.%2C%20incorporation%20of%20NH2%5Cu2013%20formed%20from%20decomposition%20of%20NH3%20at%20C12A7%3Ae%5Cu2013%20surface%20followed%20by%20the%20NH2%5Cu2013%20species%20reacting%20to%20form%20N2%20molecules.%20Encapsulation%20of%20neutral%20molecules%2C%20as%20opposed%20to%20negatively%20charged%20species%20reported%20in%20C12A7%20previously%2C%20offers%20new%20opportunities%20for%20trapping%20and%20storing%20gaseous%20substances%20in%20nanoporous%20materials.%22%2C%22date%22%3A%222021-02-04%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.jpclett.0c03800%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpclett.0c03800%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-09-27T03%3A35%3A32Z%22%7D%7D%2C%7B%22key%22%3A%22KUL3X3HL%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22%5Cu677e%5Cu77f3%5Cu8061%20and%20%5Cu5c71%5Cu672c%5Cu9686%5Cu6587%22%2C%22parsedDate%22%3A%222021-03%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3E%26%23x677E%3B%26%23x77F3%3B%26%23x8061%3B%3B%20%26%23x5C71%3B%26%23x672C%3B%26%23x9686%3B%26%23x6587%3B.%20%26%23x8907%3B%26%23x5408%3B%26%23x30A2%3B%26%23x30CB%3B%26%23x30AA%3B%26%23x30F3%3B%26%23x5316%3B%26%23x5408%3B%26%23x7269%3B%26%23x306E%3B%26%23x96FB%3B%26%23x5B50%3B%26%23x7269%3B%26%23x6027%3B.%20In%20%26%23x8907%3B%26%23x5408%3B%26%23x30A2%3B%26%23x30CB%3B%26%23x30AA%3B%26%23x30F3%3B%26%23x5316%3B%26%23x5408%3B%26%23x7269%3B%26%23x306E%3B%26%23x79D1%3B%26%23x5B66%3B%3B%20%26%23x4E38%3B%26%23x5584%3B%26%23x51FA%3B%26%23x7248%3B%2C%202021%3B%20pp%20177%26%23x2013%3B200.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22bookSection%22%2C%22title%22%3A%22%5Cu8907%5Cu5408%5Cu30a2%5Cu30cb%5Cu30aa%5Cu30f3%5Cu5316%5Cu5408%5Cu7269%5Cu306e%5Cu96fb%5Cu5b50%5Cu7269%5Cu6027%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22name%22%3A%22%5Cu677e%5Cu77f3%5Cu8061%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22name%22%3A%22%5Cu5c71%5Cu672c%5Cu9686%5Cu6587%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22bookTitle%22%3A%22%5Cu8907%5Cu5408%5Cu30a2%5Cu30cb%5Cu30aa%5Cu30f3%5Cu5316%5Cu5408%5Cu7269%5Cu306e%5Cu79d1%5Cu5b66%22%2C%22date%22%3A%222021%5C%2F3%22%2C%22language%22%3A%22%22%2C%22ISBN%22%3A%22978-4-621-30610-9%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.maruzen-publishing.co.jp%5C%2Fitem%5C%2F%3Fbook_no%3D304140%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-10-04T02%3A43%3A56Z%22%7D%7D%2C%7B%22key%22%3A%22ZL4Q3YVB%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Yamamoto%20et%20al.%22%2C%22parsedDate%22%3A%222021-05%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EYamamoto%2C%20Y.%3B%20Yamaoka%2C%20H.%3B%20Uozumi%2C%20T.%3B%20Hariki%2C%20A.%3B%20Onari%2C%20S.%3B%20Yamaura%2C%20J.%3B%20Ishii%2C%20K.%3B%20Kawai%2C%20T.%3B%20Yoshida%2C%20M.%3B%20Taguchi%2C%20M.%3B%20Kobayashi%2C%20K.%3B%20Lin%2C%20J.-F.%3B%20Hiraoka%2C%20N.%3B%20Ishii%2C%20H.%3B%20Tsuei%2C%20K.-D.%3B%20Okanishi%2C%20H.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Mizuki%2C%20J.%20Electronic%20and%20Crystal%20Structures%20of%20%3Ci%3ELn%3C%5C%2Fi%3EFeAsO%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%20%28Ln%20%3D%20La%2C%20Sm%29%20Studied%20by%20x-Ray%20Absorption%20Spectroscopy%2C%20x-Ray%20Emission%20Spectroscopy%2C%20and%20x-Ray%20Diffraction%20%28Part%20I%3A%20Carrier-Doping%20Dependence%29.%20%3Ci%3EJ.%20Phys.%3A%20Condens.%20Matter%3C%5C%2Fi%3E%20%3Cb%3E2021%3C%5C%2Fb%3E%2C%20%3Ci%3E33%3C%5C%2Fi%3E%20%2825%29%2C%20255602.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-648x%5C%2Fabf9b9%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-648x%5C%2Fabf9b9%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Electronic%20and%20crystal%20structures%20of%20%3Ci%3ELn%3C%5C%2Fi%3EFeAsO%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%20%28Ln%20%3D%20La%2C%20Sm%29%20studied%20by%20x-ray%20absorption%20spectroscopy%2C%20x-ray%20emission%20spectroscopy%2C%20and%20x-ray%20diffraction%20%28part%20I%3A%20carrier-doping%20dependence%29%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshiya%22%2C%22lastName%22%3A%22Yamamoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hitoshi%22%2C%22lastName%22%3A%22Yamaoka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takayuki%22%2C%22lastName%22%3A%22Uozumi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Atsushi%22%2C%22lastName%22%3A%22Hariki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Seiichiro%22%2C%22lastName%22%3A%22Onari%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jun-ichi%22%2C%22lastName%22%3A%22Yamaura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kenji%22%2C%22lastName%22%3A%22Ishii%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takuma%22%2C%22lastName%22%3A%22Kawai%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masahiro%22%2C%22lastName%22%3A%22Yoshida%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Munetaka%22%2C%22lastName%22%3A%22Taguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kensuke%22%2C%22lastName%22%3A%22Kobayashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jung-Fu%22%2C%22lastName%22%3A%22Lin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nozomu%22%2C%22lastName%22%3A%22Hiraoka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hirofumi%22%2C%22lastName%22%3A%22Ishii%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ku-Ding%22%2C%22lastName%22%3A%22Tsuei%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Okanishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jun%27ichiro%22%2C%22lastName%22%3A%22Mizuki%22%7D%5D%2C%22abstractNote%22%3A%22A%20carrier%20doping%20by%20a%20hydrogen%20substitution%20in%20LaFeAsO1%5Cu2212x%20H%20x%20is%20known%20to%20cause%20two%20superconducting%20%28SC%29%20domes%20with%20the%20magnetic%20order%20at%20both%20end%20sides%20of%20the%20doping.%20In%20contrast%2C%20SmFeAsO1%5Cu2212x%20H%20x%20has%20a%20similar%20phase%20diagram%20but%20shows%20single%20SC%20dome.%20Here%2C%20we%20investigated%20the%20electronic%20and%20crystal%20structures%20for%20iron%20oxynitride%20LnFeAsO1%5Cu2212x%20H%20x%20%28Ln%20%3D%20La%2C%20Sm%29%20with%20the%20range%20of%20x%20%3D%200%5Cu20130.5%20by%20using%20x-ray%20absorption%20spectroscopy%2C%20x-ray%20emission%20spectroscopy%2C%20and%20x-ray%20diffraction.%20For%20both%20compounds%2C%20we%20observed%20that%20the%20pre-edge%20peaks%20of%20x-ray%20absorption%20spectra%20near%20the%20Fe-K%20edge%20were%20reduced%20in%20intensity%20on%20doping.%20The%20character%20arises%20from%20the%20weaker%20As%5Cu2013Fe%20hybridization%20with%20the%20longer%20As%5Cu2013Fe%20distance%20in%20the%20higher%20doped%20region.%20We%20can%20reproduce%20the%20spectra%20near%20the%20Fe-K%20edge%20according%20to%20the%20Anderson%20impurity%20model%20with%20realistic%20valence%20structures%20using%20the%20local-density%20approximation%20%28LDA%29%20plus%20dynamical%20mean-field%20theory%20%28DMFT%29.%20For%20Ln%20%3D%20Sm%2C%20the%20integrated-absolute%20difference%20%28IAD%29%20analysis%20from%20x-ray%20Fe-K%5Cu03b2%20emission%20spectra%20increases%20significantly.%20This%20is%20attributed%20to%20the%20enhancement%20of%20magnetic%20moment%20of%20Fe%203d%20electrons%20stemming%20from%20the%20localized%20picture%20in%20the%20higher%20doped%20region.%20A%20theoretical%20simulation%20implementing%20the%20self-consistent%20vertex-correction%20method%20reveals%20that%20the%20single%20dome%20superconducting%20phase%20for%20Ln%20%3D%20Sm%20arises%20from%20a%20better%20nesting%20condition%20in%20comparison%20with%20Ln%20%3D%20La.%22%2C%22date%22%3A%222021-05%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1088%5C%2F1361-648X%5C%2Fabf9b9%22%2C%22ISSN%22%3A%220953-8984%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-648x%5C%2Fabf9b9%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222023-09-11T03%3A53%3A39Z%22%7D%7D%2C%7B%22key%22%3A%22W2PK74W5%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Saitoh%20et%20al.%22%2C%22parsedDate%22%3A%222021-05-15%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ESaitoh%2C%20A.%3B%20Hayashi%2C%20K.%3B%20Hanzawa%2C%20K.%3B%20Ueda%2C%20S.%3B%20Kawachi%2C%20S.%3B%20Yamaura%2C%20J.%3B%20Ide%2C%20K.%3B%20Kim%2C%20J.%3B%20Tricot%2C%20G.%3B%20Matsuishi%2C%20S.%3B%20Mitsui%2C%20K.%3B%20Shimizu%2C%20T.%3B%20Mori%2C%20M.%3B%20Hosono%2C%20H.%3B%20Hiramatsu%2C%20H.%20Origins%20of%20the%20Coloration%20from%20Structure%20and%20Valence%20State%20of%20Bismuth%20Oxide%20Glasses.%20%3Ci%3EJournal%20of%20Non-Crystalline%20Solids%3C%5C%2Fi%3E%20%3Cb%3E2021%3C%5C%2Fb%3E%2C%20%3Ci%3E560%3C%5C%2Fi%3E%2C%20120720.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jnoncrysol.2021.120720%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jnoncrysol.2021.120720%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Origins%20of%20the%20coloration%20from%20structure%20and%20valence%20state%20of%20bismuth%20oxide%20glasses%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Akira%22%2C%22lastName%22%3A%22Saitoh%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katsuki%22%2C%22lastName%22%3A%22Hayashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kota%22%2C%22lastName%22%3A%22Hanzawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shigenori%22%2C%22lastName%22%3A%22Ueda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shiro%22%2C%22lastName%22%3A%22Kawachi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jun-ichi%22%2C%22lastName%22%3A%22Yamaura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Keisuke%22%2C%22lastName%22%3A%22Ide%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Junghwan%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gr%5Cu00e9gory%22%2C%22lastName%22%3A%22Tricot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazuki%22%2C%22lastName%22%3A%22Mitsui%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tatsuki%22%2C%22lastName%22%3A%22Shimizu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masami%22%2C%22lastName%22%3A%22Mori%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hidenori%22%2C%22lastName%22%3A%22Hiramatsu%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20the%20origins%20of%20the%20coloration%20of%20Bi2O3%5Cu2013SiO2%2C%20Bi2O3%5Cu2013B2O3%2C%20and%20Bi2O3%5Cu2013P2O5%20glasses.%20The%20glasses%20were%20quantitatively%20analyzed%20to%20reveal%20the%20Bi%20valence%20state%20and%20network%20connectivity%20of%20silicate%2C%20borate%2C%20and%20phosphate.%20The%20electronic%20structure%20was%20correlated%20with%20Bi%20valence%20states%2C%20giving%20two%20types%20of%20signals%3A%20those%20related%20to%20optical%20bandgaps%20with%20Bi3%2B%20s%5Cu2013p%20intra-transition%20states%20at%203.6%5Cu20134.7%5Cu00a0eV%20and%20visible%20absorption%20bands%20at%202.5%5Cu20132.7%5Cu00a0eV%20originating%20from%20the%20charge%20transfer%20between%20Bi3%2B%20and%20Bi5%2B%20and%5C%2For%20plasmonic%20Bi0%20clusters%20in%20the%20colored%20glasses.%20These%20Bi%20oxide%20glasses%20with%20tvisible%20transparent%20and%20high%20refractive%20index%20are%20attractive%20to%20replace%20toxic%20Pb-containing%20optical%20glasses.%22%2C%22date%22%3A%22May%2015%2C%202021%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jnoncrysol.2021.120720%22%2C%22ISSN%22%3A%220022-3093%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS002230932100079X%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-07-15T01%3A03%3A21Z%22%7D%7D%5D%7D
(1)
Nakao, T.; Ogasawara, K.; Kitano, M.; Matsuishi, S.; Sushko, P. V.; Hosono, H. Ship-in-a-Bottle Synthesis of High Concentration of N2 Molecules in a Cage-Structured Electride. J. Phys. Chem. Lett. 2021, 12 (4), 1295–1299. https://doi.org/10.1021/acs.jpclett.0c03800.
(1)
松石聡; 山本隆文. 複合アニオン化合物の電子物性. In 複合アニオン化合物の科学; 丸善出版, 2021; pp 177–200.
(1)
Yamamoto, Y.; Yamaoka, H.; Uozumi, T.; Hariki, A.; Onari, S.; Yamaura, J.; Ishii, K.; Kawai, T.; Yoshida, M.; Taguchi, M.; Kobayashi, K.; Lin, J.-F.; Hiraoka, N.; Ishii, H.; Tsuei, K.-D.; Okanishi, H.; Iimura, S.; Matsuishi, S.; Hosono, H.; Mizuki, J. Electronic and Crystal Structures of LnFeAsO1-xHx (Ln = La, Sm) Studied by x-Ray Absorption Spectroscopy, x-Ray Emission Spectroscopy, and x-Ray Diffraction (Part I: Carrier-Doping Dependence). J. Phys.: Condens. Matter 2021, 33 (25), 255602. https://doi.org/10.1088/1361-648x/abf9b9.
(1)
Saitoh, A.; Hayashi, K.; Hanzawa, K.; Ueda, S.; Kawachi, S.; Yamaura, J.; Ide, K.; Kim, J.; Tricot, G.; Matsuishi, S.; Mitsui, K.; Shimizu, T.; Mori, M.; Hosono, H.; Hiramatsu, H. Origins of the Coloration from Structure and Valence State of Bismuth Oxide Glasses. Journal of Non-Crystalline Solids 2021, 560, 120720. https://doi.org/10.1016/j.jnoncrysol.2021.120720.
244926
P5622579
2020
items
1
american-chemical-society-with-titles-sentence-case-doi
0
date
asc
year
6
https://www.mces.titech.ac.jp/authors/matsuishi/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-305a0520334e219de5abc34ca3520cd5%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22ILSI4DU4%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Liu%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ELiu%2C%20Z.%3B%20Liu%2C%20T.%3B%20Savory%2C%20C.%20N.%3B%20Jurado%2C%20J.%20P.%3B%20Reparaz%2C%20J.%20S.%3B%20Li%2C%20J.%3B%20Pan%2C%20L.%3B%20Faul%2C%20C.%20F.%20J.%3B%20Parkin%2C%20I.%20P.%3B%20Sankar%2C%20G.%3B%20Matsuishi%2C%20S.%3B%20Campoy%26%23x2010%3BQuiles%2C%20M.%3B%20Scanlon%2C%20D.%20O.%3B%20Zwijnenburg%2C%20M.%20A.%3B%20Fenwick%2C%20O.%3B%20Schroeder%2C%20B.%20C.%20Controlling%20the%20Thermoelectric%20Properties%20of%20Organometallic%20Coordination%20Polymers%20via%20Ligand%20Design.%20%3Ci%3EAdvanced%20Functional%20Materials%3C%5C%2Fi%3E%20%3Cb%3E2020%3C%5C%2Fb%3E%2C%20%3Ci%3E30%3C%5C%2Fi%3E%20%2832%29%2C%202003106.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadfm.202003106%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadfm.202003106%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Controlling%20the%20Thermoelectric%20Properties%20of%20Organometallic%20Coordination%20Polymers%20via%20Ligand%20Design%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zilu%22%2C%22lastName%22%3A%22Liu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tianjun%22%2C%22lastName%22%3A%22Liu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christopher%20N.%22%2C%22lastName%22%3A%22Savory%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jos%5Cu00e9%20P.%22%2C%22lastName%22%3A%22Jurado%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Juan%20Sebasti%5Cu00e1n%22%2C%22lastName%22%3A%22Reparaz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jianwei%22%2C%22lastName%22%3A%22Li%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Long%22%2C%22lastName%22%3A%22Pan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Charl%20F.%20J.%22%2C%22lastName%22%3A%22Faul%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ivan%20P.%22%2C%22lastName%22%3A%22Parkin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gopinathan%22%2C%22lastName%22%3A%22Sankar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mariano%22%2C%22lastName%22%3A%22Campoy%5Cu2010Quiles%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%20O.%22%2C%22lastName%22%3A%22Scanlon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Martijn%20A.%22%2C%22lastName%22%3A%22Zwijnenburg%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Oliver%22%2C%22lastName%22%3A%22Fenwick%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bob%20C.%22%2C%22lastName%22%3A%22Schroeder%22%7D%5D%2C%22abstractNote%22%3A%22Organometallic%20coordination%20polymers%20%28OMCPs%29%20are%20a%20promising%20class%20of%20thermoelectric%20materials%20with%20high%20electrical%20conductivities%20and%20thermal%20resistivities.%20The%20design%20criteria%20for%20these%20materials%2C%20however%2C%20remain%20elusive%20and%20so%20far%20material%20modifications%20have%20been%20focused%20primarily%20on%20the%20nature%20of%20the%20metal%20cation%20to%20tune%20the%20thermoelectric%20properties.%20Herein%2C%20an%20alternative%20approach%20is%20described%20by%20synthesizing%20new%20organic%20ligands%20for%20OMCPs%2C%20allowing%20modulation%20of%20the%20thermoelectric%20properties%20of%20the%20novel%20OMCP%20materials%20over%20several%20orders%20of%20magnitude%2C%20as%20well%20as%20controlling%20the%20polarity%20of%20the%20Seebeck%20coefficient.%20Extensive%20material%20purification%20combined%20with%20spectroscopy%20experiments%20and%20calculations%20furthermore%20reveal%20the%20charge-neutral%20character%20of%20the%20polymer%20backbones.%20In%20the%20absence%20of%20counter-cations%2C%20the%20OMCP%20backbones%20are%20composed%20of%20air-stable%2C%20ligand-centered%20radicals.%20The%20findings%20open%20up%20new%20synthetic%20possibilities%20for%20OMCPs%20by%20removing%20structural%20constraints%20and%20putting%20significant%20emphasis%20on%20the%20molecular%20structure%20of%20the%20organic%20ligands%20in%20OMCP%20materials%20to%20tune%20their%20thermoelectric%20properties.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadfm.202003106%22%2C%22ISSN%22%3A%221616-3028%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fonlinelibrary.wiley.com%5C%2Fdoi%5C%2Fabs%5C%2F10.1002%5C%2Fadfm.202003106%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-09-24T06%3A01%3A02Z%22%7D%7D%2C%7B%22key%22%3A%224CS5U5XB%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Wu%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EWu%2C%20J.%3B%20Liu%2C%20F.%3B%20Liu%2C%20C.%3B%20Wang%2C%20Y.%3B%20Li%2C%20C.%3B%20Lu%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Toward%202D%20Magnets%20in%20the%20%28MnBi2Te4%29%28Bi2Te3%29n%20Bulk%20Crystal.%20%3Ci%3EAdvanced%20Materials%3C%5C%2Fi%3E%20%3Cb%3E2020%3C%5C%2Fb%3E%2C%20%3Ci%3E32%3C%5C%2Fi%3E%20%2823%29%2C%202001815.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadma.202001815%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadma.202001815%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Toward%202D%20Magnets%20in%20the%20%28MnBi2Te4%29%28Bi2Te3%29n%20Bulk%20Crystal%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jiazhen%22%2C%22lastName%22%3A%22Wu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fucai%22%2C%22lastName%22%3A%22Liu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Can%22%2C%22lastName%22%3A%22Liu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yong%22%2C%22lastName%22%3A%22Wang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Changcun%22%2C%22lastName%22%3A%22Li%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yangfan%22%2C%22lastName%22%3A%22Lu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%222D%20magnets%20and%20their%20engineered%20magnetic%20heterostructures%20are%20intriguing%20materials%20for%20both%20fundamental%20physics%20and%20application%20prospects.%20On%20the%20basis%20of%20the%20recently%20discovered%20intrinsic%20magnetic%20topological%20insulators%20%28MnBi2Te4%29%28Bi2Te3%29n%2C%20here%2C%20a%20new%20type%20of%20magnet%2C%20in%20which%20the%20magnetic%20layers%20are%20separated%20by%20a%20large%20number%20of%20non-magnetic%20layers%20and%20become%20magnetically%20independent%2C%20is%20proposed.%20This%20magnet%20is%20named%20as%20a%20single-layer%20magnet%2C%20regarding%20the%20vanishing%20interlayer%20exchange%20coupling.%20Theoretical%20calculations%20and%20magnetization%20measurements%20indicate%20that%2C%20the%20decoupling%20of%20the%20magnetic%20layers%20starts%20to%20emerge%20from%20n%20%3D%202%20and%203%2C%20as%20revealed%20by%20a%20unique%20slow-relaxation%20behavior%20below%20a%20ferromagnetic-type%20transition%20at%20Tc%20%3D%2012%5Cu201314%20K.%20Magnetization%20data%20analysis%20shows%20that%20the%20proposed%20new%20magnetic%20states%20have%20a%20strong%20uniaxial%20anisotropy%20along%20the%20c-axis%2C%20forming%20an%20Ising-type%20magnetic%20structure%2C%20where%20Tc%20is%20the%20ordering%20temperature%20for%20each%20magnetic%20layer.%20The%20characteristic%20slow%20relaxation%2C%20which%20exists%20only%20along%20the%20c-axis%20but%20is%20absent%20along%20the%20ab%20plane%2C%20can%20be%20ascribed%20to%20interlayer%20coherent%20spin%20rotation%20and%5C%2For%20intralayer%20domain%20wall%20movement.%20The%20present%20results%20will%20stimulate%20further%20theoretical%20and%20experimental%20investigations%20for%20the%20prototypical%20magnetic%20structures%2C%20and%20their%20combination%20with%20the%20topological%20surface%20states%20may%20lead%20to%20exotic%20physical%20properties.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadma.202001815%22%2C%22ISSN%22%3A%221521-4095%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fonlinelibrary.wiley.com%5C%2Fdoi%5C%2Fabs%5C%2F10.1002%5C%2Fadma.202001815%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222024-02-15T06%3A46%3A27Z%22%7D%7D%2C%7B%22key%22%3A%22DSJT4R5V%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hiraishi%20et%20al.%22%2C%22parsedDate%22%3A%222020-05-11%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHiraishi%2C%20M.%3B%20Kojima%2C%20K.%20M.%3B%20Okabe%2C%20H.%3B%20Takeshita%2C%20S.%3B%20Koda%2C%20A.%3B%20Kadono%2C%20R.%3B%20Khasanov%2C%20R.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Magnetism%20Driven%20by%20Strong%20Electronic%20Correlations%20in%20the%20Heavily%20Carrier-Doped%20Iron%20Oxypnictide%20LaFeAsO0.4H0.51.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2020%3C%5C%2Fb%3E%2C%20%3Ci%3E101%3C%5C%2Fi%3E%20%2817%29%2C%20174414.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.101.174414%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.101.174414%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Magnetism%20driven%20by%20strong%20electronic%20correlations%20in%20the%20heavily%20carrier-doped%20iron%20oxypnictide%20LaFeAsO0.4H0.51%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Hiraishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%20M.%22%2C%22lastName%22%3A%22Kojima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Okabe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Takeshita%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Koda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Kadono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Khasanov%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%20magnetism%20of%20the%20second%20antiferromagnetic%20phase%20%28AF2%29%20arising%20in%20the%20iron-based%20LaFeAsO1%5Cu2212xHx%20superconductor%20for%20x%5Cu22730.4%20was%20investigated%20by%20muon%20spin%20rotation%20measurements%20under%20hydrostatic%20pressure%20up%20to%202.6%20GPa.%20The%20N%5Cu00e9el%20temperature%20%28TN%29%20obtained%20for%20a%20sample%20with%20x%3D0.51%20exhibits%20considerably%20greater%20sensitivity%20to%20pressure%20than%20that%20in%20the%20pristine%20antiferromagnetic%20phase%20%28AF1%3B%20x%5Cu22720.06%29.%20Moreover%2C%20while%20the%20AF1%20phase%20is%20always%20accompanied%20by%20the%20structural%20transition%20%28from%20tetragonal%20to%20orthorhombic%29%20at%20a%20temperature%20%28Ts%29%20which%20is%20slightly%20higher%20than%20TN%2C%20the%20AF2%20phase%20prevails%20at%20higher%20pressures%2C%20above%20%5Cu223c1.5%20GPa%2C%20where%20the%20structural%20transition%20is%20suppressed%20%28Ts%3D0%29.%20These%20features%20indicate%20that%20the%20microscopic%20origin%20of%20the%20AF2%20phase%20is%20distinct%20from%20that%20of%20AF1%2C%20suggesting%20that%20electronic%20correlation%20plays%20an%20important%20role%20in%20the%20former%20phase.%20We%20argue%20that%20the%20orbital-selective%20Mott%20transition%20is%20a%20plausible%20scenario%20to%20account%20for%20the%20observed%20pressure%20dependence%20of%20TN%20and%20Ts%20in%20the%20AF2%20phase.%22%2C%22date%22%3A%22May%2011%2C%202020%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.101.174414%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.101.174414%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T03%3A19%3A39Z%22%7D%7D%2C%7B%22key%22%3A%223TK8DITE%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Maeda%20et%20al.%22%2C%22parsedDate%22%3A%222020-07-09%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMaeda%2C%20K.%3B%20Wakayama%2C%20H.%3B%20Washio%2C%20Y.%3B%20Ishikawa%2C%20A.%3B%20Okazaki%2C%20M.%3B%20Nakata%2C%20H.%3B%20Matsuishi%2C%20S.%20Visible-Light-Induced%20Photocatalytic%20Activity%20of%20Stacked%20MXene%20Sheets%20of%20Y2CF2.%20%3Ci%3EJ.%20Phys.%20Chem.%20C%3C%5C%2Fi%3E%20%3Cb%3E2020%3C%5C%2Fb%3E%2C%20%3Ci%3E124%3C%5C%2Fi%3E%20%2827%29%2C%2014640%26%23x2013%3B14645.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcc.0c03072%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcc.0c03072%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Visible-Light-Induced%20Photocatalytic%20Activity%20of%20Stacked%20MXene%20Sheets%20of%20Y2CF2%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazuhiko%22%2C%22lastName%22%3A%22Maeda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Haruki%22%2C%22lastName%22%3A%22Wakayama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yasuhito%22%2C%22lastName%22%3A%22Washio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Asako%22%2C%22lastName%22%3A%22Ishikawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Megumi%22%2C%22lastName%22%3A%22Okazaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroko%22%2C%22lastName%22%3A%22Nakata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%5D%2C%22abstractNote%22%3A%22Transition%20metal%20carbides%2C%20nitrides%2C%20and%20carbonitrides%20%28MXenes%29%20are%20emerging%20two-dimensional%20%282D%29%20materials%2C%20with%20a%20variety%20of%20applications%2C%20such%20as%20heterogeneous%20catalysis%2C%20due%20to%20their%20metallic%20conductivity%20and%20resulting%20charge%20transport%20properties.%20However%2C%20the%20semiconductor%20photocatalysis%20of%20MXene-related%20materials%20has%20not%20been%20experimentally%20demonstrated.%20Here%2C%20we%20show%20that%20stacked%20MXene%20sheets%20of%20Y2CF2%20behave%20as%20an%20n-type%20semiconductor%2C%20with%20a%201.9%20eV%20band%20gap%20and%20a%20rather%20negative%20conduction%20band%20potential%20of%20approximately%20%5Cu22122.1%20V%20versus%20Ag%5C%2FAgNO3.%20In%20the%20presence%20of%20triethanolamine%20as%20an%20electron%20donor%2C%20Y2CF2%20exhibits%20the%20ability%20to%20reduce%20protons%20into%20H2%20under%20visible%20light.%20However%2C%20Y2CF2%20is%20not%20very%20stable%20during%20the%20photoreaction%2C%20even%20in%20the%20presence%20of%20triethanolamine%2C%20undergoing%20oxidative%20degradation%20to%20form%20fluorocarbon%20and%20carbonate%20species%20due%20primarily%20to%20the%20high-energy%20valence%20band%20formed%20by%20C%202p%20orbitals.%22%2C%22date%22%3A%222020-07-09%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.jpcc.0c03072%22%2C%22ISSN%22%3A%221932-7447%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcc.0c03072%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-07-15T01%3A03%3A29Z%22%7D%7D%2C%7B%22key%22%3A%226VPJB3GE%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Wu%20et%20al.%22%2C%22parsedDate%22%3A%222020-10-19%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EWu%2C%20T.%3B%20Fujii%2C%20K.%3B%20Murakami%2C%20T.%3B%20Yashima%2C%20M.%3B%20Matsuishi%2C%20S.%20Synthesis%20and%20Photoluminescence%20Properties%20of%20Rare-Earth-Activated%20Sr3%26%23x2013%3BXAxAlO4H%20%28A%20%3D%20Ca%2C%20Ba%3B%20x%20%3D%200%2C%201%29%3A%20New%20Members%20of%20Aluminate%20Oxyhydrides.%20%3Ci%3EInorg.%20Chem.%3C%5C%2Fi%3E%20%3Cb%3E2020%3C%5C%2Fb%3E%2C%20%3Ci%3E59%3C%5C%2Fi%3E%20%2820%29%2C%2015384%26%23x2013%3B15393.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.0c02356%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.0c02356%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Synthesis%20and%20Photoluminescence%20Properties%20of%20Rare-Earth-Activated%20Sr3%5Cu2013xAxAlO4H%20%28A%20%3D%20Ca%2C%20Ba%3B%20x%20%3D%200%2C%201%29%3A%20New%20Members%20of%20Aluminate%20Oxyhydrides%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tong%22%2C%22lastName%22%3A%22Wu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kotaro%22%2C%22lastName%22%3A%22Fujii%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Taito%22%2C%22lastName%22%3A%22Murakami%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masatomo%22%2C%22lastName%22%3A%22Yashima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%5D%2C%22abstractNote%22%3A%22A%20series%20of%20aluminate-based%20oxyhydrides%2C%20Sr3%5Cu2013xAxAlO4H%20%28A%20%3D%20Ca%2C%20Ba%3B%20x%20%3D%200%2C%201%29%2C%20has%20been%20synthesized%20by%20high-temperature%20reaction%20of%20oxide%20and%20hydride%20precursors%20under%20a%20H2%20atmosphere.%20Their%20crystal%20structures%20determined%20via%20X-ray%20and%20neutron%20powder%20diffraction%20are%20isostructural%20with%20tetragonal%20Sr3AlO4F%20%28space%20group%20I4%5C%2Fmcm%29%2C%20consisting%20of%20%28Sr1%5Cu2013x%5C%2F3Ax%5C%2F3%292H%20layers%20and%20isolated%20AlO4%20tetrahedra.%20Rietveld%20refinement%20based%20on%20the%20diffraction%20patterns%20and%20bond-valence-sum%20analysis%20show%20that%20Ba%20preferentially%20occupies%20the%2010-coordinated%20Sr1%20sites%2C%20while%20Ca%20strongly%20prefers%20to%20occupy%20the%208-coordinated%20Sr2%20sites.%20Luminescence%20owing%20to%20the%204f%5Cu20135d%20transition%20of%20Eu2%2B%20or%20Ce3%2B%20was%20observed%20from%20Eu-%20and%20Ce-doped%20samples%2C%20Sr3%5Cu2013x%5Cu2013yAxByAlO4H%20%28A%20%3D%20Ca%2C%20Ba%3B%20B%20%3D%20Eu%2C%20Ce%3B%20x%20%3D%200%2C%201%2C%20y%20%3D%200.02%29%2C%20under%20excitation%20of%20near-ultraviolet%20light.%20Compared%20with%20its%20fluoride%20analogue%2C%20Sr3AlO4H%3ACe3%2B%20shows%20red%20shifts%20of%20both%20the%20excitation%20and%20emission%20bands%2C%20which%20is%20consistent%20with%20the%20reported%20hydride-based%20phosphors%20and%20can%20be%20explained%20by%20the%20covalency%20of%20the%20hydride%20ligands.%20The%20observed%20luminescence%20spectra%20can%20be%20decomposed%20into%20two%20sets%20of%20sub-bands%20corresponding%20to%20Ce3%2B%20centers%20occupying%20Sr1%20and%20Sr2%20sites%20with%20distinctly%20different%20Stokes%20shifts%20%281.27%20and%200.54%20eV%2C%20respectively%29%2C%20as%20suggested%20by%20the%20results%20of%20constrained%20density%20functional%20theory%20%28cDFT%29.%20The%20cDFT%20results%20also%20suggest%20that%20the%20large%20shift%20for%20Ce3%2B%20at%20Sr1%20is%20induced%20by%20large%20distortion%20of%20the%20coordinated%20structure%20with%20shortening%20of%20the%20H%5Cu2013Ce%20bond%20in%20the%20excited%20state.%20The%20current%20findings%20expand%20the%20class%20of%20oxyhydride%20materials%20and%20show%20the%20potential%20of%20hydride-based%20phosphors%20for%20optical%20applications.%22%2C%22date%22%3A%222020-10-19%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.inorgchem.0c02356%22%2C%22ISSN%22%3A%220020-1669%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.0c02356%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22ZITQFSDI%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A16%3A35Z%22%7D%7D%2C%7B%22key%22%3A%22KVAPPR2H%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hirayama%20et%20al.%22%2C%22parsedDate%22%3A%222020-10-26%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHirayama%2C%20M.%3B%20Takahashi%2C%20R.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Murakami%2C%20S.%20Higher-Order%20Topological%20Crystalline%20Insulating%20Phase%20and%20Quantized%20Hinge%20Charge%20in%20Topological%20Electride%20Apatite.%20%3Ci%3EPhys.%20Rev.%20Research%3C%5C%2Fi%3E%20%3Cb%3E2020%3C%5C%2Fb%3E%2C%20%3Ci%3E2%3C%5C%2Fi%3E%20%284%29%2C%20043131.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevResearch.2.043131%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevResearch.2.043131%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Higher-order%20topological%20crystalline%20insulating%20phase%20and%20quantized%20hinge%20charge%20in%20topological%20electride%20apatite%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Motoaki%22%2C%22lastName%22%3A%22Hirayama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ryo%22%2C%22lastName%22%3A%22Takahashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shuichi%22%2C%22lastName%22%3A%22Murakami%22%7D%5D%2C%22abstractNote%22%3A%22In%20some%20kind%20of%20three-dimensional%20higher-order%20topological%20insulators%2C%20bulk%20and%20surface%20electronic%20states%20are%20gapped%2C%20while%20there%20appear%20gapless%20hinge%20states%20protected%20by%20spatial%20symmetry.%20Here%20we%20show%20by%20ab%20initio%20calculations%20that%20the%20La%20apatite%20electride%20is%20a%20higher-order%20topological%20crystalline%20insulator.%20It%20is%20a%20one-dimensional%20electride%2C%20in%20which%20the%20one-dimensional%20interstitial%20hollows%20along%20the%20c%20axis%20support%20anionic%20electrons%2C%20and%20the%20electronic%20states%20in%20these%20one-dimensional%20channels%20are%20well%20approximated%20by%20the%20one-dimensional%20Su-Schrieffer-Heeger%20model.%20When%20the%20crystal%20is%20cleaved%20into%20a%20hexagonal%20prism%2C%20the%20120%5Cu2218%20hinges%20support%20gapless%20hinge%20states%2C%20with%20their%20filling%20quantized%20to%20be%202%5C%2F3.%20This%20quantization%20of%20the%20filling%20comes%20from%20a%20topological%20origin.%20We%20find%20that%20the%20quantized%20value%20of%20the%20filling%20depends%20on%20the%20fundamental%20blocks%20that%20constitute%20the%20crystal.%20The%20apatite%20consists%20of%20the%20triangular%20blocks%2C%20which%20is%20crucial%20for%20giving%20nontrivial%20fractional%20charge%20at%20the%20hinge.%22%2C%22date%22%3A%22October%2026%2C%202020%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevResearch.2.043131%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevResearch.2.043131%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-09-24T06%3A01%3A17Z%22%7D%7D%2C%7B%22key%22%3A%22RH5SFEAY%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Tamatsukuri%20et%20al.%22%2C%22parsedDate%22%3A%222020-12-04%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ETamatsukuri%2C%20H.%3B%20Murakami%2C%20Y.%3B%20Kuramoto%2C%20Y.%3B%20Sagayama%2C%20H.%3B%20Matsuura%2C%20M.%3B%20Kawakita%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Washio%2C%20Y.%3B%20Inoshita%2C%20T.%3B%20Hamada%2C%20N.%3B%20Hosono%2C%20H.%20Magnetism%20Induced%20by%20Interlayer%20Electrons%20in%20the%20Quasi-Two-Dimensional%20Electride%20Y2C%3A%20Inelastic%20Neutron%20Scattering%20Study.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2020%3C%5C%2Fb%3E%2C%20%3Ci%3E102%3C%5C%2Fi%3E%20%2822%29%2C%20224406.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.102.224406%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.102.224406%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Magnetism%20induced%20by%20interlayer%20electrons%20in%20the%20quasi-two-dimensional%20electride%20Y2C%3A%20Inelastic%20neutron%20scattering%20study%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiromu%22%2C%22lastName%22%3A%22Tamatsukuri%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Youichi%22%2C%22lastName%22%3A%22Murakami%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshio%22%2C%22lastName%22%3A%22Kuramoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hajime%22%2C%22lastName%22%3A%22Sagayama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masato%22%2C%22lastName%22%3A%22Matsuura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yukinobu%22%2C%22lastName%22%3A%22Kawakita%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yasuhito%22%2C%22lastName%22%3A%22Washio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takeshi%22%2C%22lastName%22%3A%22Inoshita%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Noriaki%22%2C%22lastName%22%3A%22Hamada%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Magnetic%20excitations%20in%20layered%20electride%20Y2C%20have%20been%20found%20by%20inelastic%20neutron%20scattering.%20We%20have%20observed%20weak%20but%20clear%20magnetic%20scattering%20around%20the%20wave%20number%20Q%3D0%2C%20but%20no%20magnetic%20order%20down%20to%20the%20lowest%20temperature%20measured%20%287%20K%29.%20The%20imaginary%20part%20of%20the%20dynamical%20susceptibility%20deduced%20is%20well%20described%20by%20the%20Lorentz%20function%20of%20energy%20E%20for%20each%20momentum%20Q.%20The%20width%20%5Cu0393%28Q%29%20of%20the%20Lorentzian%20is%20proportional%20to%20Q%28Q2%2B%5Cu03ba2%29%20with%20%5Cu03ba%5Cu22121%5Cu223c4%5Cu00c5%20at%20T%3D7%20K.%20We%20have%20also%20found%20that%20with%20increasing%20Q%20the%20magnetic%20form%20factor%20decays%20faster%20than%20that%20of%20a%204d%20electron%20in%20a%20single%20Y%20atom%2C%20which%20indicates%20a%20more%20extended%20magnetic%20moment%20in%20Y2C.%20These%20results%20provide%20experimental%20evidence%20that%20the%20itinerant%20magnetism%20in%20Y2C%20originates%20from%20the%20anionic%20electrons%20that%20reside%20in%20the%20interlayers.%20The%20Curie-Weiss-like%20behavior%20of%20the%20magnetic%20susceptibility%20reported%20in%20Y2C%20is%20ascribed%20to%20the%20mode%20coupling%20effects%20of%20spin%20fluctuations.%22%2C%22date%22%3A%22December%204%2C%202020%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.102.224406%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.102.224406%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T03%3A19%3A13Z%22%7D%7D%5D%7D
(1)
Liu, Z.; Liu, T.; Savory, C. N.; Jurado, J. P.; Reparaz, J. S.; Li, J.; Pan, L.; Faul, C. F. J.; Parkin, I. P.; Sankar, G.; Matsuishi, S.; Campoy‐Quiles, M.; Scanlon, D. O.; Zwijnenburg, M. A.; Fenwick, O.; Schroeder, B. C. Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design. Advanced Functional Materials 2020, 30 (32), 2003106. https://doi.org/https://doi.org/10.1002/adfm.202003106.
(1)
Wu, J.; Liu, F.; Liu, C.; Wang, Y.; Li, C.; Lu, Y.; Matsuishi, S.; Hosono, H. Toward 2D Magnets in the (MnBi2Te4)(Bi2Te3)n Bulk Crystal. Advanced Materials 2020, 32 (23), 2001815. https://doi.org/https://doi.org/10.1002/adma.202001815.
(1)
Hiraishi, M.; Kojima, K. M.; Okabe, H.; Takeshita, S.; Koda, A.; Kadono, R.; Khasanov, R.; Iimura, S.; Matsuishi, S.; Hosono, H. Magnetism Driven by Strong Electronic Correlations in the Heavily Carrier-Doped Iron Oxypnictide LaFeAsO0.4H0.51. Phys. Rev. B 2020, 101 (17), 174414. https://doi.org/10.1103/PhysRevB.101.174414.
(1)
Maeda, K.; Wakayama, H.; Washio, Y.; Ishikawa, A.; Okazaki, M.; Nakata, H.; Matsuishi, S. Visible-Light-Induced Photocatalytic Activity of Stacked MXene Sheets of Y2CF2. J. Phys. Chem. C 2020, 124 (27), 14640–14645. https://doi.org/10.1021/acs.jpcc.0c03072.
(1)
Wu, T.; Fujii, K.; Murakami, T.; Yashima, M.; Matsuishi, S. Synthesis and Photoluminescence Properties of Rare-Earth-Activated Sr3–XAxAlO4H (A = Ca, Ba; x = 0, 1): New Members of Aluminate Oxyhydrides. Inorg. Chem. 2020, 59 (20), 15384–15393. https://doi.org/10.1021/acs.inorgchem.0c02356.
(1)
Hirayama, M.; Takahashi, R.; Matsuishi, S.; Hosono, H.; Murakami, S. Higher-Order Topological Crystalline Insulating Phase and Quantized Hinge Charge in Topological Electride Apatite. Phys. Rev. Research 2020, 2 (4), 043131. https://doi.org/10.1103/PhysRevResearch.2.043131.
(1)
Tamatsukuri, H.; Murakami, Y.; Kuramoto, Y.; Sagayama, H.; Matsuura, M.; Kawakita, Y.; Matsuishi, S.; Washio, Y.; Inoshita, T.; Hamada, N.; Hosono, H. Magnetism Induced by Interlayer Electrons in the Quasi-Two-Dimensional Electride Y2C: Inelastic Neutron Scattering Study. Phys. Rev. B 2020, 102 (22), 224406. https://doi.org/10.1103/PhysRevB.102.224406.
244926
P5622579
2019
items
1
american-chemical-society-with-titles-sentence-case-doi
0
date
asc
year
6
https://www.mces.titech.ac.jp/authors/matsuishi/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-c23919735a2b74bf491dd7b29a80f8f0%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22HAJZVKBX%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hanzawa%20et%20al.%22%2C%22parsedDate%22%3A%222019-01-24%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHanzawa%2C%20K.%3B%20Yamaguchi%2C%20Y.%3B%20Obata%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hiramatsu%2C%20H.%3B%20Kamiya%2C%20T.%3B%20Hosono%2C%20H.%20Insulator-like%20Behavior%20Coexisting%20with%20Metallic%20Electronic%20Structure%20in%20Strained%20FeSe%20Thin%20Films%20Grown%20by%20Molecular%20Beam%20Epitaxy.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2019%3C%5C%2Fb%3E%2C%20%3Ci%3E99%3C%5C%2Fi%3E%20%283%29%2C%20035148.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.99.035148%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.99.035148%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Insulator-like%20behavior%20coexisting%20with%20metallic%20electronic%20structure%20in%20strained%20FeSe%20thin%20films%20grown%20by%20molecular%20beam%20epitaxy%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kota%22%2C%22lastName%22%3A%22Hanzawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yuta%22%2C%22lastName%22%3A%22Yamaguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yukiko%22%2C%22lastName%22%3A%22Obata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hidenori%22%2C%22lastName%22%3A%22Hiramatsu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshio%22%2C%22lastName%22%3A%22Kamiya%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22This%20paper%20reports%20that%20%5Cu223c10-nm-thick%20iron%20selenide%20%28FeSe%29%20thin%20films%20exhibit%20insulator-like%20behavior%20in%20terms%20of%20the%20temperature%20dependence%20of%20their%20electrical%20resistivity%20even%20though%20bulk%20FeSe%20has%20a%20metallic%20electronic%20structure%20that%20has%20been%20confirmed%20by%20photoemission%20spectroscopy%20and%20first-principles%20calculations.%20This%20apparent%20contradiction%20is%20explained%20by%20potential%20barriers%20formed%20in%20the%20conduction%20band.%20Very%20thin%20FeSe%20epitaxial%20films%20with%20various%20atomic%20composition%20ratios%20%28%5BFe%5D%5C%2F%5BSe%5D%29%20were%20fabricated%20by%20molecular%20beam%20epitaxy%20and%20classified%20into%20two%20groups%20with%20respect%20to%20lattice%20strain%20and%20electrical%20properties.%20Lattice%20parameter%20a%20increased%20and%20lattice%20parameter%20c%20decreased%20with%20increasing%20%5BFe%5D%5C%2F%5BSe%5D%20up%20to%201.1%20and%20then%20a%20leveled%20off%20and%20c%20began%20to%20decrease%20at%20higher%20%5BFe%5D%5C%2F%5BSe%5D.%20Consequently%2C%20the%20FeSe%20films%20had%20the%20most%20strained%20lattice%20when%20%5BFe%5D%5C%2F%5BSe%5D%20was%201.1%2C%20but%20these%20films%20had%20the%20best%20quality%20with%20respect%20to%20crystallinity%20and%20surface%20flatness.%20All%20the%20FeSe%20films%20with%20%5BFe%5D%5C%2F%5BSe%5D%20of%200.8%5Cu20131.9%20exhibited%20insulator-like%20behavior%2C%20but%20the%20temperature%20dependences%20of%20their%20electrical%20resistivities%20exhibited%20different%20activation%20energies%20Ea%20between%20the%20Se-rich%20and%20Fe-rich%20regions%3B%20i.e.%2C%20Ea%20were%20small%20%28a%20few%20meV%29%20up%20to%20%5BFe%5D%5C%2F%5BSe%5D%3D1.1%20but%20jumped%20up%20to%20%5Cu223c25%20meV%20at%20higher%20%5BFe%5D%5C%2F%5BSe%5D.%20The%20film%20with%20%5BFe%5D%5C%2F%5BSe%5D%3D1.1%20had%20the%20smallest%20Ea%20of%201.1%20meV%20and%20exhibited%20an%20insulator%5Cu2013superconducting%20transition%20at%2035%20K%20with%20zero%20resistance%20under%20gate%20bias.%20The%20large%20Ea%20of%20the%20Fe-rich%20films%20was%20attributed%20to%20the%20unusual%20lattice%20strain%20with%20tensile%20in-plane%20and%20relaxed%20out-of-plane%20strains.%20The%20large%20Ea%20of%20films%20with%20%5BFe%5D%5C%2F%5BSe%5D%20%3E%201.1%20resulted%20in%20low%20mobility%20with%20a%20high%20potential%20barrier%20of%20%5Cu223c50%20meV%20in%20the%20conduction%20band%20for%20percolation%20carrier%20conduction%20compared%20with%20that%20of%20the%20%5BFe%5D%5C%2F%5BSe%5D%3D1.1%20film%20%28%5Cu223c17%20meV%29.%20Therefore%2C%20the%20Fe-rich%20films%20exhibited%20remarkable%20insulator-like%20behavior%20similar%20to%20a%20semiconductor%20despite%20their%20metallic%20electronic%20structure.%20The%20high%20potential%20barrier%20of%20Fe-rich%20films%20is%20tentatively%20attributed%20to%20the%20presence%20of%20large%20amounts%20of%20excess%20Fe%2C%20which%20could%20plausibly%20cause%20a%20broad%20superconducting%20transition%20without%20zero%20resistance%20under%20gating.%22%2C%22date%22%3A%22January%2024%2C%202019%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.99.035148%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.99.035148%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A25%3A31Z%22%7D%7D%2C%7B%22key%22%3A%226N3N6QYY%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Wu%20et%20al.%22%2C%22parsedDate%22%3A%222019-02-11%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EWu%2C%20T.%3B%20Ishikawa%2C%20A.%3B%20Honda%2C%20T.%3B%20Tamatsukuri%2C%20H.%3B%20Ikeda%2C%20K.%3B%20Otomo%2C%20T.%3B%20Matsuishi%2C%20S.%20Nephelauxetic%20Effect%20of%20the%20Hydride%20Ligand%20in%20Sr%3Csub%3E2%3C%5C%2Fsub%3ELiSiO%3Csub%3E4%3C%5C%2Fsub%3EH%20as%20a%20Host%20Material%20for%20Rare-Earth-Activated%20Phosphors.%20%3Ci%3ERSC%20Adv.%3C%5C%2Fi%3E%20%3Cb%3E2019%3C%5C%2Fb%3E%2C%20%3Ci%3E9%3C%5C%2Fi%3E%20%2810%29%2C%205282%26%23x2013%3B5287.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FC8RA08344D%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FC8RA08344D%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Nephelauxetic%20effect%20of%20the%20hydride%20ligand%20in%20Sr%3Csub%3E2%3C%5C%2Fsub%3ELiSiO%3Csub%3E4%3C%5C%2Fsub%3EH%20as%20a%20host%20material%20for%20rare-earth-activated%20phosphors%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tong%22%2C%22lastName%22%3A%22Wu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Asako%22%2C%22lastName%22%3A%22Ishikawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takashi%22%2C%22lastName%22%3A%22Honda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiromu%22%2C%22lastName%22%3A%22Tamatsukuri%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazutaka%22%2C%22lastName%22%3A%22Ikeda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshiya%22%2C%22lastName%22%3A%22Otomo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%5D%2C%22abstractNote%22%3A%22Strontium%20lithium%20orthosilicate%20hydride%20Sr2LiSiO4H%20was%20synthesized%20by%20the%20reaction%20of%20Sr2SiO4%20with%20LiH%20at%20700%20%5Cu00b0C%20in%20a%20H2%20rich%20atmosphere.%20Rietveld%20refinement%20of%20the%20neutron%20powder%20diffraction%20pattern%20revealed%20that%20Sr2LiSiO4H%20is%20isostructural%20to%20Sr2LiSiO4F%20%28space%20group%20P21%5C%2Fm%29%20and%20its%20channel-like%20structure%20preferentially%20accommodates%20H%5Cu2212%20ions%20over%20F%5Cu2212%20ions.%20In%20addition%2C%20Sr2LiSiO4H%20is%20stable%20in%20air%20and%20its%20Eu2%2B-doped%20analog%20exhibits%20yellow%20photoluminescence%20with%20an%20emission%20band%20at%20544%20nm%20and%20a%20broad%20excitation%20band%20ranging%20from%20250%20to%20450%20nm.%20These%20bands%20were%20observed%20in%20the%20longer%20wavelength%20region%20when%20compared%20with%20those%20displayed%20by%20Sr2LiSiO4F%3AEu2%2B.%20The%20red%20shift%2C%20which%20is%20induced%20by%20H%5Cu2212%20substitution%2C%20is%20consistent%20with%20the%20constrained%20density%20functional%20theory%20calculations%2C%20predicting%20the%20photo-excitation%20and%20emission%20energies%20of%204f%5Cu20135d%20transitions.%20The%20present%20study%20reports%20the%20synthesis%20of%20stable%20oxyhydrides%20acting%20as%20phosphor%20hosts%20for%20rare%20earth%20ions.%20The%20phosphor%20hosts%20exhibit%20large%20nephelauxetic%20effects%20owing%20to%20the%20presence%20of%20H%5Cu2212%20ligands.%22%2C%22date%22%3A%222019-02-11%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1039%5C%2FC8RA08344D%22%2C%22ISSN%22%3A%222046-2069%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fpubs.rsc.org%5C%2Fen%5C%2Fcontent%5C%2Farticlelanding%5C%2F2019%5C%2Fra%5C%2Fc8ra08344d%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22ZITQFSDI%22%5D%2C%22dateModified%22%3A%222019-03-07T09%3A38%3A15Z%22%7D%7D%2C%7B%22key%22%3A%22THGEZKJB%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Obata%20et%20al.%22%2C%22parsedDate%22%3A%222019-03-22%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EObata%2C%20Y.%3B%20Kohama%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Shubnikov--de%20Haas%20Oscillations%20in%20the%20Three-Dimensional%20Dirac%20Fermion%20System%20Ca%3Csub%3E3%3C%5C%2Fsub%3EPbO.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2019%3C%5C%2Fb%3E%2C%20%3Ci%3E99%3C%5C%2Fi%3E%20%2811%29%2C%20115133.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.99.115133%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.99.115133%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Shubnikov--de%20Haas%20oscillations%20in%20the%20three-dimensional%20Dirac%20fermion%20system%20Ca%3Csub%3E3%3C%5C%2Fsub%3EPbO%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yukiko%22%2C%22lastName%22%3A%22Obata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshimitsu%22%2C%22lastName%22%3A%22Kohama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Cubic%20antiperovskite%20Ca3PbO%20is%20a%20candidate%20for%20three-dimensional%20%283D%29%20Dirac%20fermion%20systems%20that%20have%20recently%20emerged%20as%20a%20class%20of%20topological%20materials%20exhibiting%20linear%20energy%20dispersion%20in%20the%20bulk.%20We%20report%20magnetotransport%20and%20tunnel%20diode%20oscillation%20%28TDO%29%20measurements%20on%20Bi-doped%20Ca3PbO%20in%20magnetic%20fields%20up%20to%2055%20T%20and%20temperatures%20between%202%20and%2078%20K.%20By%20observing%20the%20Shubnikov%5Cu2013de%20Haas%20%28SdH%29%20oscillations%2C%20we%20resolve%20the%20bulk%203D%20Fermi%20surface%20%28FS%29%20with%20distinctive%20features%20of%20Dirac%20fermions%20including%20linear%20magnetoresistance%2C%20light%20effective%20mass%2C%20and%20a%20nontrivial%20phase%20shift.%20TDO%20measurements%20under%20high%20fields%20reveal%20the%20existence%20of%20two%20primary%20SdH%20frequencies%2C%20one%20being%20twice%20the%20other.%20Together%20with%20the%20low%20effective%20mass%2C%20the%20oscillations%20of%20these%20two%20frequencies%20account%20for%20the%20emergence%20of%20the%20Landau%20level%20splitting%20that%20persists%20up%20to%2043%20K.%20The%20field-angular-dependence%20of%20the%20oscillation%20frequencies%20with%20three%20branches%20confirms%20that%20the%20FS%20is%20composed%20of%20three%20pairs%20of%20hole%20pockets%20with%20uniaxial%20anisotropy%20on%20the%20%5Cu0393-X%20path%2C%20as%20predicted%20for%20bulk%20Ca3PbO%20crystal%20by%20density%20functional%20theory%20calculation.%22%2C%22date%22%3A%22March%2022%2C%202019%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.99.115133%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.99.115133%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222019-04-18T07%3A34%3A48Z%22%7D%7D%2C%7B%22key%22%3A%22IJ3C2D2Z%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Takeuchi%20et%20al.%22%2C%22parsedDate%22%3A%222019-05-28%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ETakeuchi%2C%20M.%3B%20Fujiwara%2C%20N.%3B%20Kuwayama%2C%20T.%3B%20Nakagawa%2C%20S.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Yamakawa%2C%20Y.%3B%20Kontani%2C%20H.%3B%20Hosono%2C%20H.%20Pressure-Induced%20Quantum%20Critical%20Point%20in%20the%20Heavily%20Hydrogen-Doped%20Iron-Based%20Superconductor%20LaFeAsO.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2019%3C%5C%2Fb%3E%2C%20%3Ci%3E99%3C%5C%2Fi%3E%20%2817%29%2C%20174517.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.99.174517%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.99.174517%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Pressure-induced%20quantum%20critical%20point%20in%20the%20heavily%20hydrogen-doped%20iron-based%20superconductor%20LaFeAsO%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masayoshi%22%2C%22lastName%22%3A%22Takeuchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Naoki%22%2C%22lastName%22%3A%22Fujiwara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takanori%22%2C%22lastName%22%3A%22Kuwayama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoshi%22%2C%22lastName%22%3A%22Nakagawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Youichi%22%2C%22lastName%22%3A%22Yamakawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Kontani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22An%20iron-based%20superconductor%20LaFeAsO1%5Cu2212xHx%280%5Cu2264x%5Cu22640.6%29%20undergoes%20two%20antiferromagnetic%20%28AF%29%20phases%20upon%20H%20doping.%20We%20investigated%20the%20second%20AF%20phase%20%28x%3D0.6%29%20using%20NMR%20techniques%20under%20pressure.%20At%20pressures%20up%20to%202%20GPa%2C%20the%20ground%20state%20is%20a%20spin-density-wave%20state%20with%20a%20large%20gap%3B%20however%2C%20the%20gap%20closes%20at%204.0%20GPa%2C%20suggesting%20a%20pressure-induced%20quantum%20critical%20point.%20Interestingly%2C%20the%20gapped%20excitation%20coexists%20with%20gapless%20magnetic%20fluctuations%20at%20pressures%20between%202%20and%204%20GPa.%20This%20coexistence%20is%20attributable%20to%20the%20lift%20up%20of%20the%20dxy%20orbital%20to%20the%20Fermi%20level%2C%20a%20Lifshitz%20transition%20under%20pressure.%22%2C%22date%22%3A%22May%2028%2C%202019%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.99.174517%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.99.174517%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A24%3A54Z%22%7D%7D%2C%7B%22key%22%3A%22TAUV2YBH%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fujiwara%20et%20al.%22%2C%22parsedDate%22%3A%222019-06-04%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EFujiwara%2C%20N.%3B%20Takeuchi%2C%20M.%3B%20Kuwayama%2C%20T.%3B%20Nakagawa%2C%20S.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Nuclear%20Magnetic%20Resonance%20on%20LaFeAsO0.4H0.6%20at%203.7%20GPa.%20%3Ci%3EPapers%20in%20Physics%3C%5C%2Fi%3E%20%3Cb%3E2019%3C%5C%2Fb%3E%2C%20%3Ci%3E11%3C%5C%2Fi%3E%2C%20110002%26%23x2013%3B110002.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.4279%5C%2Fpip.110002%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.4279%5C%2Fpip.110002%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Nuclear%20magnetic%20resonance%20on%20LaFeAsO0.4H0.6%20at%203.7%20GPa%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Fujiwara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Takeuchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Kuwayama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Nakagawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22A%20prototypical%20electron-doped%20iron-based%20superconductor%20LaFeAsO1%5Cu2212xHxLaFeAsO1%5Cu2212xHxLaFeAsO_%7B1-x%7DH_x%20undergoes%20an%20antiferromagnetic%20%28AF%29%20phase%20for%20x%5Cu22650.49x%5Cu22650.49x%5Cu00a0%20%5C%5Cgeq%200.49.%20We%20performed%20NMR%20measurements%20on%20LaFeAsO0.4H0.6LaFeAsO0.4H0.6LaFeAsO_%7B0.4%7DH_%7B0.6%7D%20at%203.7%20GPa%20to%20investigate%20the%20magnetic%20properties%20in%20the%20vicinity%20of%20a%20pressure-induced%20QCP.%20The%20linewidth%20of%20%5Cu00a01H%5Cu00a01H~%5E1H-NMR%20spectra%20broadens%20at%20low%20temperatures%20below%2030%20K%2C%20suggesting%20that%20the%20ordered%20spin%20moments%20remain%20at%203.7%20GPa.%20The%20coexistence%20of%20gapped%20and%20gapless%20spin%20excitations%20was%20confirmed%20in%20the%20ordered%20state%20from%20the%20relaxation%20time%20T1T1T_1%20of%20%5Cu00a075As%5Cu00a075As~%5E%7B75%7DAs.%20The%20pressure-induced%20QCP%20is%20estimated%20to%20be%204.1%20GPa%20from%20the%20pressure%20dependence%20of%20the%20gapped%20excitation.%5Cn%5Cu00a0%5CnEdited%20by%3A%20A.%20Go%5Cu00f1i%2C%20A.%20Cantarero%2C%20J.%20S.%20Reparaz%22%2C%22date%22%3A%222019%5C%2F06%5C%2F04%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.4279%5C%2Fpip.110002%22%2C%22ISSN%22%3A%221852-4249%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.papersinphysics.org%5C%2Fpapersinphysics%5C%2Farticle%5C%2Fview%5C%2F475%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A54%3A46Z%22%7D%7D%2C%7B%22key%22%3A%228X2LMRXB%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Yamaura%20et%20al.%22%2C%22parsedDate%22%3A%222019-06-13%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EYamaura%2C%20J.%3B%20Hiraka%2C%20H.%3B%20Iimura%2C%20S.%3B%20Muraba%2C%20Y.%3B%20Bang%2C%20J.%3B%20Ikeuchi%2C%20K.%3B%20Nakamura%2C%20M.%3B%20Inamura%2C%20Y.%3B%20Honda%2C%20T.%3B%20Hiraishi%2C%20M.%3B%20Kojima%2C%20K.%20M.%3B%20Kadono%2C%20R.%3B%20Kuramoto%2C%20Y.%3B%20Murakami%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Quantum%20Dynamics%20of%20Hydrogen%20in%20the%20Iron-Based%20Superconductor%20LaFeAsO%3Csub%3E0.9%3C%5C%2Fsub%3ED%3Csub%3E0.1%3C%5C%2Fsub%3E%20Measured%20with%20Inelastic%20Neutron%20Spectroscopy.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2019%3C%5C%2Fb%3E%2C%20%3Ci%3E99%3C%5C%2Fi%3E%20%2822%29%2C%20220505.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.99.220505%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.99.220505%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Quantum%20dynamics%20of%20hydrogen%20in%20the%20iron-based%20superconductor%20LaFeAsO%3Csub%3E0.9%3C%5C%2Fsub%3ED%3Csub%3E0.1%3C%5C%2Fsub%3E%20measured%20with%20inelastic%20neutron%20spectroscopy%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jun-ichi%22%2C%22lastName%22%3A%22Yamaura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Haruhiro%22%2C%22lastName%22%3A%22Hiraka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshinori%22%2C%22lastName%22%3A%22Muraba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joonho%22%2C%22lastName%22%3A%22Bang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazuhiko%22%2C%22lastName%22%3A%22Ikeuchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mitsutaka%22%2C%22lastName%22%3A%22Nakamura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yasuhiro%22%2C%22lastName%22%3A%22Inamura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takashi%22%2C%22lastName%22%3A%22Honda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masatoshi%22%2C%22lastName%22%3A%22Hiraishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kenji%20M.%22%2C%22lastName%22%3A%22Kojima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ryosuke%22%2C%22lastName%22%3A%22Kadono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshio%22%2C%22lastName%22%3A%22Kuramoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Youichi%22%2C%22lastName%22%3A%22Murakami%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Inelastic%20neutron%20scattering%20was%20performed%20for%20an%20iron-based%20superconductor%20LaFeAsO0.9D0.1%2C%20where%20most%20of%20D%20%28deuterium%29%20replaces%20oxygen%2C%20while%20a%20tiny%20amount%20goes%20into%20the%20interstitial%20sites.%20By%20first-principles%20calculation%2C%20we%20characterize%20the%20interstitial%20sites%20for%20D%20%28and%20for%20H%20slightly%20mixed%29%20with%20four%20equivalent%20potential%20minima.%20Below%20the%20superconducting%20transition%20temperature%20Tc%3D26K%2C%20excitations%20emerge%20in%20the%20range%205%5Cu201315%20meV%2C%20while%20they%20are%20absent%20in%20the%20reference%20system%20LaFeAsO0.9F0.1.%20The%20strong%20excitations%20at%2014.5%20and%2011.1%20meV%20broaden%20rapidly%20around%2015%20and%2020%20K%2C%20respectively%2C%20where%20each%20energy%20becomes%20comparable%20to%20twice%20the%20superconducting%20gap.%20The%20strong%20excitations%20are%20ascribed%20to%20a%20quantum%20rattling%2C%20or%20a%20band%20motion%20of%20hydrogen%2C%20which%20arises%20only%20if%20the%20number%20of%20potential%20minima%20is%20larger%20than%20two.%22%2C%22date%22%3A%22June%2013%2C%202019%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.99.220505%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.99.220505%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222023-08-30T09%3A31%3A55Z%22%7D%7D%2C%7B%22key%22%3A%22QM768VZJ%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Mizoguchi%20et%20al.%22%2C%22parsedDate%22%3A%222019-06-20%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMizoguchi%2C%20H.%3B%20Matsuishi%2C%20S.%3B%20Park%2C%20S.-W.%3B%20Hosono%2C%20H.%20Hydrogen-Insertion-Induced%20Itinerant%20Ferromagnetism%20in%20Zr2CoH4.8%20with%20Co%20Chains.%20%3Ci%3EJ.%20Phys.%20Chem.%20C%3C%5C%2Fi%3E%20%3Cb%3E2019%3C%5C%2Fb%3E%2C%20%3Ci%3E123%3C%5C%2Fi%3E%20%2824%29%2C%2014964%26%23x2013%3B14968.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcc.9b03793%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcc.9b03793%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Hydrogen-Insertion-Induced%20Itinerant%20Ferromagnetism%20in%20Zr2CoH4.8%20with%20Co%20Chains%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Mizoguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sang-Won%22%2C%22lastName%22%3A%22Park%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22It%20is%20known%20that%20an%20intermetallic%2C%20Zr2Co%20adopting%20an%20Al2Cu-type%20crystal%20structure%2C%20exhibits%20superconductivity%20at%20Tc%20%3D%205.6%20K%20and%20can%20enable%20topotactic%20hydrogen%20insertion.%20Although%20hydrogen%20insertion%20into%20alloys%5C%2Fintermetallics%20of%20transition%20metal%20often%20prevents%20ordering%20of%20magnetic%20spin%2C%20Matar%20has%20theoretically%20predicted%20ferromagnetic%20spin%20ordering%20in%20Zr2CoH5%20based%20on%20Stoner%20conditions%20%5BMatar%2C%20S.%20F.%2C%20Intermetallics%202013%2C%2036%2C%2025%5D.%20We%20confirmed%20intercalation%5C%2Fdeintercalation%20of%20hydrogen%20into%20Zr2Co%20at%20%5Cu223c300%20%5Cu00b0C%2C%20keeping%20the%20parent%20Al2Cu-type%20structure.%20We%20have%20succeeded%20in%20experimentally%20identifying%20a%20ferromagnetic%20transition%20in%20Zr2CoH4.8%20at%20Tc%20%3D%20128%20K%2C%20as%20well%20as%20superconductivity%20in%20Zr2Co.%20The%20magnetization%20at%202%20K%20was%20%5Cu223c0.3%5Cu03bcB%2C%20although%20it%20did%20not%20saturate%20up%20to%205.5%20kOe%2C%20even%20at%202%20K.%20On%20the%20basis%20of%20analysis%20of%20magnetization%20curves%2C%20we%20confirmed%20the%20weak%20itinerant%20ferromagnetism%20of%20Zr2CoH4.8%20derived%20from%20spin%20fluctuation.%20This%20hydride%20has%20an%20isolated%20Co%20chain%20running%20along%20the%20tetragonal%20c%20axis%20with%20a%20dCo%5Cu2013Co%20intrachain%20distance%20of%202.824%287%29%20%5Cu00c5%2C%20which%20is%20longer%20than%20that%20in%20metallic%20hcp-Co%20%28%5Cu223c2.5%20%5Cu00c5%29.%20Band%20structure%20calculations%20of%20paramagnetic%20Zr2CoH5%20suggested%20that%20a%20moderate%20Co%20dz2%5Cu2013Co%20dz2%20interaction%20in%20the%20chain%20plays%20an%20important%20role%2C%20similar%20to%20that%20in%20Pt-chain%20electronic%20conductors.%22%2C%22date%22%3A%222019-06-20%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.jpcc.9b03793%22%2C%22ISSN%22%3A%221932-7447%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcc.9b03793%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A22%3A52Z%22%7D%7D%2C%7B%22key%22%3A%22PG9L4W6A%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kojima%20et%20al.%22%2C%22parsedDate%22%3A%222019-09-16%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EKojima%2C%20K.%20M.%3B%20Hiraishi%2C%20M.%3B%20Okabe%2C%20H.%3B%20Koda%2C%20A.%3B%20Kadono%2C%20R.%3B%20Ide%2C%20K.%3B%20Matsuishi%2C%20S.%3B%20Kumomi%2C%20H.%3B%20Kamiya%2C%20T.%3B%20Hosono%2C%20H.%20Electronic%20Structure%20of%20Interstitial%20Hydrogen%20in%20In-Ga-Zn-O%20Semiconductor%20Simulated%20by%20Muon.%20%3Ci%3EAppl.%20Phys.%20Lett.%3C%5C%2Fi%3E%20%3Cb%3E2019%3C%5C%2Fb%3E%2C%20%3Ci%3E115%3C%5C%2Fi%3E%20%2812%29%2C%20122104.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.5117771%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.5117771%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Electronic%20structure%20of%20interstitial%20hydrogen%20in%20In-Ga-Zn-O%20semiconductor%20simulated%20by%20muon%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%20M.%22%2C%22lastName%22%3A%22Kojima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Hiraishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Okabe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Koda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Kadono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Ide%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Kumomi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Kamiya%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20on%20the%20local%20electronic%20structure%20of%20an%20interstitial%20muon%20%28Mu%29%20as%20pseudohydrogen%20in%20In-Ga-Zn%20oxide%20%28IGZO%29%20semiconductors%20studied%20by%20muon%20spin%20rotation%5C%2Frelaxation%20%28%5Cu03bcSR%29%20experiment.%20In%20polycrystalline%20%28c-%29%20IGZO%2C%20it%20is%20inferred%20that%20Mu%20is%20in%20a%20diamagnetic%20state%2C%20where%20the%20%5Cu03bcSR%20time%20spectra%20under%20zero%20external%20field%20are%20perfectly%20described%20by%20the%20Gaussian%20Kubo-Toyabe%20relaxation%20function%20with%20the%20linewidth%20%5Cu0394%20serving%20as%20a%20sensitive%20measure%20for%20the%20random%20local%20fields%20from%20In%5C%2FGa%20nuclear%20magnetic%20moments.%20The%20magnitude%20of%20%5Cu0394%20combined%20with%20the%20density%20functional%20theory%20calculations%20for%20H%20%28to%20mimic%20Mu%29%20suggests%20that%20Mu%20occupies%20Zn-O%20bond-center%20site%20%28MuBC%29%20similar%20to%20the%20case%20in%20crystalline%20ZnO.%20This%20implies%20that%20the%20diamagnetic%20state%20in%20c-IGZO%20corresponds%20to%20Mu%2BBCMuBC%2B%3Cmath%20display%3D%5C%22inline%5C%22%20overflow%3D%5C%22scroll%5C%22%20altimg%3D%5C%22eq-00001.gif%5C%22%3E%20%3Cmrow%3E%20%3Cmsubsup%3E%20%3Cmrow%3E%20%3Cmtext%3EMu%3C%5C%2Fmtext%3E%3C%5C%2Fmrow%3E%20%3Cmrow%3E%20%3Cmtext%3EBC%3C%5C%2Fmtext%3E%3C%5C%2Fmrow%3E%20%3Cmo%3E%2B%3C%5C%2Fmo%3E%3C%5C%2Fmsubsup%3E%3C%5C%2Fmrow%3E%3C%5C%2Fmath%3E%2C%20thus%20serving%20as%20an%20electron%20donor.%20In%20amorphous%20%28a-%29%20IGZO%2C%20the%20local%20Mu%20structure%20in%20the%20as-deposited%20films%20is%20nearly%20identical%20to%20that%20in%20c-IGZO%2C%20suggesting%20Mu%2BBCMuBC%2B%3Cmath%20display%3D%5C%22inline%5C%22%20overflow%3D%5C%22scroll%5C%22%20altimg%3D%5C%22eq-00002.gif%5C%22%3E%20%3Cmrow%3E%20%3Cmsubsup%3E%20%3Cmrow%3E%20%3Cmtext%3EMu%3C%5C%2Fmtext%3E%3C%5C%2Fmrow%3E%20%3Cmrow%3E%20%3Cmtext%3EBC%3C%5C%2Fmtext%3E%3C%5C%2Fmrow%3E%20%3Cmo%3E%2B%3C%5C%2Fmo%3E%3C%5C%2Fmsubsup%3E%3C%5C%2Fmrow%3E%3C%5C%2Fmath%3E%20for%20the%20electronic%20state.%20In%20contrast%2C%20the%20diamagnetic%20signal%20in%20heavily%20hydrogenated%20a-IGZO%20films%20exhibits%20the%20Lorentzian%20Kubo-Toyabe%20relaxation%2C%20implying%20that%20Mu%20accompanies%20more%20inhomogeneous%20distribution%20of%20the%20neighboring%20nuclear%20spins%20that%20may%20involve%20a%20Mu%5Cu2212%20H%5Cu2212-complex%20state%20in%20an%20oxygen%20vacancy.%22%2C%22date%22%3A%22September%2016%2C%202019%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F1.5117771%22%2C%22ISSN%22%3A%220003-6951%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Faip.scitation.org%5C%2Fdoi%5C%2F10.1063%5C%2F1.5117771%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A21%3A56Z%22%7D%7D%2C%7B%22key%22%3A%22P9SRHEA6%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Saitoh%20et%20al.%22%2C%22parsedDate%22%3A%222019-10-01%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ESaitoh%2C%20A.%3B%20Kitani%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Kawaji%2C%20H.%3B%20Takebe%2C%20H.%3B%20Hosono%2C%20H.%20Structure%20and%20Photoelastic%20Constant%20of%20Binary%20Ns2-Type%20Metal%20Cation%20Containing%20Silicate%20Glasses.%20%3Ci%3EJournal%20of%20Non-Crystalline%20Solids%3C%5C%2Fi%3E%20%3Cb%3E2019%3C%5C%2Fb%3E%2C%20%3Ci%3E521%3C%5C%2Fi%3E%2C%20119526.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jnoncrysol.2019.119526%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jnoncrysol.2019.119526%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Structure%20and%20photoelastic%20constant%20of%20binary%20ns2-type%20metal%20cation%20containing%20silicate%20glasses%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Akira%22%2C%22lastName%22%3A%22Saitoh%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Suguru%22%2C%22lastName%22%3A%22Kitani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hitoshi%22%2C%22lastName%22%3A%22Kawaji%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiromichi%22%2C%22lastName%22%3A%22Takebe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%20photoelastic%20constant%20of%20nominal%20molar%20compositions%20RO%28R%272O3%29%5Cu2013SiO2%20%28R%5Cu202f%3D%5Cu202fPb%2C%20R%27%5Cu202f%3D%5Cu202fSb%2C%20Bi%29%20decreases%20with%20increasing%20RO%20and%20R%272O3%2C%20which%20is%20in%20agreement%20with%20calculations%20based%20on%20the%20quantitative%20structural%20information%20of%20silicate%20tetrahedra%20determined%20by%2029Si%20MAS-NMR.%20Compositional%20dependence%20of%20the%20photoelastic%20property%20is%20attributed%20to%20the%20electronic%20polarizabilities%20of%20the%20constituent%20ions.%20To%20understand%20the%20relationship%20between%20the%20structure%20and%20photoelastic%20response%2C%20the%20reported%20electronic%20polarizability%20is%20modified%20to%20match%20the%20value%20that%20includes%20the%20observed%20density%20and%20refractive%20index%20based%20on%20Lorentz%5Cu2013Lorenz%20eq.%20A%20composition%20of%20photoelastic%20glass%20with%20zero%20photoelastic%20constant%20is%20identified%20by%20an%20empirical%20equation%20that%20provides%20the%20ratio%20of%20the%20metal%5Cu2011oxygen%20bond%20length%20to%20the%20coordination%20number.%20Our%20finding%20is%20that%20the%20compositional%20response%20in%20the%20photoelastic%20constant%20is%20due%20to%20the%20variation%20in%20the%20electronic%20polarizability%2C%20despite%20the%20different%20ns2-type%20metal%20cations%20incorporated%20in%20the%20silicate%20glass.%22%2C%22date%22%3A%22October%201%2C%202019%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jnoncrysol.2019.119526%22%2C%22ISSN%22%3A%220022-3093%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS0022309319303977%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A21%3A25Z%22%7D%7D%2C%7B%22key%22%3A%22TC6WZEKX%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kitano%20et%20al.%22%2C%22parsedDate%22%3A%222019-12-26%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EKitano%2C%20M.%3B%20Kujirai%2C%20J.%3B%20Ogasawara%2C%20K.%3B%20Matsuishi%2C%20S.%3B%20Tada%2C%20T.%3B%20Abe%2C%20H.%3B%20Niwa%2C%20Y.%3B%20Hosono%2C%20H.%20Low-Temperature%20Synthesis%20of%20Perovskite%20Oxynitride-Hydrides%20as%20Ammonia%20Synthesis%20Catalysts.%20%3Ci%3EJ.%20Am.%20Chem.%20Soc.%3C%5C%2Fi%3E%20%3Cb%3E2019%3C%5C%2Fb%3E%2C%20%3Ci%3E141%3C%5C%2Fi%3E%20%2851%29%2C%2020344%26%23x2013%3B20353.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fjacs.9b10726%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fjacs.9b10726%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Low-Temperature%20Synthesis%20of%20Perovskite%20Oxynitride-Hydrides%20as%20Ammonia%20Synthesis%20Catalysts%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masaaki%22%2C%22lastName%22%3A%22Kitano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jun%22%2C%22lastName%22%3A%22Kujirai%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kiya%22%2C%22lastName%22%3A%22Ogasawara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomofumi%22%2C%22lastName%22%3A%22Tada%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hitoshi%22%2C%22lastName%22%3A%22Abe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yasuhiro%22%2C%22lastName%22%3A%22Niwa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Mixed%20anionic%20materials%20such%20as%20oxyhydrides%20and%20oxynitrides%20have%20recently%20attracted%20significant%20attention%20due%20to%20their%20unique%20properties%2C%20such%20as%20fast%20hydride%20ion%20conduction%2C%20enhanced%20ferroelectrics%2C%20and%20catalytic%20activity.%20However%2C%20high%20temperature%20%28%5Cu2265800%20%5Cu00b0C%29%20and%5C%2For%20complicated%20processes%20are%20required%20for%20the%20synthesis%20of%20these%20compounds.%20Here%20we%20report%20that%20a%20novel%20perovskite%20oxynitride-hydride%2C%20BaCeO3%5Cu2013xNyHz%2C%20can%20be%20directly%20synthesized%20by%20the%20reaction%20of%20CeO2%20with%20Ba%28NH2%292%20at%20low%20temperatures%20%28300%5Cu2013600%20%5Cu00b0C%29.%20BaCeO3%5Cu2013xNyHz%2C%20with%20and%20without%20transition%20metal%20nanoparticles%2C%20functions%20as%20an%20efficient%20catalyst%20for%20ammonia%20synthesis%20through%20the%20lattice%20N3%5Cu2013%20and%20H%5Cu2013%20ion-mediated%20Mars%5Cu2013van%20Krevelen%20mechanism%2C%20while%20ammonia%20synthesis%20occurs%20over%20conventional%20catalysts%20through%20a%20Langmuir%5Cu2013Hinshelwood%20mechanism%20with%20high%20energy%20barriers%20%2885%5Cu2013121%20kJ%20mol%5Cu20131%29.%20As%20a%20consequence%2C%20the%20unique%20reaction%20mechanism%20leads%20to%20enhancement%20of%20the%20activity%20of%20BaCeO3-based%20catalysts%20by%20a%20factor%20of%208%5Cu2013218%20and%20lowers%20the%20activation%20energy%20%2846%5Cu201362%20kJ%20mol%5Cu20131%29%20for%20ammonia%20synthesis.%20Furthermore%2C%20isotopic%20experiments%20reveal%20that%20this%20catalyst%20shifts%20the%20rate-determining%20step%20for%20ammonia%20synthesis%20from%20N2%20dissociation%20to%20N%5Cu2013H%20bond%20formation.%22%2C%22date%22%3A%222019-12-26%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Fjacs.9b10726%22%2C%22ISSN%22%3A%220002-7863%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fjacs.9b10726%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A21%3A30Z%22%7D%7D%5D%7D
(1)
Hanzawa, K.; Yamaguchi, Y.; Obata, Y.; Matsuishi, S.; Hiramatsu, H.; Kamiya, T.; Hosono, H. Insulator-like Behavior Coexisting with Metallic Electronic Structure in Strained FeSe Thin Films Grown by Molecular Beam Epitaxy. Phys. Rev. B 2019, 99 (3), 035148. https://doi.org/10.1103/PhysRevB.99.035148.
(1)
Wu, T.; Ishikawa, A.; Honda, T.; Tamatsukuri, H.; Ikeda, K.; Otomo, T.; Matsuishi, S. Nephelauxetic Effect of the Hydride Ligand in Sr2LiSiO4H as a Host Material for Rare-Earth-Activated Phosphors. RSC Adv. 2019, 9 (10), 5282–5287. https://doi.org/10.1039/C8RA08344D.
(1)
Obata, Y.; Kohama, Y.; Matsuishi, S.; Hosono, H. Shubnikov--de Haas Oscillations in the Three-Dimensional Dirac Fermion System Ca3PbO. Phys. Rev. B 2019, 99 (11), 115133. https://doi.org/10.1103/PhysRevB.99.115133.
(1)
Takeuchi, M.; Fujiwara, N.; Kuwayama, T.; Nakagawa, S.; Iimura, S.; Matsuishi, S.; Yamakawa, Y.; Kontani, H.; Hosono, H. Pressure-Induced Quantum Critical Point in the Heavily Hydrogen-Doped Iron-Based Superconductor LaFeAsO. Phys. Rev. B 2019, 99 (17), 174517. https://doi.org/10.1103/PhysRevB.99.174517.
(1)
Fujiwara, N.; Takeuchi, M.; Kuwayama, T.; Nakagawa, S.; Iimura, S.; Matsuishi, S.; Hosono, H. Nuclear Magnetic Resonance on LaFeAsO0.4H0.6 at 3.7 GPa. Papers in Physics 2019, 11, 110002–110002. https://doi.org/10.4279/pip.110002.
(1)
Yamaura, J.; Hiraka, H.; Iimura, S.; Muraba, Y.; Bang, J.; Ikeuchi, K.; Nakamura, M.; Inamura, Y.; Honda, T.; Hiraishi, M.; Kojima, K. M.; Kadono, R.; Kuramoto, Y.; Murakami, Y.; Matsuishi, S.; Hosono, H. Quantum Dynamics of Hydrogen in the Iron-Based Superconductor LaFeAsO0.9D0.1 Measured with Inelastic Neutron Spectroscopy. Phys. Rev. B 2019, 99 (22), 220505. https://doi.org/10.1103/PhysRevB.99.220505.
(1)
Mizoguchi, H.; Matsuishi, S.; Park, S.-W.; Hosono, H. Hydrogen-Insertion-Induced Itinerant Ferromagnetism in Zr2CoH4.8 with Co Chains. J. Phys. Chem. C 2019, 123 (24), 14964–14968. https://doi.org/10.1021/acs.jpcc.9b03793.
(1)
Kojima, K. M.; Hiraishi, M.; Okabe, H.; Koda, A.; Kadono, R.; Ide, K.; Matsuishi, S.; Kumomi, H.; Kamiya, T.; Hosono, H. Electronic Structure of Interstitial Hydrogen in In-Ga-Zn-O Semiconductor Simulated by Muon. Appl. Phys. Lett. 2019, 115 (12), 122104. https://doi.org/10.1063/1.5117771.
(1)
Saitoh, A.; Kitani, S.; Matsuishi, S.; Kawaji, H.; Takebe, H.; Hosono, H. Structure and Photoelastic Constant of Binary Ns2-Type Metal Cation Containing Silicate Glasses. Journal of Non-Crystalline Solids 2019, 521, 119526. https://doi.org/10.1016/j.jnoncrysol.2019.119526.
(1)
Kitano, M.; Kujirai, J.; Ogasawara, K.; Matsuishi, S.; Tada, T.; Abe, H.; Niwa, Y.; Hosono, H. Low-Temperature Synthesis of Perovskite Oxynitride-Hydrides as Ammonia Synthesis Catalysts. J. Am. Chem. Soc. 2019, 141 (51), 20344–20353. https://doi.org/10.1021/jacs.9b10726.
244926
P5622579
2018
items
1
american-chemical-society-with-titles-sentence-case-doi
0
date
asc
year
6
https://www.mces.titech.ac.jp/authors/matsuishi/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-9b103093798fe572ffc0c35c966c714f%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22RXJ6G39S%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Saitoh%20et%20al.%22%2C%22parsedDate%22%3A%222018-07-13%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ESaitoh%2C%20A.%3B%20Itadani%2C%20M.%3B%20Kitani%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Sasaki%2C%20M.%3B%20Kawaji%2C%20H.%3B%20Hosono%2C%20H.%3B%20Takebe%2C%20H.%20Characterization%20and%20Structure%20of%20a%20Fiber%20of%20BaO%26%23x2013%3BSnO%26%23x2013%3BP2O5%26%23x2013%3BB2O3%20Glass%20with%20a%20Very%20Small%20Photoelastic%20Constant.%20%3Ci%3EJpn.%20J.%20Appl.%20Phys.%3C%5C%2Fi%3E%20%3Cb%3E2018%3C%5C%2Fb%3E%2C%20%3Ci%3E57%3C%5C%2Fi%3E%20%288%29%2C%20080310.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.7567%5C%2FJJAP.57.080310%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.7567%5C%2FJJAP.57.080310%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Characterization%20and%20structure%20of%20a%20fiber%20of%20BaO%5Cu2013SnO%5Cu2013P2O5%5Cu2013B2O3%20glass%20with%20a%20very%20small%20photoelastic%20constant%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Akira%22%2C%22lastName%22%3A%22Saitoh%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masayuki%22%2C%22lastName%22%3A%22Itadani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Suguru%22%2C%22lastName%22%3A%22Kitani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masaru%22%2C%22lastName%22%3A%22Sasaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hitoshi%22%2C%22lastName%22%3A%22Kawaji%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiromichi%22%2C%22lastName%22%3A%22Takebe%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222018-07-13%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.7567%5C%2FJJAP.57.080310%22%2C%22ISSN%22%3A%221347-4065%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fiopscience.iop.org%5C%2Farticle%5C%2F10.7567%5C%2FJJAP.57.080310%5C%2Fmeta%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A28%3A32Z%22%7D%7D%2C%7B%22key%22%3A%225LLY6R3F%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hiraishi%20et%20al.%22%2C%22parsedDate%22%3A%222018-07-17%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHiraishi%2C%20M.%3B%20Kojima%2C%20K.%20M.%3B%20Yamauchi%2C%20I.%3B%20Okabe%2C%20H.%3B%20Takeshita%2C%20S.%3B%20Koda%2C%20A.%3B%20Kadono%2C%20R.%3B%20Zhang%2C%20X.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Hirata%2C%20K.%3B%20Otani%2C%20S.%3B%20Ohashi%2C%20N.%20Electronic%20Correlation%20in%20the%20Quasi-Two-Dimensional%20Electride%20Y2C.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2018%3C%5C%2Fb%3E%2C%20%3Ci%3E98%3C%5C%2Fi%3E%20%284%29%2C%20041104.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.98.041104%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.98.041104%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Electronic%20correlation%20in%20the%20quasi-two-dimensional%20electride%20Y2C%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Hiraishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%20M.%22%2C%22lastName%22%3A%22Kojima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22I.%22%2C%22lastName%22%3A%22Yamauchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Okabe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Takeshita%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Koda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Kadono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22X.%22%2C%22lastName%22%3A%22Zhang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Hirata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Otani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Ohashi%22%7D%5D%2C%22abstractNote%22%3A%22The%20magnetic%20properties%20of%20the%20electride%20compound%20Y2C%20were%20investigated%20by%20muon%20spin%20rotation%20and%20magnetic%20susceptibility%20on%20two%20samples%20with%20different%20forms%20%28polycrystalline%20and%20single%20crystalline%29%2C%20to%20examine%20the%20theoretically%20predicted%20Stoner%20ferromagnetism%20for%20electride%20bands.%20There%20was%20no%20evidence%20of%20static%20magnetic%20order%20in%20both%20samples%20even%20at%20temperatures%20down%20to%200.024%20K.%20For%20the%20polycrystalline%20sample%2C%20the%20presence%20of%20a%20paramagnetic%20moment%20at%20the%20Y%20sites%20was%20inferred%20from%20the%20Curie-Weiss%20behavior%20of%20the%20muon%20Knight%20shift%20and%20susceptibility%2C%20whereas%20no%20such%20tendency%20was%20observed%20in%20the%20single-crystalline%20sample.%20These%20observations%20suggest%20that%20the%20electronic%20ground%20state%20of%20Y2C%20is%20at%20the%20limit%20between%20weak-to-strong%20electronic%20correlation%2C%20where%20on-site%20Coulomb%20repulsion%20is%20sensitive%20to%20a%20local%20modulation%20of%20the%20electronic%20state%20or%20a%20shift%20in%20the%20Fermi%20level%20due%20to%20the%20presence%20of%20defects%20and%5C%2For%20impurities.%22%2C%22date%22%3A%22July%2017%2C%202018%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.98.041104%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.98.041104%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A55%3A07Z%22%7D%7D%2C%7B%22key%22%3A%224QNZI954%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Ueda%20et%20al.%22%2C%22parsedDate%22%3A%222018-07-19%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EUeda%2C%20J.%3B%20Matsuishi%2C%20S.%3B%20Tokunaga%2C%20T.%3B%20Tanabe%2C%20S.%20Preparation%2C%20Electronic%20Structure%20of%20Gadolinium%20Oxyhydride%20and%20Low-Energy%205d%20Excitation%20Band%20for%20Green%20Luminescence%20of%20Doped%20Tb%3Csub%3E3%2B%3C%5C%2Fsub%3E%20Ions.%20%3Ci%3EJ.%20Mater.%20Chem.%20C%3C%5C%2Fi%3E%20%3Cb%3E2018%3C%5C%2Fb%3E%2C%20%3Ci%3E6%3C%5C%2Fi%3E%20%2828%29%2C%207541%26%23x2013%3B7548.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FC8TC01682H%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FC8TC01682H%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Preparation%2C%20electronic%20structure%20of%20gadolinium%20oxyhydride%20and%20low-energy%205d%20excitation%20band%20for%20green%20luminescence%20of%20doped%20Tb%3Csub%3E3%2B%3C%5C%2Fsub%3E%20ions%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jumpei%22%2C%22lastName%22%3A%22Ueda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takayuki%22%2C%22lastName%22%3A%22Tokunaga%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Setsuhisa%22%2C%22lastName%22%3A%22Tanabe%22%7D%5D%2C%22abstractNote%22%3A%22Oxyhydride%20compounds%20of%20GdHO%20and%20GdHO%3ATb3%2B%20were%20successfully%20prepared%20by%20solid%20state%20reaction%20of%20GdH3%2C%20Gd2O3%20and%20Gd2O3%3ATb3%2B%20under%20a%20H2%20atmosphere.%20XRD%20analysis%20suggests%20that%20GdHO%20has%20a%20cubic%20fluorite%20structure%20%28space%20group%20Fmm%2C%20lattice%20parameter%20a%20%3D%205.38450%284%29%20%5Cu00c5%20for%20GdHO%20and%205.38523%286%29%20%5Cu00c5%20for%20GdHO%3ATb%29%2C%20which%20is%20different%20from%20the%20tetragonal%20fluorite-like%20superstructure%20for%20previously%20reported%20LnHO%20%28Ln%20%3D%20La%2C%20Ce%2C%20Pr%20and%20Nd%29%20%28space%20group%20P4%5C%2Fnmm%29%20materials.%20The%20prepared%20GdHO%3ATb3%2B%20shows%20photoluminescence%20bands%20in%20the%20range%20between%20470%20and%20650%20nm%2C%20which%20are%20attributed%20to%20Tb3%2B%3A5D4%20%5Cu2192%207FJ%20transitions.%20In%20the%20photoluminescence%20excitation%20spectrum%2C%20a%20broad%204f%5Cu20135d%20band%20of%20Tb3%2B%20was%20clearly%20observed%20at%20around%20310%20nm%2C%20which%20is%20one%20of%20the%20lowest%205d%20energy%20positions%20compared%20with%20other%20Tb3%2B-doped%20compounds.%20This%20shift%20may%20be%20caused%20by%20partially%20coordinated%20hydride%20ions%20with%20strong%20covalency%20around%20Tb3%2B%2C%20which%20cause%20a%20large%20nephelauxetic%20effect%20and%20crystal%20field%20splitting.%20The%20lifetime%20of%20Tb3%2B%3A5D4%20is%20almost%20unchanged%20from%2083%20to%20500%20K%20and%20decreases%20above%20500%20K.%20The%20thermal%20luminescence%20quenching%20of%20the%205D4%20%5Cu2192%207FJ%20transition%20is%20caused%20by%20a%20thermally%20activated%20crossover%20to%20the%20ground%20state%20through%20the%205d%20energy%20state.%20The%20band%20gap%20energy%20of%20GdHO%20%285.39%20eV%29%20was%20smaller%20than%20that%20of%20cubic%20and%20monoclinic%20Gd2O3%20%285.93%20and%206.10%20eV%2C%20respectively%29.%20Based%20on%20the%20constructed%20vacuum%20referred%20binding%20energy%20diagram%20and%20DFT%20calculation%2C%20the%20top%20of%20the%20valence%20band%20%28VB%29%20energy%20of%20GdHO%20is%20much%20higher%20than%20that%20of%20cubic%20and%20monoclinic%20Gd2O3%20due%20to%20the%20higher%20energy%20level%20of%20the%20hydride%201s%20orbital%20than%20that%20of%20the%20oxide%202p%20orbital.%22%2C%22date%22%3A%222018-07-19%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1039%5C%2FC8TC01682H%22%2C%22ISSN%22%3A%222050-7534%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fpubs.rsc.org%5C%2Fen%5C%2Fcontent%5C%2Farticlelanding%5C%2F2018%5C%2Ftc%5C%2Fc8tc01682h%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222018-10-24T05%3A28%3A30Z%22%7D%7D%2C%7B%22key%22%3A%22KPLDHTLD%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hasegawa%20et%20al.%22%2C%22parsedDate%22%3A%222018-07-24%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHasegawa%2C%20G.%3B%20Moriya%2C%20S.%3B%20Inada%2C%20M.%3B%20Kitano%2C%20M.%3B%20Okunaka%2C%20M.%3B%20Yamamoto%2C%20T.%3B%20Matsukawa%2C%20Y.%3B%20Nishimi%2C%20K.%3B%20Shima%2C%20K.%3B%20Enomoto%2C%20N.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Hayashi%2C%20K.%20Topotactic%20Synthesis%20of%20Mesoporous%2012CaO%26%23xB7%3B7Al%3Csub%3E2%3C%5C%2Fsub%3EO%3Csub%3E3%3C%5C%2Fsub%3E%20Mesocrystalline%20Microcubes%20toward%20Catalytic%20Ammonia%20Synthesis.%20%3Ci%3EChem.%20Mater.%3C%5C%2Fi%3E%20%3Cb%3E2018%3C%5C%2Fb%3E%2C%20%3Ci%3E30%3C%5C%2Fi%3E%20%2814%29%2C%204498%26%23x2013%3B4502.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.8b01819%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.8b01819%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Topotactic%20Synthesis%20of%20Mesoporous%2012CaO%5Cu00b77Al%3Csub%3E2%3C%5C%2Fsub%3EO%3Csub%3E3%3C%5C%2Fsub%3E%20Mesocrystalline%20Microcubes%20toward%20Catalytic%20Ammonia%20Synthesis%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22George%22%2C%22lastName%22%3A%22Hasegawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shizuka%22%2C%22lastName%22%3A%22Moriya%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Miki%22%2C%22lastName%22%3A%22Inada%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masaaki%22%2C%22lastName%22%3A%22Kitano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masaaki%22%2C%22lastName%22%3A%22Okunaka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takahisa%22%2C%22lastName%22%3A%22Yamamoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yuko%22%2C%22lastName%22%3A%22Matsukawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazuma%22%2C%22lastName%22%3A%22Nishimi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazunari%22%2C%22lastName%22%3A%22Shima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Naoya%22%2C%22lastName%22%3A%22Enomoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katsuro%22%2C%22lastName%22%3A%22Hayashi%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%22July%2024%2C%202018%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.chemmater.8b01819%22%2C%22ISSN%22%3A%220897-4756%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.8b01819%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222018-10-24T05%3A28%3A17Z%22%7D%7D%2C%7B%22key%22%3A%22MXWZTYBD%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hirayama%20et%20al.%22%2C%22parsedDate%22%3A%222018-09-12%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHirayama%2C%20M.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Murakami%2C%20S.%20Electrides%20as%20a%20New%20Platform%20of%20Topological%20Materials.%20%3Ci%3EPhys.%20Rev.%20X%3C%5C%2Fi%3E%20%3Cb%3E2018%3C%5C%2Fb%3E%2C%20%3Ci%3E8%3C%5C%2Fi%3E%20%283%29%2C%20031067.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevX.8.031067%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevX.8.031067%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Electrides%20as%20a%20New%20Platform%20of%20Topological%20Materials%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Motoaki%22%2C%22lastName%22%3A%22Hirayama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shuichi%22%2C%22lastName%22%3A%22Murakami%22%7D%5D%2C%22abstractNote%22%3A%22Recent%20discoveries%20of%20topological%20phases%20realized%20in%20electronic%20states%20in%20solids%20have%20revealed%20an%20important%20role%20of%20topology%2C%20which%20ubiquitously%20appears%20in%20various%20materials%20in%20nature.%20Many%20well-known%20materials%20have%20turned%20out%20to%20be%20topological%20materials%2C%20and%20this%20new%20viewpoint%20of%20topology%20has%20opened%20a%20new%20horizon%20in%20material%20science.%20In%20this%20paper%2C%20we%20find%20that%20electrides%20are%20suitable%20for%20achieving%20various%20topological%20phases%2C%20including%20topological%20insulating%20and%20topological%20semimetal%20phases.%20In%20the%20electrides%2C%20in%20which%20electrons%20serve%20as%20anions%2C%20the%20bands%20occupied%20by%20the%20anionic%20electrons%20lie%20near%20the%20Fermi%20level%2C%20because%20the%20anionic%20electrons%20are%20weakly%20bound%20by%20the%20lattice.%20This%20property%20of%20the%20electrides%20is%20favorable%20for%20achieving%20band%20inversions%20needed%20for%20topological%20phases%2C%20and%2C%20thus%2C%20the%20electrides%20are%20prone%20to%20topological%20phases.%20From%20such%20a%20point%20of%20view%2C%20we%20find%20many%20topological%20electrides%2C%20Y2C%20%5Bnodal-line%20semimetal%20%28NLS%29%5D%2C%20Sc2C%20%28insulator%20with%20a%20%5Cu03c0%20Zak%20phase%29%2C%20Sr2Bi%20%28NLS%29%2C%20HfBr%20%28quantum%20spin%20Hall%20system%29%2C%20and%20LaBr%20%28quantum%20anomalous%20Hall%20insulator%29%2C%20by%20using%20ab%20initio%20calculation.%20The%20close%20relationship%20between%20the%20electrides%20and%20the%20topological%20materials%20is%20useful%20in%20material%20science%20in%20both%20fields.%22%2C%22date%22%3A%22September%2012%2C%202018%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevX.8.031067%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevX.8.031067%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222020-04-21T06%3A12%3A57Z%22%7D%7D%2C%7B%22key%22%3A%222LUBRX3F%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Daicho%20et%20al.%22%2C%22parsedDate%22%3A%222018-09-17%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EDaicho%2C%20H.%3B%20Enomoto%2C%20K.%3B%20Sawa%2C%20H.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Improved%20Color%20Uniformity%20in%20White%20Light-Emitting%20Diodes%20Using%20Newly%20Developed%20Phosphors.%20%3Ci%3EOpt.%20Express%2C%20OE%3C%5C%2Fi%3E%20%3Cb%3E2018%3C%5C%2Fb%3E%2C%20%3Ci%3E26%3C%5C%2Fi%3E%20%2819%29%2C%2024784%26%23x2013%3B24791.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1364%5C%2FOE.26.024784%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1364%5C%2FOE.26.024784%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Improved%20color%20uniformity%20in%20white%20light-emitting%20diodes%20using%20newly%20developed%20phosphors%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hisayoshi%22%2C%22lastName%22%3A%22Daicho%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kiminori%22%2C%22lastName%22%3A%22Enomoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Sawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20novel%20white%20light-emitting%20diode%20%28WLED%29%20devices%20that%20improve%20emission%20color%20uniformity.%20The%20WLEDs%20consist%20of%20a%20violet%20chip%20and%20a%20mixed-phosphor%20layer%20of%20three%20phosphors%20previously%20developed%20by%20us.%20It%20is%20found%20that%20each%20phosphor%20does%20not%20reabsorb%20the%20luminescence%20from%20the%20other%20phosphors%3B%20consequently%2C%20the%20emission%20color%20of%20the%20WLEDs%20does%20not%20get%20affected%20by%20the%20mounted%20quantity%20of%20phosphors%20and%5C%2For%20the%20variation%20in%20chip%20emission%20wavelength.%20Furthermore%2C%20an%20encapsulated%20WLED%20with%20a%20hemispherical%20dome-shaped%20mixed-phosphor%20layer%20enables%20an%20area%20to%20be%20irradiated%20with%20uniform%20color%2C%20producing%20an%20excellent%20color%20rendering%20index%20and%20improved%20luminous%20flux%20because%20of%20the%20reduced%20inelastic%20scattering%20loss%20in%20the%20phosphor%20layer.%22%2C%22date%22%3A%222018%5C%2F09%5C%2F17%22%2C%22language%22%3A%22EN%22%2C%22DOI%22%3A%2210.1364%5C%2FOE.26.024784%22%2C%22ISSN%22%3A%221094-4087%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.osapublishing.org%5C%2Foe%5C%2Fabstract.cfm%3Furi%3Doe-26-19-24784%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A27%3A48Z%22%7D%7D%2C%7B%22key%22%3A%22ABJ7C2UW%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Muraba%20et%20al.%22%2C%22parsedDate%22%3A%222018-09-25%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMuraba%2C%20Y.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hiramatsu%2C%20H.%3B%20Honda%2C%20T.%3B%20Ikeda%2C%20K.%3B%20Otomo%2C%20T.%3B%20Hosono%2C%20H.%20Phase%20Transition%20in%20CaFeAsH%3A%20Bridging%201111%20and%20122%20Iron-Based%20Superconductors.%20%3Ci%3EDalton%20Trans.%3C%5C%2Fi%3E%20%3Cb%3E2018%3C%5C%2Fb%3E%2C%20%3Ci%3E47%3C%5C%2Fi%3E%20%2837%29%2C%2012964%26%23x2013%3B12971.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FC8DT02387E%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FC8DT02387E%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Phase%20transition%20in%20CaFeAsH%3A%20bridging%201111%20and%20122%20iron-based%20superconductors%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshinori%22%2C%22lastName%22%3A%22Muraba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hidenori%22%2C%22lastName%22%3A%22Hiramatsu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takashi%22%2C%22lastName%22%3A%22Honda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazutaka%22%2C%22lastName%22%3A%22Ikeda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshiya%22%2C%22lastName%22%3A%22Otomo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Iron-based%20superconductors%20can%20be%20categorized%20into%20two%20types%20of%20parent%20compounds%20by%20considering%20the%20nature%20of%20their%20temperature-induced%20phase%20transitions%3B%20namely%2C%20first%20order%20transitions%20for%20122-%20and%2011-type%20compounds%20and%20second-order%20transitions%20for%201111-type%20compounds.%20This%20work%20examines%20the%20structural%20and%20magnetic%20transitions%20%28ST%20and%20MT%29%20of%20CaFeAsH%20by%20specific%20heat%2C%20X-ray%20diffraction%2C%20neutron%20diffraction%2C%20and%20electrical%20resistivity%20measurements.%20Heat%20capacity%20measurements%20revealed%20a%20second-order%20phase%20transition%20that%20accompanies%20an%20apparent%20single%20peak%20at%2096%20K.%20However%2C%20a%20clear%20ST%20from%20the%20tetragonal%20to%20orthorhombic%20phase%20and%20an%20MT%20from%20the%20paramagnetic%20to%20the%20antiferromagnetic%20phase%20were%20detected.%20The%20structural%20%28Ts%29%20and%20N%5Cu00e9el%20temperatures%20%28TN%29%20were%20respectively%20determined%20to%20be%2095%282%29%20and%2096%20K%20by%20X-ray%20and%20neutron%20diffraction%20and%20resistivity%20measurements.%20This%20small%20temperature%20difference%2C%20Ts%20%5Cu2212%20TN%2C%20was%20attributed%20to%20strong%20magnetic%20coupling%20in%20the%20inter-layer%20direction%20owing%20to%20CaFeAsH%20having%20the%20shortest%20lattice%20constant%20c%20among%20parent%201111-type%20iron%20arsenides.%20Considering%20that%20a%20first-order%20transition%20takes%20place%20in%2011-%20and%20122-type%20compounds%20with%20a%20short%20inter-layer%20distance%2C%20we%20conclude%20that%20the%20nature%20of%20the%20ST%20and%20MT%20in%20CaFeAsH%20is%20intermediate%20in%20character%2C%20between%20the%20second-order%20transition%20for%201111-type%20compounds%20and%20the%20first-order%20transition%20for%20other%2011-%20and%20122-type%20compounds.%22%2C%22date%22%3A%222018-09-25%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1039%5C%2FC8DT02387E%22%2C%22ISSN%22%3A%221477-9234%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fpubs.rsc.org%5C%2Fen%5C%2Fcontent%5C%2Farticlelanding%5C%2F2018%5C%2Fdt%5C%2Fc8dt02387e%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A26%3A28Z%22%7D%7D%2C%7B%22key%22%3A%22RL7XEFSM%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Obata%20et%20al.%22%2C%22parsedDate%22%3A%222018-10-01%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EObata%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Flux%20Growth%20and%20Magneto-Transport%20Properties%20of%20Cubic%20Antiperovskite%20Ca%3Csub%3E3%3C%5C%2Fsub%3EPbO%20Single%20Crystals.%20%3Ci%3EMaterials%20Research%20Bulletin%3C%5C%2Fi%3E%20%3Cb%3E2018%3C%5C%2Fb%3E%2C%20%3Ci%3E106%3C%5C%2Fi%3E%2C%201%26%23x2013%3B6.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.materresbull.2018.05.020%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.materresbull.2018.05.020%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Flux%20growth%20and%20magneto-transport%20properties%20of%20cubic%20antiperovskite%20Ca%3Csub%3E3%3C%5C%2Fsub%3EPbO%20single%20crystals%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yukiko%22%2C%22lastName%22%3A%22Obata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20the%20single%20crystal%20growth%20of%20cubic%20antiperovskite%20Ca3PbO%20by%20a%20Ca-self-flux%20method.%20Cubic%20crystals%2C%201%5Cu202fmm%20in%20size%2C%20were%20successfully%20obtained%20through%20the%20use%20of%20iron%20crucibles%20sealed%20in%20stainless%20steel%20capsules.%20The%20crucible%20material%20and%20sealing%20method%20were%20found%20to%20be%20critical%20factors%20for%20achieving%20large%20crystals%20with%20low%20carrier%20density.%20The%20crystals%20were%20subsequently%20characterized%20by%20powder%20and%20single-crystal%20x-ray%20diffraction%20experiments%2C%20electron-probe%20microanalysis%2C%20and%20Hall%20effect%20measurements.%20Through%20the%20use%20of%20short%20stainless%20steel%20rods%20as%20tight%20caps%20for%20the%20crucible%20and%20fillers%20to%20occupy%20extra%20space%20in%20the%20capsule%2C%20the%20Ca%20evaporation%20loss%20of%20the%20flux%2C%20which%20contributes%20to%20Ca%20vacancy%20formation%2C%20was%20effectively%20reduced.%20Hence%2C%20the%20hole%20carrier%20density%20in%20the%20single%20crystal%20was%20reduced%20to%204.0%5Cu202f%5Cu00d7%5Cu202f1019%5Cu202fcm%5Cu22123.%20The%20crystal%20synthesized%20under%20optimized%20growth%20conditions%20showed%20clear%20Shubnikov-de%20Haas%20oscillations%2C%20indicating%20its%20high%20purity%20and%20homogeneity.%22%2C%22date%22%3A%22October%201%2C%202018%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.materresbull.2018.05.020%22%2C%22ISSN%22%3A%220025-5408%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS0025540817347001%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222018-10-24T05%3A29%3A00Z%22%7D%7D%2C%7B%22key%22%3A%22JC5GGFYV%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fujiwara%20et%20al.%22%2C%22parsedDate%22%3A%222018-10-01%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EFujiwara%2C%20N.%3B%20Takeuchi%2C%20M.%3B%20Kuwayama%2C%20T.%3B%20Nakagawa%2C%20S.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Pressure-Induced%20Quantum%20Critical%20Behavior%20in%20LaFeAsO1-XHx%20Studied%20via%20NMR.%20%3Ci%3EAIP%20Advances%3C%5C%2Fi%3E%20%3Cb%3E2018%3C%5C%2Fb%3E%2C%20%3Ci%3E8%3C%5C%2Fi%3E%20%2810%29%2C%20101331.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.5042482%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.5042482%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Pressure-induced%20quantum%20critical%20behavior%20in%20LaFeAsO1-xHx%20studied%20via%20NMR%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Naoki%22%2C%22lastName%22%3A%22Fujiwara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masayoshi%22%2C%22lastName%22%3A%22Takeuchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takanori%22%2C%22lastName%22%3A%22Kuwayama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoshi%22%2C%22lastName%22%3A%22Nakagawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22LaFeAsO1-xHx%20is%20a%20prototypical%20iron-based%20superconductor.%20However%2C%20its%20phase%20diagram%20presents%20unique%20properties%20compared%20to%20conventional%20iron-based%20superconductors%3A%20%281%29%20the%20superconducting%20phase%20is%20sandwiched%20between%20two%20antiferromagnetic%20%28AF%29%20phases%20appearing%20in%20lightly%20%28x%20%5Cu2264%200.05%29%20and%20heavily%20%280.49%20%5Cu2264%20x%29%20H-doped%20regimes.%20%282%29%20The%20AF%20phase%20%280.49%20%5Cu2264%20x%29%20is%20strongly%20suppressed%20when%20applying%20pressure.%20We%20measured%20the%20relaxation%20time%20T1%20at%2075As%20sites%20for%20x%3D0.6%20under%20pressures%20up%20to%203.7%20GPa%20to%20investigate%20the%20behavior%20near%20the%20quantum%20critical%20point%20%28QCP%29.%20The%20relaxation%20rate%20divided%20by%20temperature%20%28T%29%201%5C%2FT1T%20exhibited%20a%20peak%20at%20the%20AF%20transition%20temperature%20%28TN%29%20followed%20by%20Curie-Weiss%20behavior%20at%20low%20temperatures%20below%20TN..%20The%20result%20demonstrates%20that%20the%20gapped%20excitation%20originating%20from%20the%20spin-density-wave%20state%20and%20the%20gapless%20excitation%20characteristic%20to%20the%20QCP%20coexist%20near%20the%20pressure-induced%20QCP.%22%2C%22date%22%3A%22October%201%2C%202018%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F1.5042482%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Faip.scitation.org%5C%2Fdoi%5C%2F10.1063%5C%2F1.5042482%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A26%3A50Z%22%7D%7D%5D%7D
(1)
Saitoh, A.; Itadani, M.; Kitani, S.; Matsuishi, S.; Sasaki, M.; Kawaji, H.; Hosono, H.; Takebe, H. Characterization and Structure of a Fiber of BaO–SnO–P2O5–B2O3 Glass with a Very Small Photoelastic Constant. Jpn. J. Appl. Phys. 2018, 57 (8), 080310. https://doi.org/10.7567/JJAP.57.080310.
(1)
Hiraishi, M.; Kojima, K. M.; Yamauchi, I.; Okabe, H.; Takeshita, S.; Koda, A.; Kadono, R.; Zhang, X.; Matsuishi, S.; Hosono, H.; Hirata, K.; Otani, S.; Ohashi, N. Electronic Correlation in the Quasi-Two-Dimensional Electride Y2C. Phys. Rev. B 2018, 98 (4), 041104. https://doi.org/10.1103/PhysRevB.98.041104.
(1)
Ueda, J.; Matsuishi, S.; Tokunaga, T.; Tanabe, S. Preparation, Electronic Structure of Gadolinium Oxyhydride and Low-Energy 5d Excitation Band for Green Luminescence of Doped Tb3+ Ions. J. Mater. Chem. C 2018, 6 (28), 7541–7548. https://doi.org/10.1039/C8TC01682H.
(1)
Hasegawa, G.; Moriya, S.; Inada, M.; Kitano, M.; Okunaka, M.; Yamamoto, T.; Matsukawa, Y.; Nishimi, K.; Shima, K.; Enomoto, N.; Matsuishi, S.; Hosono, H.; Hayashi, K. Topotactic Synthesis of Mesoporous 12CaO·7Al2O3 Mesocrystalline Microcubes toward Catalytic Ammonia Synthesis. Chem. Mater. 2018, 30 (14), 4498–4502. https://doi.org/10.1021/acs.chemmater.8b01819.
(1)
Hirayama, M.; Matsuishi, S.; Hosono, H.; Murakami, S. Electrides as a New Platform of Topological Materials. Phys. Rev. X 2018, 8 (3), 031067. https://doi.org/10.1103/PhysRevX.8.031067.
(1)
Daicho, H.; Enomoto, K.; Sawa, H.; Matsuishi, S.; Hosono, H. Improved Color Uniformity in White Light-Emitting Diodes Using Newly Developed Phosphors. Opt. Express, OE 2018, 26 (19), 24784–24791. https://doi.org/10.1364/OE.26.024784.
(1)
Muraba, Y.; Iimura, S.; Matsuishi, S.; Hiramatsu, H.; Honda, T.; Ikeda, K.; Otomo, T.; Hosono, H. Phase Transition in CaFeAsH: Bridging 1111 and 122 Iron-Based Superconductors. Dalton Trans. 2018, 47 (37), 12964–12971. https://doi.org/10.1039/C8DT02387E.
(1)
Obata, Y.; Matsuishi, S.; Hosono, H. Flux Growth and Magneto-Transport Properties of Cubic Antiperovskite Ca3PbO Single Crystals. Materials Research Bulletin 2018, 106, 1–6. https://doi.org/10.1016/j.materresbull.2018.05.020.
(1)
Fujiwara, N.; Takeuchi, M.; Kuwayama, T.; Nakagawa, S.; Iimura, S.; Matsuishi, S.; Hosono, H. Pressure-Induced Quantum Critical Behavior in LaFeAsO1-XHx Studied via NMR. AIP Advances 2018, 8 (10), 101331. https://doi.org/10.1063/1.5042482.
244926
P5622579
2017
items
1
american-chemical-society-with-titles-sentence-case-doi
0
date
asc
year
6
https://www.mces.titech.ac.jp/authors/matsuishi/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-f14b372de39dbd54369390209b241045%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22SUYIFYR3%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Mizoguchi%20et%20al.%22%2C%22parsedDate%22%3A%222017%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMizoguchi%2C%20H.%3B%20Muraba%2C%20Y.%3B%20Fredrickson%2C%20D.%20C.%3B%20Matsuishi%2C%20S.%3B%20Kamiya%2C%20T.%3B%20Hosono%2C%20H.%20The%20Unique%20Electronic%20Structure%20of%20Mg2Si%3A%20Shaping%20the%20Conduction%20Bands%20of%20Semiconductors%20with%20Multicenter%20Bonding.%20%3Ci%3EAngewandte%20Chemie%20International%20Edition%3C%5C%2Fi%3E%20%3Cb%3E2017%3C%5C%2Fb%3E%2C%20%3Ci%3E56%3C%5C%2Fi%3E%20%2834%29%2C%2010135%26%23x2013%3B10139.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fanie.201701681%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fanie.201701681%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22The%20Unique%20Electronic%20Structure%20of%20Mg2Si%3A%20Shaping%20the%20Conduction%20Bands%20of%20Semiconductors%20with%20Multicenter%20Bonding%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Mizoguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshinori%22%2C%22lastName%22%3A%22Muraba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniel%20C.%22%2C%22lastName%22%3A%22Fredrickson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshio%22%2C%22lastName%22%3A%22Kamiya%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%20electronic%20structures%20of%20the%20antifluorite-type%20compound%20Mg2Si%20is%20described%20in%20which%20a%20sublattice%20of%20short%20cation%5Cu2013cation%20contacts%20creates%20a%20very%20low%20conduction%20band%20minimum.%20Since%20Mg2Si%20shows%20n-type%20conductivity%20without%20intentional%20carrier%20doping%2C%20the%20present%20result%20indicates%20that%20the%20cage%20defined%20by%20the%20cations%20plays%20critical%20roles%20in%20carrier%20transport%20similar%20to%20those%20of%20inorganic%20electrides%2C%20such%20as%2012%20CaO%5Cu22c57%20Al2O3%3Ae%5Cu2212%20and%20Ca2N.%20A%20distinct%20difference%20in%20the%20location%20of%20conduction%20band%20minimum%20between%20Mg2Si%20and%20the%20isostructural%20phase%20Na2S%20is%20explained%20in%20terms%20of%20factors%20such%20as%20the%20differing%20interaction%20strengths%20of%20the%20Si%5C%2FS%203s%20orbitals%20with%20the%20cation%20levels%2C%20with%20the%20more%20core-like%20character%20of%20the%20S%203s%20leading%20to%20a%20relatively%20low%20conduction%20band%20energy%20at%20the%20%5Cu0393%20point.%20Based%20on%20these%20results%20and%20previous%20research%20on%20electrides%2C%20approaches%20can%20be%20devised%20to%20control%20the%20energy%20levels%20of%20cation%20sublattices%20in%20semiconductors.%22%2C%22date%22%3A%222017%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fanie.201701681%22%2C%22ISSN%22%3A%221521-3773%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fonlinelibrary.wiley.com%5C%2Fdoi%5C%2Fabs%5C%2F10.1002%5C%2Fanie.201701681%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A34%3A16Z%22%7D%7D%2C%7B%22key%22%3A%22HAECW8SA%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Iimura%20et%20al.%22%2C%22parsedDate%22%3A%222017-01-03%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EIimura%2C%20S.%3B%20Tomota%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Masuda%2C%20R.%3B%20Seto%2C%20M.%3B%20Hiraka%2C%20H.%3B%20Ikeda%2C%20K.%3B%20Otomo%2C%20T.%3B%20Hosono%2C%20H.%20Ferrimagnetic%20Cage%20Framework%20in%20Ca12Fe10Si4O32Cl6.%20%3Ci%3EInorg.%20Chem.%3C%5C%2Fi%3E%20%3Cb%3E2017%3C%5C%2Fb%3E%2C%20%3Ci%3E56%3C%5C%2Fi%3E%20%281%29%2C%20566%26%23x2013%3B572.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.6b02404%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.6b02404%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ferrimagnetic%20Cage%20Framework%20in%20Ca12Fe10Si4O32Cl6%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yudai%22%2C%22lastName%22%3A%22Tomota%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ryo%22%2C%22lastName%22%3A%22Masuda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Makoto%22%2C%22lastName%22%3A%22Seto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Haruhiro%22%2C%22lastName%22%3A%22Hiraka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazutaka%22%2C%22lastName%22%3A%22Ikeda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshiya%22%2C%22lastName%22%3A%22Otomo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%20positively%20charged%20cage%20framework%20of%20the%20natural%20mineral%20mayenite%2C%20which%20enables%20various%20species%20with%20negative%20charge%20to%20be%20stabilized%2C%20is%20one%20of%20the%20key%20structures%20to%20provide%20the%20new%20functionalities%20exploited%20in%20applications.%20Here%20we%20report%20the%20structural%20and%20magnetic%20properties%20of%20recently%20found%20eltyubyuite%2C%20Ca12Fe10Si4O32Cl6%2C%20which%20is%20the%20first%20compound%20bearing%20a%20transition%20metal%20oxide%20as%20a%20main%20constituent%20in%20the%20mayenite-type%20structure.%20From%20neutron%20powder%20diffraction%20measurements%20at%20T%20%3D%2020%20K%20and%20the%20low%20temperature%20M%5Cu00f6ssbauer%20measurement%2C%20we%20determined%20the%20magnetic%20structure%20of%20eltyubyuite%20to%20be%20a%20ferrimagnet%20with%20oppositely%20aligned%20magnetic%20moments%20of%20%2B3.17%283%29%20and%20%5Cu22123.05%288%29%20%5Cu03bcB%20in%20two%20tetrahedral%20Fe%20sites%20with%20different%20oxygen%20ligands%2C%20all%20bridging%20oxygens%20or%20mixed%20bridging%20and%20nonbridging%20oxygens.%20As%20far%20as%20is%20known%2C%20this%20result%20is%20likely%20to%20be%20a%20first%20example%20showing%20ferrimagnetism%20stemming%20from%20only%20tetrahedral%20Fe3%2B%20ions.%20The%20reduced%20magnetic%20moment%20per%20Fe3%2B%20and%20the%20resultant%20small%20net%20moment%20per%20unit%20cell%20of%2022%20%5Cu03bcB%20at%20%5Cu03bc0H%20%3D%205%20T%20and%20T%20%3D%2015%20K%20are%20attributed%20to%20strong%20covalency%20in%20much%20shorter%20Fe%5Cu2013O%20bonds%20in%20the%20FeO4%20tetrahedra.%22%2C%22date%22%3A%222017-01-03%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.inorgchem.6b02404%22%2C%22ISSN%22%3A%220020-1669%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.6b02404%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A35%3A33Z%22%7D%7D%2C%7B%22key%22%3A%22Q8IIVM3X%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Nakamura%20et%20al.%22%2C%22parsedDate%22%3A%222017-02-02%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ENakamura%2C%20A.%3B%20Shimojima%2C%20T.%3B%20Sonobe%2C%20T.%3B%20Yoshida%2C%20S.%3B%20Ishizaka%2C%20K.%3B%20Malaeb%2C%20W.%3B%20Shin%2C%20S.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Multiple-Pseudogap%20Phases%20in%20the%20Hydrogen-Doped%20LaFeAsO%20System.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2017%3C%5C%2Fb%3E%2C%20%3Ci%3E95%3C%5C%2Fi%3E%20%286%29%2C%20064501.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.95.064501%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.95.064501%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Multiple-pseudogap%20phases%20in%20the%20hydrogen-doped%20LaFeAsO%20system%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Nakamura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Shimojima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Sonobe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Yoshida%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Ishizaka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22W.%22%2C%22lastName%22%3A%22Malaeb%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Shin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%20low-energy%20electronic%20structure%20of%20LaFeAsO1%5Cu2212xHx%20%280.0%5Cu2264x%5Cu22640.60%29%2C%20a%20system%20which%20exhibits%20two%20superconducting%20domes%20and%20antiferromagnetic%20orders%20in%20its%20phase%20diagram%2C%20is%20investigated%20by%20utilizing%20laser%20photoemission%20spectroscopy.%20From%20the%20precise%20temperature-dependent%20measurement%20of%20the%20spectra%20near%20the%20Fermi%20level%2C%20we%20find%20a%20suppression%20of%20the%20density%20of%20states%20with%20cooling%2C%20namely%20a%20pseudogap%20formation%2C%20for%20all%20doping%20range.%20The%20pseudogap%20gets%20suppressed%20on%20doping%20through%20the%20first%20superconducting%20dome%20regime%20to%20the%20higher-x%20region%2C%20whereas%20it%20tends%20to%20recover%20when%20further%20increasing%20x%20toward%20the%20second%20antiferromagnetic%20ordered%20phase.%20The%20systematic%20doping%20dependence%20indicates%20the%20different%20origins%20of%20pseudogaps%20in%20the%20low-%20and%20high-x%20regions%2C%20possibly%20related%20to%20the%20respective%20antiferromagnetic%20ground%20states%20residing%20at%20both%20ends%20of%20the%20phase%20diagram.%22%2C%22date%22%3A%22February%202%2C%202017%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.95.064501%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.95.064501%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A35%3A03Z%22%7D%7D%2C%7B%22key%22%3A%22GQT9QTCG%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Tang%20et%20al.%22%2C%22parsedDate%22%3A%222017-05-02%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ETang%2C%20H.%3B%20Kishida%2C%20Y.%3B%20Ide%2C%20K.%3B%20Toda%2C%20Y.%3B%20Hiramatsu%2C%20H.%3B%20Matsuishi%2C%20S.%3B%20Ueda%2C%20S.%3B%20Ohashi%2C%20N.%3B%20Kumomi%2C%20H.%3B%20Hosono%2C%20H.%3B%20Kamiya%2C%20T.%20Multiple%20Roles%20of%20Hydrogen%20Treatments%20in%20Amorphous%20In%26%23x2013%3BGa%26%23x2013%3BZn%26%23x2013%3BO%20Films.%20%3Ci%3EECS%20J.%20Solid%20State%20Sci.%20Technol.%3C%5C%2Fi%3E%20%3Cb%3E2017%3C%5C%2Fb%3E%2C%20%3Ci%3E6%3C%5C%2Fi%3E%20%287%29%2C%20P365.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1149%5C%2F2.0071707jss%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1149%5C%2F2.0071707jss%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Multiple%20Roles%20of%20Hydrogen%20Treatments%20in%20Amorphous%20In%5Cu2013Ga%5Cu2013Zn%5Cu2013O%20Films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Haochun%22%2C%22lastName%22%3A%22Tang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yosuke%22%2C%22lastName%22%3A%22Kishida%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Keisuke%22%2C%22lastName%22%3A%22Ide%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshitake%22%2C%22lastName%22%3A%22Toda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hidenori%22%2C%22lastName%22%3A%22Hiramatsu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shigenori%22%2C%22lastName%22%3A%22Ueda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Naoki%22%2C%22lastName%22%3A%22Ohashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideya%22%2C%22lastName%22%3A%22Kumomi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshio%22%2C%22lastName%22%3A%22Kamiya%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222017-05-02%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1149%5C%2F2.0071707jss%22%2C%22ISSN%22%3A%222162-8777%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fiopscience.iop.org%5C%2Farticle%5C%2F10.1149%5C%2F2.0071707jss%5C%2Fmeta%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A36%3A06Z%22%7D%7D%2C%7B%22key%22%3A%22HEVYC7G6%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Iimura%20et%20al.%22%2C%22parsedDate%22%3A%222017-05-30%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EIimura%2C%20S.%3B%20Okanishi%2C%20H.%3B%20Matsuishi%2C%20S.%3B%20Hiraka%2C%20H.%3B%20Honda%2C%20T.%3B%20Ikeda%2C%20K.%3B%20Hansen%2C%20T.%20C.%3B%20Otomo%2C%20T.%3B%20Hosono%2C%20H.%20Large-Moment%20Antiferromagnetic%20Order%20in%20Overdoped%20High-%20%3Ci%3ET%3C%5C%2Fi%3E%20%3Csub%3Ec%3C%5C%2Fsub%3E%20Superconductor%20%3Csup%3E154%3C%5C%2Fsup%3E%20SmFeAsO%20%3Csub%3E%201%26%23x2212%3B%20%3Ci%3Ex%3C%5C%2Fi%3E%20%3C%5C%2Fsub%3E%20D%20%3Csub%3E%20%3Ci%3Ex%3C%5C%2Fi%3E%20%3C%5C%2Fsub%3E.%20%3Ci%3EProc.%20Natl.%20Acad.%20Sci.%20U.S.A.%3C%5C%2Fi%3E%20%3Cb%3E2017%3C%5C%2Fb%3E%2C%20%3Ci%3E114%3C%5C%2Fi%3E%20%2822%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1073%5C%2Fpnas.1703295114%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1073%5C%2Fpnas.1703295114%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Large-moment%20antiferromagnetic%20order%20in%20overdoped%20high-%20%3Ci%3ET%3C%5C%2Fi%3E%20%3Csub%3Ec%3C%5C%2Fsub%3E%20superconductor%20%3Csup%3E154%3C%5C%2Fsup%3E%20SmFeAsO%20%3Csub%3E%201%5Cu2212%20%3Ci%3Ex%3C%5C%2Fi%3E%20%3C%5C%2Fsub%3E%20D%20%3Csub%3E%20%3Ci%3Ex%3C%5C%2Fi%3E%20%3C%5C%2Fsub%3E%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Okanishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Haruhiro%22%2C%22lastName%22%3A%22Hiraka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takashi%22%2C%22lastName%22%3A%22Honda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazutaka%22%2C%22lastName%22%3A%22Ikeda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%20C.%22%2C%22lastName%22%3A%22Hansen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshiya%22%2C%22lastName%22%3A%22Otomo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Significance%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20Using%20neutron%20powder%20diffraction%20measurements%20on%20the%20bulk%20highest-%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20T%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20c%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20superconductor%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20154%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20SmFeAsO%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%201%5Cu2212%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20x%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20D%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20x%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%2C%20we%20discovered%20a%20new%20antiferromagnetic%20%28AFM%29%20phase%20in%20the%20electron-overdoped%20regime%2C%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20x%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cu2265%200.56%20%28AFM2%29.%20The%20magnetic%20moment%20on%20Fe%20in%20AFM2%20reaches%202.73%20%5Cu03bc%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20B%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5C%2FFe%2C%20which%20is%20the%20largest%20in%20all%20the%20nondoped%20iron-based%20antiferromagnets%20reported%20so%20far.%20Our%20theoretical%20calculations%20reveal%20that%20the%20AFM2%20phase%20in%20SmFeAsO%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%201%5Cu2212%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20x%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20H%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20x%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20originates%20in%20the%20kinetic%20frustration%20of%20the%20Fe-3%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20d%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20xy%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20orbital%2C%20in%20which%20the%20Fe-3%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20d%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20xy%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20nearest-neighbor%20hopping%20parameter%20becomes%20zero.%20The%20unique%20phase%20diagram%2C%20i.e.%2C%20the%20highest-%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20T%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20c%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20superconducting%20phase%20adjacent%20to%20the%20strongly%20electron-correlated%20phase%20in%20heavily%20electron-doped%20regime%20%28not%20nondoped%20regime%29%2C%20yields%20important%20clues%20to%20the%20unconventional%20origins%20of%20superconductivity.%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%2C%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20In%20iron-based%20superconductors%2C%20high%20critical%20temperature%20%28%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20T%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20c%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%29%20superconductivity%20over%2050%20K%20has%20only%20been%20accomplished%20in%20electron-doped%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20hRE%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20FeAsO%20%28%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20hRE%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20is%20heavy%20rare%20earth%20%28%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20RE%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%29%20element%29.%20Although%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20hRE%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20FeAsO%20has%20the%20highest%20bulk%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20T%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20c%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%2858%20K%29%2C%20progress%20in%20understanding%20its%20physical%20properties%20has%20been%20relatively%20slow%20due%20to%20difficulties%20in%20achieving%20high-concentration%20electron%20doping%20and%20carrying%20out%20neutron%20experiments.%20Here%2C%20we%20present%20a%20systematic%20neutron%20powder%20diffraction%20study%20of%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20154%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20SmFeAsO%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%201%5Cu2212%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20x%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20D%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20x%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%2C%20and%20the%20discovery%20of%20a%20long-range%20antiferromagnetic%20ordering%20with%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20x%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cu2265%200.56%20%28AFM2%29%20accompanying%20a%20structural%20transition%20from%20tetragonal%20to%20orthorhombic.%20Surprisingly%2C%20the%20Fe%20magnetic%20moment%20in%20AFM2%20reaches%20a%20magnitude%20of%202.73%20%5Cu03bc%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20B%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5C%2FFe%2C%20which%20is%20the%20largest%20in%20all%20nondoped%20iron%20pnictides%20and%20chalcogenides.%20Theoretical%20calculations%20suggest%20that%20the%20AFM2%20phase%20originates%20in%20kinetic%20frustration%20of%20the%20Fe-3%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20d%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20%20xy%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20orbital%2C%20in%20which%20the%20nearest-neighbor%20hopping%20parameter%20becomes%20zero.%20The%20unique%20phase%20diagram%2C%20i.e.%2C%20highest-%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20T%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20c%5Cn%20%20%20%20%20%20%20%20%20%20%20%20%20%20superconducting%20phase%20adjacent%20to%20the%20strongly%20correlated%20phase%20in%20electron-overdoped%20regime%2C%20yields%20important%20clues%20to%20the%20unconventional%20origins%20of%20superconductivity.%22%2C%22date%22%3A%222017-05-30%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1073%5C%2Fpnas.1703295114%22%2C%22ISSN%22%3A%220027-8424%2C%201091-6490%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fpnas.org%5C%2Fdoi%5C%2Ffull%5C%2F10.1073%5C%2Fpnas.1703295114%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222023-09-06T07%3A23%3A03Z%22%7D%7D%2C%7B%22key%22%3A%22HUM458YR%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bang%20et%20al.%22%2C%22parsedDate%22%3A%222017-06-05%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EBang%2C%20J.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Hydrogen%20Anion%20and%20Subgap%20States%20in%20Amorphous%20In%26%23x2013%3BGa%26%23x2013%3BZn%26%23x2013%3BO%20Thin%20Films%20for%20TFT%20Applications.%20%3Ci%3EAppl.%20Phys.%20Lett.%3C%5C%2Fi%3E%20%3Cb%3E2017%3C%5C%2Fb%3E%2C%20%3Ci%3E110%3C%5C%2Fi%3E%20%2823%29%2C%20232105.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4985627%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4985627%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Hydrogen%20anion%20and%20subgap%20states%20in%20amorphous%20In%5Cu2013Ga%5Cu2013Zn%5Cu2013O%20thin%20films%20for%20TFT%20applications%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joonho%22%2C%22lastName%22%3A%22Bang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%22June%205%2C%202017%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F1.4985627%22%2C%22ISSN%22%3A%220003-6951%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Faip.scitation.org%5C%2Fdoi%5C%2Fabs%5C%2F10.1063%5C%2F1.4985627%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222020-04-21T06%3A13%3A15Z%22%7D%7D%2C%7B%22key%22%3A%22UIVB8WDU%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Iimura%20et%20al.%22%2C%22parsedDate%22%3A%222017-07-02%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EIimura%2C%20S.%3B%20Muramoto%2C%20T.%3B%20Fujitsu%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20High%20Pressure%20Growth%20and%20Electron%20Transport%20Properties%20of%20Superconducting%20SmFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E%20Single%20Crystals.%20%3Ci%3EJournal%20of%20Asian%20Ceramic%20Societies%3C%5C%2Fi%3E%20%3Cb%3E2017%3C%5C%2Fb%3E.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jascer.2017.06.009%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jascer.2017.06.009%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22High%20pressure%20growth%20and%20electron%20transport%20properties%20of%20superconducting%20SmFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E%20single%20crystals%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takashi%22%2C%22lastName%22%3A%22Muramoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Fujitsu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20the%20single%20crystal%20growth%20and%20characterization%20of%20the%20highest%20Tc%20iron-based%20superconductor%20SmFeAsO1%5Cu2212xHx.%20Some%20sub-millimeter-sized%20crystals%20were%20grown%20using%20the%20mixture%20flux%20of%20Na3As%2B3NaH%2BAs%20at%203.0GPa%20and%201473K.%20The%20chemical%20composition%20analyses%20confirmed%2010%25%20substitution%20of%20hydrogen%20for%20the%20oxygen%20site%20%28x%3D0.10%29%2C%20however%2C%20the%20structural%20analyses%20suggested%20that%20the%20obtained%20crystal%20forms%20a%20multi-domain%20structure.%20By%20using%20the%20FIB%20technique%20we%20fabricated%20the%20single%20domain%20SmFeAsO0.9H0.10%20crystal%20with%20the%20Tc%20of%2042K%2C%20and%20revealed%20the%20metallic%20conduction%20in%20in-plane%20%28%5Cu03c1ab%29%2C%20while%20semiconducting%20in%20the%20out-of-plane%20%28%5Cu03c1c%29.%20From%20the%20in-plane%20Hall%20coefficient%20measurements%2C%20we%20confirmed%20that%20the%20dominant%20carrier%20of%20SmFeAsO0.9H0.10%20crystal%20is%20an%20electron%2C%20and%20the%20hydride%20ion%20occupied%20at%20the%20site%20of%20the%20oxygen%20ion%20effectively%20supplies%20a%20carrier%20electron%20per%20iron%20following%20the%20equation%3A%20O2%5Cu2212%5Cu2192H%5Cu2212%2Be%5Cu2212.%22%2C%22date%22%3A%22July%202%2C%202017%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jascer.2017.06.009%22%2C%22ISSN%22%3A%222187-0764%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS2187076417300829%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222023-09-11T03%3A50%3A55Z%22%7D%7D%2C%7B%22key%22%3A%22A3E6PHX2%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Obata%20et%20al.%22%2C%22parsedDate%22%3A%222017-10-09%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EObata%2C%20Y.%3B%20Yukawa%2C%20R.%3B%20Horiba%2C%20K.%3B%20Kumigashira%2C%20H.%3B%20Toda%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20ARPES%20Studies%20of%20the%20Inverse%20Perovskite%20Ca%3Csub%3E3%3C%5C%2Fsub%3EPbO%3A%20Experimental%20Confirmation%20of%20a%20Candidate%203D%20Dirac%20Fermion%20System.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2017%3C%5C%2Fb%3E%2C%20%3Ci%3E96%3C%5C%2Fi%3E%20%2815%29%2C%20155109.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.96.155109%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.96.155109%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22ARPES%20studies%20of%20the%20inverse%20perovskite%20Ca%3Csub%3E3%3C%5C%2Fsub%3EPbO%3A%20Experimental%20confirmation%20of%20a%20candidate%203D%20Dirac%20fermion%20system%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yukiko%22%2C%22lastName%22%3A%22Obata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ryu%22%2C%22lastName%22%3A%22Yukawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Koji%22%2C%22lastName%22%3A%22Horiba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Kumigashira%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshitake%22%2C%22lastName%22%3A%22Toda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20investigate%20the%20band%20structure%20of%20the%20inverse%20perovskite%20Ca3PbO%2C%20a%20candidate%20three-dimensional%20%283D%29%20Dirac%20fermion%20material%2C%20through%20soft%20x-ray%20angle-resolved%20photoemission%20spectroscopy.%20Conelike%20band%20dispersions%20are%20observed%20for%20Ca3PbO%2C%20in%20close%20agreement%20with%20the%20predictions%20of%20electronic%20structure%20calculations.%20We%20further%20demonstrate%20that%20chemical%20substitution%20of%20Bi%20for%20Pb%20is%20effective%20in%20tuning%20the%20Fermi%20level%20of%20Ca3PbO%20while%20leaving%20its%20electronic%20structure%20intact.%20Our%20study%20confirms%20that%20the%20inverse%20perovskite%20family%20provides%20a%20promising%20platform%20for%20the%20exploration%20of%203D%20Dirac%20fermion%20systems.%22%2C%22date%22%3A%22October%209%2C%202017%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.96.155109%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.96.155109%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222018-08-31T19%3A44%3A58Z%22%7D%7D%2C%7B%22key%22%3A%22BHDIYZUV%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fujiwara%20et%20al.%22%2C%22parsedDate%22%3A%222017-10-30%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EFujiwara%2C%20N.%3B%20Kawaguchi%2C%20N.%3B%20IImura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Quantum%20Phase%20Transition%20under%20Pressure%20in%20the%20Heavily%20Hydrogen-Doped%20Iron-Based%20Superconductor%20LaFeAsO.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2017%3C%5C%2Fb%3E%2C%20%3Ci%3E96%3C%5C%2Fi%3E%20%2814%29%2C%20140507.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.96.140507%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.96.140507%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Quantum%20phase%20transition%20under%20pressure%20in%20the%20heavily%20hydrogen-doped%20iron-based%20superconductor%20LaFeAsO%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Naoki%22%2C%22lastName%22%3A%22Fujiwara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Naoto%22%2C%22lastName%22%3A%22Kawaguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soushi%22%2C%22lastName%22%3A%22IImura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Hydrogen%20%28H%29-doped%20LaFeAsO%20is%20a%20prototypical%20iron-based%20superconductor.%20However%2C%20its%20phase%20diagram%20extends%20beyond%20the%20standard%20framework%2C%20where%20a%20superconducting%20%28SC%29%20phase%20follows%20an%20antiferromagnetic%20%28AF%29%20phase%20upon%20carrier%20doping%3B%20instead%2C%20the%20SC%20phase%20is%20sandwiched%20between%20two%20AF%20phases%20appearing%20in%20lightly%20and%20heavily%20H-doped%20regimes.%20We%20performed%20nuclear%20magnetic%20resonance%20%28NMR%29%20measurements%20under%20pressure%2C%20focusing%20on%20the%20second%20AF%20phase%20in%20the%20heavily%20H-doped%20regime.%20The%20second%20AF%20phase%20is%20strongly%20suppressed%20when%20a%20pressure%20of%203.0%20GPa%20is%20applied%2C%20and%20apparently%20shifts%20to%20a%20highly%20H-doped%20regime%2C%20thereby%20a%20%5Cu201cbare%5Cu201d%20quantum%20critical%20point%20%28QCP%29%20emerges.%20A%20quantum%20critical%20regime%20emerges%20in%20a%20paramagnetic%20state%20near%20the%20QCP%2C%20however%2C%20the%20influence%20of%20the%20AF%20critical%20fluctuations%20to%20the%20SC%20phase%20is%20limited%20in%20the%20narrow%20doping%20regime%20near%20the%20QCP.%20The%20optimal%20SC%20condition%20%28Tc%5Cu223c48%20K%29%20is%20unaffected%20by%20AF%20fluctuations.%22%2C%22date%22%3A%22October%2030%2C%202017%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.96.140507%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.96.140507%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A33%3A37Z%22%7D%7D%2C%7B%22key%22%3A%22PB4BLW4P%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Daicho%20et%20al.%22%2C%22parsedDate%22%3A%222017-11-29%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EDaicho%2C%20H.%3B%20Iwasaki%2C%20T.%3B%20Shinomiya%2C%20Y.%3B%20Nakano%2C%20A.%3B%20Sawa%2C%20H.%3B%20Yamada%2C%20W.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Nanocomposite%20Phosphor%20Consisting%20of%20CaI%3Csub%3E2%3C%5C%2Fsub%3E%3AEu%3Csup%3E2%2B%3C%5C%2Fsup%3E%20Single%20Nanocrystals%20Embedded%20in%20Crystalline%20SiO%3Csub%3E2%3C%5C%2Fsub%3E.%20%3Ci%3EACS%20Appl.%20Mater.%20Interfaces%3C%5C%2Fi%3E%20%3Cb%3E2017%3C%5C%2Fb%3E%2C%20%3Ci%3E9%3C%5C%2Fi%3E%20%2847%29%2C%2041405%26%23x2013%3B41412.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.7b14132%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.7b14132%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Nanocomposite%20Phosphor%20Consisting%20of%20CaI%3Csub%3E2%3C%5C%2Fsub%3E%3AEu%3Csup%3E2%2B%3C%5C%2Fsup%3E%20Single%20Nanocrystals%20Embedded%20in%20Crystalline%20SiO%3Csub%3E2%3C%5C%2Fsub%3E%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hisayoshi%22%2C%22lastName%22%3A%22Daicho%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takeshi%22%2C%22lastName%22%3A%22Iwasaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yu%22%2C%22lastName%22%3A%22Shinomiya%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Akitoshi%22%2C%22lastName%22%3A%22Nakano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Sawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wataru%22%2C%22lastName%22%3A%22Yamada%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22High%20luminescence%20efficiency%20is%20obtained%20in%20halide-%20and%20chalcogenide-based%20phosphors%2C%20but%20they%20are%20impractical%20because%20of%20their%20poor%20chemical%20durability.%20Here%20we%20report%20a%20halide-based%20nanocomposite%20phosphor%20with%20excellent%20luminescence%20efficiency%20and%20sufficient%20durability%20for%20practical%20use.%20Our%20approach%20was%20to%20disperse%20luminescent%20single%20nanocrystals%20of%20CaI2%3AEu2%2B%20in%20a%20chemically%20stable%2C%20translucent%20crystalline%20SiO2%20matrix.%20Using%20this%20approach%2C%20we%20successfully%20prepared%20a%20nanocomposite%20phosphor%20by%20means%20of%20self-organization%20through%20a%20simple%20solid-state%20reaction.%20Single%20nanocrystals%20of%206H%20polytype%20%28thr%20notation%29%20CaI2%3AEu2%2B%20with%20diameters%20of%20about%2050%20nm%20could%20be%20generated%20not%20only%20in%20a%20SiO2%20amorphous%20powder%20but%20also%20in%20a%20SiO2%20glass%20plate.%20The%20nanocomposite%20phosphor%20formed%20upon%20solidification%20of%20molten%20CaI2%20left%20behind%20in%20the%20crystalline%20SiO2%20that%20formed%20from%20the%20amorphous%20SiO2%20under%20the%20influence%20of%20a%20CaI2%20flux%20effect.%20The%20resulting%20nanocomposite%20phosphor%20emitted%20brilliant%20blue%20luminescence%20with%20an%20internal%20quantum%20efficiency%20up%20to%2098%25%20upon%20407%20nm%20violet%20excitation.%20We%20used%20cathodoluminescence%20microscopy%2C%20scanning%20transmission%20electron%20microscopy%2C%20and%20Rietveld%20refinement%20of%20the%20X-ray%20diffraction%20patterns%20to%20confirm%20that%20the%20blue%20luminescence%20was%20generated%20only%20by%20the%20CaI2%3AEu2%2B%20single%20nanocrystals.%20The%20phosphor%20was%20chemically%20durable%20because%20the%20luminescence%20sites%20were%20embedded%20in%20the%20crystalline%20SiO2%20matrix.%20The%20phosphor%20is%20suitable%20for%20use%20in%20near-ultraviolet%20light-emitting%20diodes.%20The%20concept%20for%20this%20nanocomposite%20phosphor%20can%20be%20expected%20to%20be%20effective%20for%20improvements%20in%20the%20practicality%20of%20poorly%20durable%20materials%20such%20as%20halides%20and%20chalcogenides.%22%2C%22date%22%3A%222017%5C%2F11%5C%2F29%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facsami.7b14132%22%2C%22ISSN%22%3A%221944-8244%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facsami.7b14132%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222018-08-31T19%3A46%3A29Z%22%7D%7D%2C%7B%22key%22%3A%22CA9VLIRX%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Daicho%20et%20al.%22%2C%22parsedDate%22%3A%222017-12-06%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EDaicho%2C%20H.%3B%20Shinomiya%2C%20Y.%3B%20Enomoto%2C%20K.%3B%20Nakano%2C%20A.%3B%20Sawa%2C%20H.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20A%20Novel%20Red-Emitting%20K%3Csub%3E2%3C%5C%2Fsub%3ECa%28PO%3Csub%3E4%3C%5C%2Fsub%3E%29F%3AEu%3Csup%3E2%2B%3C%5C%2Fsup%3E%20Phosphor%20with%20a%20Large%20Stokes%20Shift.%20%3Ci%3EChem.%20Commun.%3C%5C%2Fi%3E%20%3Cb%3E2017%3C%5C%2Fb%3E.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FC7CC08202A%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FC7CC08202A%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22A%20novel%20red-emitting%20K%3Csub%3E2%3C%5C%2Fsub%3ECa%28PO%3Csub%3E4%3C%5C%2Fsub%3E%29F%3AEu%3Csup%3E2%2B%3C%5C%2Fsup%3E%20phosphor%20with%20a%20large%20Stokes%20shift%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Daicho%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Shinomiya%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Enomoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Nakano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Sawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20a%20K2CaPO4F%3AEu2%2B%20phosphor%20with%20a%20new%20crystal%20structure.%20This%20phosphor%20has%20a%20large%20Stokes%20shift%20and%20converts%20near-ultraviolet%20light%20to%20red%20luminescence%20without%20absorption%20of%20other%20visible%20light.%20The%20mechanism%20was%20elucidated%20by%20applying%20a%20constrained%20density%20functional%20theory%20to%20the%20solved%20crystal%20structure.%22%2C%22date%22%3A%222017-12-06%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1039%5C%2FC7CC08202A%22%2C%22ISSN%22%3A%221364-548X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fpubs.rsc.org%5C%2Fen%5C%2Fcontent%5C%2Farticlelanding%5C%2F2017%5C%2Fcc%5C%2Fc7cc08202a%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222018-08-31T19%3A47%3A27Z%22%7D%7D%2C%7B%22key%22%3A%224P4VB3D2%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Toda%20et%20al.%22%2C%22parsedDate%22%3A%222017-12-26%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EToda%2C%20Y.%3B%20Ishiyama%2C%20S.%3B%20Khutoryan%2C%20E.%3B%20Idehara%2C%20T.%3B%20Matsuishi%2C%20S.%3B%20Sushko%2C%20P.%20V.%3B%20Hosono%2C%20H.%20Rattling%20of%20Oxygen%20Ions%20in%20a%20Sub-Nanometer-Sized%20Cage%20Converts%20Terahertz%20Radiation%20to%20Visible%20Light.%20%3Ci%3EACS%20Nano%3C%5C%2Fi%3E%20%3Cb%3E2017%3C%5C%2Fb%3E%2C%20%3Ci%3E11%3C%5C%2Fi%3E%20%2812%29%2C%2012358%26%23x2013%3B12364.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.7b06277%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.7b06277%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Rattling%20of%20Oxygen%20Ions%20in%20a%20Sub-Nanometer-Sized%20Cage%20Converts%20Terahertz%20Radiation%20to%20Visible%20Light%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshitake%22%2C%22lastName%22%3A%22Toda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shintaro%22%2C%22lastName%22%3A%22Ishiyama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Eduard%22%2C%22lastName%22%3A%22Khutoryan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshitaka%22%2C%22lastName%22%3A%22Idehara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Peter%20V.%22%2C%22lastName%22%3A%22Sushko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22A%20simple%20and%20robust%20approach%20to%20visualization%20of%20continuous%20wave%20terahertz%20%28CW-THz%29%20light%20would%20open%20up%20opportunities%20to%20couple%20physical%20phenomena%20that%20occur%20at%20fundamentally%20different%20energy%20scales.%20Here%20we%20demonstrate%20how%20nanoscale%20cages%20of%20Ca12Al14O33%20crystal%20enable%20conversion%20of%20CW-THz%20radiation%20to%20visible%20light.%20These%20crystallographic%20cages%20are%20partially%20occupied%20with%20weakly%20bonded%20oxygen%20ions%20and%20give%20rise%20to%20a%20narrow%20conduction%20band%20that%20can%20be%20populated%20with%20localized%2C%20yet%20mobile%20electrons.%20CW-THz%20light%20excites%20a%20nearly%20stand-alone%20rattling%20motion%20of%20the%20encaged%20oxygen%20species%2C%20which%20promotes%20electron%20transfer%20from%20them%20to%20the%20neighboring%20vacant%20cages.%20When%20the%20power%20of%20CW-THz%20light%20reaches%20tens%20of%20watts%2C%20the%20coupling%20between%20forced%20rattling%20in%20the%20confined%20space%2C%20electronic%20excitation%20and%20ionization%20of%20oxygen%20species%2C%20and%20corresponding%20recombination%20processes%20result%20in%20emission%20of%20bright%20visible%20light.%22%2C%22date%22%3A%222017-12-26%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facsnano.7b06277%22%2C%22ISSN%22%3A%221936-0851%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.7b06277%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A32%3A09Z%22%7D%7D%5D%7D
(1)
Mizoguchi, H.; Muraba, Y.; Fredrickson, D. C.; Matsuishi, S.; Kamiya, T.; Hosono, H. The Unique Electronic Structure of Mg2Si: Shaping the Conduction Bands of Semiconductors with Multicenter Bonding. Angewandte Chemie International Edition 2017, 56 (34), 10135–10139. https://doi.org/https://doi.org/10.1002/anie.201701681.
(1)
Iimura, S.; Tomota, Y.; Matsuishi, S.; Masuda, R.; Seto, M.; Hiraka, H.; Ikeda, K.; Otomo, T.; Hosono, H. Ferrimagnetic Cage Framework in Ca12Fe10Si4O32Cl6. Inorg. Chem. 2017, 56 (1), 566–572. https://doi.org/10.1021/acs.inorgchem.6b02404.
(1)
Nakamura, A.; Shimojima, T.; Sonobe, T.; Yoshida, S.; Ishizaka, K.; Malaeb, W.; Shin, S.; Iimura, S.; Matsuishi, S.; Hosono, H. Multiple-Pseudogap Phases in the Hydrogen-Doped LaFeAsO System. Phys. Rev. B 2017, 95 (6), 064501. https://doi.org/10.1103/PhysRevB.95.064501.
(1)
Tang, H.; Kishida, Y.; Ide, K.; Toda, Y.; Hiramatsu, H.; Matsuishi, S.; Ueda, S.; Ohashi, N.; Kumomi, H.; Hosono, H.; Kamiya, T. Multiple Roles of Hydrogen Treatments in Amorphous In–Ga–Zn–O Films. ECS J. Solid State Sci. Technol. 2017, 6 (7), P365. https://doi.org/10.1149/2.0071707jss.
(1)
Iimura, S.; Okanishi, H.; Matsuishi, S.; Hiraka, H.; Honda, T.; Ikeda, K.; Hansen, T. C.; Otomo, T.; Hosono, H. Large-Moment Antiferromagnetic Order in Overdoped High- T c Superconductor 154 SmFeAsO 1− x D x . Proc. Natl. Acad. Sci. U.S.A. 2017, 114 (22). https://doi.org/10.1073/pnas.1703295114.
(1)
Bang, J.; Matsuishi, S.; Hosono, H. Hydrogen Anion and Subgap States in Amorphous In–Ga–Zn–O Thin Films for TFT Applications. Appl. Phys. Lett. 2017, 110 (23), 232105. https://doi.org/10.1063/1.4985627.
(1)
Iimura, S.; Muramoto, T.; Fujitsu, S.; Matsuishi, S.; Hosono, H. High Pressure Growth and Electron Transport Properties of Superconducting SmFeAsO1-xHx Single Crystals. Journal of Asian Ceramic Societies 2017. https://doi.org/10.1016/j.jascer.2017.06.009.
(1)
Obata, Y.; Yukawa, R.; Horiba, K.; Kumigashira, H.; Toda, Y.; Matsuishi, S.; Hosono, H. ARPES Studies of the Inverse Perovskite Ca3PbO: Experimental Confirmation of a Candidate 3D Dirac Fermion System. Phys. Rev. B 2017, 96 (15), 155109. https://doi.org/10.1103/PhysRevB.96.155109.
(1)
Fujiwara, N.; Kawaguchi, N.; IImura, S.; Matsuishi, S.; Hosono, H. Quantum Phase Transition under Pressure in the Heavily Hydrogen-Doped Iron-Based Superconductor LaFeAsO. Phys. Rev. B 2017, 96 (14), 140507. https://doi.org/10.1103/PhysRevB.96.140507.
(1)
Daicho, H.; Iwasaki, T.; Shinomiya, Y.; Nakano, A.; Sawa, H.; Yamada, W.; Matsuishi, S.; Hosono, H. Nanocomposite Phosphor Consisting of CaI2:Eu2+ Single Nanocrystals Embedded in Crystalline SiO2. ACS Appl. Mater. Interfaces 2017, 9 (47), 41405–41412. https://doi.org/10.1021/acsami.7b14132.
(1)
Daicho, H.; Shinomiya, Y.; Enomoto, K.; Nakano, A.; Sawa, H.; Matsuishi, S.; Hosono, H. A Novel Red-Emitting K2Ca(PO4)F:Eu2+ Phosphor with a Large Stokes Shift. Chem. Commun. 2017. https://doi.org/10.1039/C7CC08202A.
(1)
Toda, Y.; Ishiyama, S.; Khutoryan, E.; Idehara, T.; Matsuishi, S.; Sushko, P. V.; Hosono, H. Rattling of Oxygen Ions in a Sub-Nanometer-Sized Cage Converts Terahertz Radiation to Visible Light. ACS Nano 2017, 11 (12), 12358–12364. https://doi.org/10.1021/acsnano.7b06277.
244926
P5622579
2016
items
1
american-chemical-society-with-titles-sentence-case-doi
0
date
asc
year
6
https://www.mces.titech.ac.jp/authors/matsuishi/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-3408db43a6c85abba0f1b4d4ed17c0e0%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22IC7G495R%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Joonho%20et%20al.%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EJoonho%20B.%3B%20Satoru%20M.%3B%20Hideo%20H.%20%26%23x30A2%3B%26%23x30E2%3B%26%23x30EB%3B%26%23x30D5%3B%26%23x30A1%3B%26%23x30B9%3BIGZO%26%23x8584%3B%26%23x819C%3B%26%23x306E%3B%26%23x6C34%3B%26%23x7D20%3B%26%23x3068%3B%26%23x30B5%3B%26%23x30D6%3B%26%23x30AE%3B%26%23x30E3%3B%26%23x30C3%3B%26%23x30D7%3B%26%23x72B6%3B%26%23x614B%3B.%20%3Ci%3EProceedings%20of%20the%20International%20Display%20Workshops%20%28CD-ROM%29%3C%5C%2Fi%3E%3B%202016%3B%20Vol.%2023rd%2C%20p%20ROMBUNNO.AMD7-4L.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22conferencePaper%22%2C%22title%22%3A%22%5Cu30a2%5Cu30e2%5Cu30eb%5Cu30d5%5Cu30a1%5Cu30b9IGZO%5Cu8584%5Cu819c%5Cu306e%5Cu6c34%5Cu7d20%5Cu3068%5Cu30b5%5Cu30d6%5Cu30ae%5Cu30e3%5Cu30c3%5Cu30d7%5Cu72b6%5Cu614b%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bang%22%2C%22lastName%22%3A%22Joonho%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matsuishi%22%2C%22lastName%22%3A%22Satoru%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hosono%22%2C%22lastName%22%3A%22Hideo%22%7D%5D%2C%22abstractNote%22%3A%22%5Cu6587%5Cu732e%5Cu300c%5Cu30a2%5Cu30e2%5Cu30eb%5Cu30d5%5Cu30a1%5Cu30b9IGZO%5Cu8584%5Cu819c%5Cu306e%5Cu6c34%5Cu7d20%5Cu3068%5Cu30b5%5Cu30d6%5Cu30ae%5Cu30e3%5Cu30c3%5Cu30d7%5Cu72b6%5Cu614b%5Cu300d%5Cu306e%5Cu8a73%5Cu7d30%5Cu60c5%5Cu5831%5Cu3067%5Cu3059%5Cu3002J-GLOBAL%20%5Cu79d1%5Cu5b66%5Cu6280%5Cu8853%5Cu7dcf%5Cu5408%5Cu30ea%5Cu30f3%5Cu30af%5Cu30bb%5Cu30f3%5Cu30bf%5Cu30fc%5Cu306f%5Cu7814%5Cu7a76%5Cu8005%5Cu3001%5Cu6587%5Cu732e%5Cu3001%5Cu7279%5Cu8a31%5Cu306a%5Cu3069%5Cu306e%5Cu60c5%5Cu5831%5Cu3092%5Cu3064%5Cu306a%5Cu3050%5Cu3053%5Cu3068%5Cu3067%5Cu3001%5Cu7570%5Cu5206%5Cu91ce%5Cu306e%5Cu77e5%5Cu3084%5Cu610f%5Cu5916%5Cu306a%5Cu767a%5Cu898b%5Cu306a%5Cu3069%5Cu3092%5Cu652f%5Cu63f4%5Cu3059%5Cu308b%5Cu65b0%5Cu3057%5Cu3044%5Cu30b5%5Cu30fc%5Cu30d3%5Cu30b9%5Cu3067%5Cu3059%5Cu3002%5Cu307e%5Cu305fJST%5Cu5185%5Cu5916%5Cu306e%5Cu826f%5Cu8cea%5Cu306a%5Cu30b3%5Cu30f3%5Cu30c6%5Cu30f3%5Cu30c4%5Cu3078%5Cu6848%5Cu5185%5Cu3044%5Cu305f%5Cu3057%5Cu307e%5Cu3059%5Cu3002%22%2C%22date%22%3A%222016%22%2C%22proceedingsTitle%22%3A%22Proceedings%20of%20the%20International%20Display%20Workshops%20%28CD-ROM%29%22%2C%22conferenceName%22%3A%22%22%2C%22language%22%3A%22ja%22%2C%22DOI%22%3A%22%22%2C%22ISBN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fjglobal.jst.go.jp%5C%2Fdetail%3FJGLOBAL_ID%3D202102223360328399%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-10-04T02%3A52%3A07Z%22%7D%7D%2C%7B%22key%22%3A%22BJUAFPJV%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Mizoguchi%20et%20al.%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMizoguchi%2C%20H.%3B%20Okunaka%2C%20M.%3B%20Kitano%2C%20M.%3B%20Matsuishi%2C%20S.%3B%20Yokoyama%2C%20T.%3B%20Hosono%2C%20H.%20Hydride-Based%20Electride%20Material%2C%20LnH2%20%28Ln%20%3D%20La%2C%20Ce%2C%20or%20Y%29.%20%3Ci%3EInorg.%20Chem.%3C%5C%2Fi%3E%20%3Cb%3E2016%3C%5C%2Fb%3E%2C%20%3Ci%3E55%3C%5C%2Fi%3E%20%2817%29%2C%208833%26%23x2013%3B8838.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.6b01369%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.6b01369%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Hydride-Based%20Electride%20Material%2C%20LnH2%20%28Ln%20%3D%20La%2C%20Ce%2C%20or%20Y%29%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Mizoguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masaaki%22%2C%22lastName%22%3A%22Okunaka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masaaki%22%2C%22lastName%22%3A%22Kitano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshiharu%22%2C%22lastName%22%3A%22Yokoyama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22In%20view%20of%20the%20strong%20electron-donating%20nature%20of%20H%5Cu2013%20and%20extensive%20vacancy%20formation%20in%20metals%20by%20hydrogen%20insertion%2C%20a%20series%20of%20LnH2%2Bx%20%28Ln%20%3D%20La%2C%20Ce%2C%20or%20Y%29%20compounds%20with%20fluorite-type%20structures%20were%20verified%20to%20be%20the%20first%20hydride-based%20electride%2C%20where%20itinerant%20electrons%20populating%20the%20cage%20are%20surrounded%20by%20H%5Cu2013%20anions.%20The%20electron%20transfer%20into%20the%20cage%20probably%20originates%20from%20Ln%5Cu2013cage%20covalent%20interaction.%20To%20the%20best%20of%20our%20knowledge%2C%20anion-rich%20electrides%20are%20extremely%20rare%2C%20and%20a%20key%20requirement%20for%20their%20formation%20is%20that%20the%20cage%20site%20is%20not%20occupied%20by%20lone%20pair%20electrons%20of%20the%20adjacent%20ions.%20In%20the%20case%20of%20LnH2%2C%20the%20cage%20site%20is%20surrounded%20by%20eight%20H%5Cu2013%20anions%20with%20isotopic%20electronic%20character%20caused%20by%20the%20lack%20of%20mixing%20of%20H%20p-orbital%20character.%20Notably%2C%20Ru-loaded%20LnH2%2Bx%20electride%20powders%20synthesized%20by%20hydrogen%20embrittlement%20%28Ln%20%3D%20La%20or%20Ce%29%20were%20found%20to%20work%20as%20efficient%20catalysts%20for%20ammonia%20synthesis%20at%20ambient%20pressure%2C%20without%20showing%20serious%20signs%20of%20hydrogen%20poisoning.%20There%20are%20several%20possible%20origins%20of%20the%20observed%20high%20catalytic%20activity%20in%20the%20hydride%20promotors%3A%20the%20small%20work%20function%20of%20LnH2%2Bx%20derived%20from%20the%20covalent%20interaction%20between%20Ln%20cation%20and%20the%20H%5Cu2013%20%5Cu03c3%20donor%2C%20and%20the%20formation%20of%20Ln%20nitride%20during%20catalytic%20reaction.%22%2C%22date%22%3A%229%5Cu6708%206%2C%202016%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.inorgchem.6b01369%22%2C%22ISSN%22%3A%220020-1669%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.inorgchem.6b01369%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A39%3A04Z%22%7D%7D%2C%7B%22key%22%3A%22XIR24ARU%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hiraishi%20et%20al.%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHiraishi%2C%20M.%3B%20Kojima%2C%20K.%20M.%3B%20Miyazaki%2C%20M.%3B%20Yamauchi%2C%20I.%3B%20Okabe%2C%20H.%3B%20Koda%2C%20A.%3B%20Kadono%2C%20R.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Cage%20Electron-Hydroxyl%20Complex%20State%20as%20Electron%20Donor%20in%20Mayenite.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2016%3C%5C%2Fb%3E%2C%20%3Ci%3E93%3C%5C%2Fi%3E%20%2812%29%2C%20121201.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.93.121201%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.93.121201%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Cage%20electron-hydroxyl%20complex%20state%20as%20electron%20donor%20in%20mayenite%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Hiraishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%20M.%22%2C%22lastName%22%3A%22Kojima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Miyazaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22I.%22%2C%22lastName%22%3A%22Yamauchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Okabe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Koda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Kadono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22It%20is%20inferred%20from%20the%20chemical%20shift%20of%20muon%20spin%20rotation%20%28%5Cu03bcSR%29%20spectra%20that%20muons%20implanted%20in%20pristine%20%28fully%20oxidized%29%20mayenite%2C%20%5BCa12Al14O32%5D2%2B%5B%5Cu25a15O2%5Cu2212%5D%20%28C12A7%2C%20with%20%5Cu25a1%20referring%20to%20the%20vacant%20cage%29%2C%20are%20bound%20to%20O2%5Cu2212%20at%20the%20cage%20center%20to%20form%20OMu%5Cu2212%20%28where%20Mu%20represents%20muonium%2C%20a%20muonic%20analog%20of%20the%20H%20atom%29.%20However%2C%20an%20isolated%20negatively%20charged%20state%20%28Mu%5Cu2212%2C%20an%20analog%20of%20H%5Cu2212%29%20becomes%20dominant%20when%20the%20compound%20approaches%20the%20state%20of%20electride%20%5BCa12Al14O32%5D2%2B%5B%5Cu25a142e%5Cu2212%5D%20as%20a%20result%20of%20the%20reduction%20process.%20Moreover%2C%20the%20OMu%5Cu2212%20state%20in%20the%20pristine%20specimen%20exhibits%20depolarization%20of%20paramagnetic%20origin%20at%20low%20temperatures%20%28below%20%5Cu223c30%20K%29%2C%20indicating%20that%20OMu%5Cu2212%20accompanies%20a%20loosely%20bound%20electron%20in%20the%20cage%20that%20can%20be%20thermally%20activated.%20This%20suggests%20that%20interstitial%20muons%20%28and%20hence%20H%29%20forming%20a%20%5Cu201ccage%20electron-hydroxyl%5Cu201d%20complex%20can%20serve%20as%20electron%20donors%20in%20C12A7.%22%2C%22date%22%3A%223%5Cu6708%209%2C%202016%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.93.121201%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.93.121201%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T01%3A33%3A43Z%22%7D%7D%2C%7B%22key%22%3A%22N9R99WUD%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Iimura%20et%20al.%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EIimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Heavy%20Electron%20Doping%20Induced%20Antiferromagnetic%20Phase%20as%20the%20Parent%20for%20the%20Iron%20Oxypnictide%20Superconductor%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2016%3C%5C%2Fb%3E%2C%20%3Ci%3E94%3C%5C%2Fi%3E%20%282%29%2C%20024512.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.94.024512%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.94.024512%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Heavy%20electron%20doping%20induced%20antiferromagnetic%20phase%20as%20the%20parent%20for%20the%20iron%20oxypnictide%20superconductor%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20perform%20transport%20measurements%20and%20band%20structure%20calculations%20of%20electron-doped%20LaFeAsO1%5Cu2212xHx%20over%20a%20wide%20range%20of%20x%20from%200.01%20to%200.66.%20The%20T2%20and%20%5Cu221aT%20dependency%20of%20the%20resistivity%20are%20observed%20at%20x%5Cu223c0.17%20and%200.41%2C%20respectively.%20The%20sign%20change%20of%20RH%20without%20opening%20of%20the%20spin-density-wave%20gap%20for%200.45%5Cu2264x%5Cu22640.58%20and%20T%3CTN%20as%20well%20as%20the%20calculated%20non-nested%20Fermi%20surface%20at%20x%3D0.5%20indicate%20the%20more%20localized%20nature%20of%20the%20AF2%20as%20compared%20to%20spin-density-wave%20phase%20at%20the%20nondoped%20sample.%20Considering%20the%20results%20from%20band%20calculations%20and%20the%20finite%20size%20of%20Hund%27s%20rule%20coupling%2C%20the%20change%20of%20the%20normal%20conducting%20state%20with%20x%20is%20reasonably%20explained%20by%20a%20strong%20depression%20of%20the%20coherent%20scale%20owing%20to%20the%20increased%20effective%20Coulomb%20repulsion%20in%20the%20narrow%20antibonding%203dxy%20band%20that%20approaches%20the%20half-filled%20regime.%20The%20following%20transition%20from%20the%20paramagnet%20to%20AF2%20is%20understood%20as%20the%20quenching%20or%20ordering%20of%20the%20less-screened%20spins%20with%20a%20large%20entropy%20at%20low%20temperature.%20These%20results%20suggest%20that%20the%20normal%20conducting%20properties%20over%20a%20wide%20doping%20range%20for%20the%20LaFeAsO1%5Cu2212xHx%20are%20strongly%20influenced%20by%20the%20local%20spins%20in%20the%20incoherent%20region.%20Thus%2C%20we%20conclude%20that%20the%20parent%20phase%20in%20LaFeAsO1%5Cu2212xHx%20is%20not%20the%20spin-density%20wave%20but%20the%20AF2%2C%20which%20may%20be%20primarily%20responsible%20for%20the%20singular%20superconducting%20properties%20of%20the%201111%20type%20compared%20with%20other%20iron%20pnictides.%22%2C%22date%22%3A%227%5Cu6708%2015%2C%202016%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.94.024512%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.94.024512%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-07-29T01%3A34%3A21Z%22%7D%7D%2C%7B%22key%22%3A%22SSKIJ7F7%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22MISHRA%20et%20al.%22%2C%22parsedDate%22%3A%222016-06-01%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMISHRA%2C%20S.%20K.%3B%20MITTAL%2C%20R.%3B%20R%20KRISHNA%2C%20P.%20S.%3B%20SASTRY%2C%20P.%20U.%3B%20CHAPLOT%2C%20S.%20L.%3B%20BABU%2C%20P.%20D.%3B%20MATSUISHI%2C%20S.%3B%20HOSONO%2C%20H.%20Thermal%20Expansion%20Behaviour%20and%20Phase%20Stability%20of%20AFe2As2%20%28A%20%3D%20Ca%2C%20Sr%20and%20Eu%29%20Using%20Powder%20Diffraction%20Technique.%20%3Ci%3EPramana%20-%20J%20Phys%3C%5C%2Fi%3E%20%3Cb%3E2016%3C%5C%2Fb%3E%2C%20%3Ci%3E86%3C%5C%2Fi%3E%20%286%29%2C%201369%26%23x2013%3B1381.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs12043-016-1201-2%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs12043-016-1201-2%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Thermal%20expansion%20behaviour%20and%20phase%20stability%20of%20AFe2As2%20%28A%20%3D%20Ca%2C%20Sr%20and%20Eu%29%20using%20powder%20diffraction%20technique%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%20K.%22%2C%22lastName%22%3A%22MISHRA%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22MITTAL%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%20S.%22%2C%22lastName%22%3A%22R%20KRISHNA%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%20U.%22%2C%22lastName%22%3A%22SASTRY%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%20L.%22%2C%22lastName%22%3A%22CHAPLOT%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%20D.%22%2C%22lastName%22%3A%22BABU%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22MATSUISHI%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22HOSONO%22%7D%5D%2C%22abstractNote%22%3A%22The%20thermal%20expansibilities%20and%20phase%20stabilities%20of%20AFe%202As%202%20%28A%20%3D%20Ca%2C%20Sr%20and%20Eu%29%20have%20been%20investigated%20by%20powder%20diffraction%20techniques%20in%20the%20temperature%20range%205%5Cu2013600%20K.%20We%20found%20the%20anisotropic%20thermal%20expansivities%20with%20temperature%20for%20all%20the%20compounds.%20The%20lattice%20parameter%20in%20the%20tetragonal%20phase%20%28%20AT%29%20of%20CaFe%202As%202%20contracts%20with%20increasing%20temperature%2C%20whereas%20CT%20expands.%20The%20rate%20of%20contraction%20in%20AT%20is%20lower%20than%20the%20rate%20of%20expansion%20in%20CT.%20Other%20compounds%20show%20normal%20thermal%20expansion%20behaviour%20along%20both%20a-%20and%20c-axes.%20In-plane%20expansion%20%28i.e.%2C%20along%20the%20a-axis%29%20is%20found%20to%20be%20the%20smallest%20for%20EuFe%202As%202%20and%20the%20highest%20for%20BaFe%202As%202.%20However%2C%20the%20rate%20of%20change%20of%20thermal%20expansivities%20along%20out-of-plane%20%28i.e.%2C%20along%20the%20c-axis%29%20is%20higher%20as%20we%20go%20from%20Ba%2C%20Sr%2C%20Eu%20and%20Ca%2C%20respectively.%20Above%20600%20K%2C%20we%20notice%20the%20appearance%20%5C%2Fdisappearance%20of%20certain%20reflections%20which%20suggest%20that%20tetragonal%20phase%20is%20not%20stable%20above%20this%20temperature%20for%20these%20compounds.%22%2C%22date%22%3A%222016-06-01%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1007%5C%2Fs12043-016-1201-2%22%2C%22ISSN%22%3A%220973-7111%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs12043-016-1201-2%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A38%3A20Z%22%7D%7D%2C%7B%22key%22%3A%22GNUR8MIV%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kitano%20et%20al.%22%2C%22parsedDate%22%3A%222016-06-21%22%2C%22numChildren%22%3A6%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EKitano%2C%20M.%3B%20Inoue%2C%20Y.%3B%20Ishikawa%2C%20H.%3B%20Yamagata%2C%20K.%3B%20Nakao%2C%20T.%3B%20Tada%2C%20T.%3B%20Matsuishi%2C%20S.%3B%20Yokoyama%2C%20T.%3B%20Hara%2C%20M.%3B%20Hosono%2C%20H.%20Essential%20Role%20of%20Hydride%20Ion%20in%20Ruthenium-Based%20Ammonia%20Synthesis%20Catalysts.%20%3Ci%3EChem.%20Sci.%3C%5C%2Fi%3E%20%3Cb%3E2016%3C%5C%2Fb%3E%2C%20%3Ci%3E7%3C%5C%2Fi%3E%20%287%29%2C%204036%26%23x2013%3B4043.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FC6SC00767H%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FC6SC00767H%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Essential%20role%20of%20hydride%20ion%20in%20ruthenium-based%20ammonia%20synthesis%20catalysts%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masaaki%22%2C%22lastName%22%3A%22Kitano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yasunori%22%2C%22lastName%22%3A%22Inoue%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroki%22%2C%22lastName%22%3A%22Ishikawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kyosuke%22%2C%22lastName%22%3A%22Yamagata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takuya%22%2C%22lastName%22%3A%22Nakao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomofumi%22%2C%22lastName%22%3A%22Tada%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshiharu%22%2C%22lastName%22%3A%22Yokoyama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michikazu%22%2C%22lastName%22%3A%22Hara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%20efficient%20reduction%20of%20atmospheric%20nitrogen%20to%20ammonia%20under%20low%20pressure%20and%20temperature%20conditions%20has%20been%20a%20challenge%20in%20meeting%20the%20rapidly%20increasing%20demand%20for%20fertilizers%20and%20hydrogen%20storage.%20Here%2C%20we%20report%20that%20Ca2N%3Ae%5Cu2212%2C%20a%20two-dimensional%20electride%2C%20combined%20with%20ruthenium%20nanoparticles%20%28Ru%5C%2FCa2N%3Ae%5Cu2212%29%20exhibits%20efficient%20and%20stable%20catalytic%20activity%20down%20to%20200%20%5Cu00b0C.%20This%20catalytic%20performance%20is%20due%20to%20%5BCa2N%5D%2B%5Cu00b7e1%5Cu2212x%5Cu2212Hx%5Cu2212%20formed%20by%20a%20reversible%20reaction%20of%20an%20anionic%20electron%20with%20hydrogen%20%28Ca2N%3Ae%5Cu2212%20%2B%20xH%20%5Cu2194%20%5BCa2N%5D%2B%5Cu00b7e1%5Cu2212x%5Cu2212Hx%5Cu2212%29%20during%20ammonia%20synthesis.%20The%20simplest%20hydride%2C%20CaH2%2C%20with%20Ru%20also%20exhibits%20catalytic%20performance%20comparable%20to%20Ru%5C%2FCa2N%3Ae%5Cu2212.%20The%20resultant%20electrons%20in%20these%20hydrides%20have%20a%20low%20work%20function%20of%202.3%20eV%2C%20which%20facilitates%20the%20cleavage%20of%20N2%20molecules.%20The%20smooth%20reversible%20exchangeability%20between%20anionic%20electrons%20and%20H%5Cu2212%20ions%20in%20hydrides%20at%20low%20temperatures%20suppresses%20hydrogen%20poisoning%20of%20the%20Ru%20surfaces.%20The%20present%20work%20demonstrates%20the%20high%20potential%20of%20metal%20hydrides%20as%20efficient%20promoters%20for%20low-temperature%20ammonia%20synthesis.%22%2C%22date%22%3A%222016%5C%2F06%5C%2F21%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1039%5C%2FC6SC00767H%22%2C%22ISSN%22%3A%222041-6539%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fpubs.rsc.org%5C%2Fen%5C%2Fcontent%5C%2Farticlelanding%5C%2F2016%5C%2Fsc%5C%2Fc6sc00767h%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22HSKL45UJ%22%5D%2C%22dateModified%22%3A%222018-05-02T05%3A23%3A11Z%22%7D%7D%2C%7B%22key%22%3A%225Q44JKUA%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Zhang%20et%20al.%22%2C%22parsedDate%22%3A%222016-07%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EZhang%2C%20X.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Critical%20Behavior%20and%20Magnetocaloric%20Effect%20in%20Layered%20Structure%20Tb2C.%20%3Ci%3EJ.%20Phys.%20D%3A%20Appl.%20Phys.%3C%5C%2Fi%3E%20%3Cb%3E2016%3C%5C%2Fb%3E%2C%20%3Ci%3E49%3C%5C%2Fi%3E%20%2833%29%2C%20335002.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F0022-3727%5C%2F49%5C%2F33%5C%2F335002%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F0022-3727%5C%2F49%5C%2F33%5C%2F335002%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Critical%20behavior%20and%20magnetocaloric%20effect%20in%20layered%20structure%20Tb2C%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xiao%22%2C%22lastName%22%3A%22Zhang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%20critical%20behavior%20and%20magnetocaloric%20effects%20of%20the%20layered%20structure%20Tb2C%20have%20been%20investigated%20using%20magnetization%20measurements%20around%20the%20Curie%20temperature.%20Analyzing%20temperature%20and%20field%20dependence%20of%20magnetization%20reveals%20that%20the%20Tb2C%20system%20undergoes%20a%20second-order%20magnetic%20phase%20transition%20at%20TC%20%3D%20266%20K.%20Critical%20exponents%20obtained%20from%20modified%20Arrott%2C%20Kouvel%5Cu2013Fisher%20%28KF%29%20and%20scaling%20plots%20are%20consistent%20with%20each%20other.%20The%20critical%20exponents%20suggest%20that%20the%20magnetic%20phase%20transition%20in%20Tb2C%20can%20be%20described%20by%20the%20mean-field%20model.%20The%20exchange%20energy%20declines%20as%20J%28r%29%20r%5Cu22124.547%2C%20indicating%20that%20long-range%20interaction%20dominates%20the%20exchange%20interaction.%20Consequently%2C%20the%20field%20dependence%20magnetic%20entropy%20change%20%28%5Cu0394SM%29%20of%20Tb2C%2C%20calculated%20using%20the%20Maxwell%20relation%2C%20clearly%20demonstrates%20that%20the%20relationship%20between%20%5Cu2212%5Cu0394SM%20and%20%28H%5C%2FTC%292%5C%2F3%20obeys%20the%20mean-field%20theory%2C%20supporting%20our%20conclusion%20of%20the%20ferromagnetism%20phase%20transition%20in%20Tb2C%20following%20the%20mean-field%20theory.%22%2C%22date%22%3A%22July%202016%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1088%5C%2F0022-3727%5C%2F49%5C%2F33%5C%2F335002%22%2C%22ISSN%22%3A%220022-3727%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F0022-3727%5C%2F49%5C%2F33%5C%2F335002%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A37%3A45Z%22%7D%7D%2C%7B%22key%22%3A%22EVRDNDQB%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kawaguchi%20et%20al.%22%2C%22parsedDate%22%3A%222016-10-04%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EKawaguchi%2C%20N.%3B%20Fujiwara%2C%20N.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Experimental%20Evidence%20of%20T%3Csub%3Ec%3C%5C%2Fsub%3E%20Enhancement%20without%20the%20Influence%20of%20Spin%20Fluctuations%3A%20NMR%20Study%20on%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E%20under%20a%20Pressure%20of%203.0%20GPa.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2016%3C%5C%2Fb%3E%2C%20%3Ci%3E94%3C%5C%2Fi%3E%20%2816%29%2C%20161104.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.94.161104%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.94.161104%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Experimental%20evidence%20of%20T%3Csub%3Ec%3C%5C%2Fsub%3E%20enhancement%20without%20the%20influence%20of%20spin%20fluctuations%3A%20NMR%20study%20on%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E%20under%20a%20pressure%20of%203.0%20GPa%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Kawaguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Fujiwara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%20electron-doped%20high-transition-temperature%20%28Tc%29%20iron-based%20pnictide%20superconductor%20LaFeAsO1%5Cu2212xHx%20has%20a%20unique%20phase%20diagram%3A%20Superconducting%20double%20domes%20are%20sandwiched%20by%20antiferromagnetic%20phases%20at%20ambient%20pressure%20and%20they%20turn%20into%20a%20single%20dome%20with%20a%20maximum%20Tc%20that%20exceeds%2045%20K%20at%20a%20pressure%20of%203.0%20GPa.%20We%20studied%20whether%20spin%20fluctuations%20are%20involved%20in%20increasing%20Tc%20under%20a%20pressure%20of%203.0%20GPa%20by%20using%20the%2075As%20nuclear%20magnetic%20resonance%20%28NMR%29%20technique.%20The%2075As-NMR%20results%20for%20the%20powder%20samples%20show%20that%20Tc%20increases%20up%20to%2048%20K%20without%20the%20influence%20of%20spin%20fluctuations.%20This%20fact%20indicates%20that%20spin%20fluctuations%20are%20not%20involved%20in%20raising%20Tc%2C%20which%20implies%20that%20other%20factors%2C%20such%20as%20orbital%20degrees%20of%20freedom%2C%20may%20be%20important%20for%20achieving%20a%20high%20Tc%20of%20almost%2050%20K.%22%2C%22date%22%3A%22October%204%2C%202016%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.94.161104%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.94.161104%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222018-08-31T19%3A48%3A37Z%22%7D%7D%2C%7B%22key%22%3A%22LKVZ3T6G%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kobayashi%20et%20al.%22%2C%22parsedDate%22%3A%222016-12-22%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EKobayashi%2C%20K.%3B%20Yamaura%2C%20J.%3B%20Iimura%2C%20S.%3B%20Maki%2C%20S.%3B%20Sagayama%2C%20H.%3B%20Kumai%2C%20R.%3B%20Murakami%2C%20Y.%3B%20Takahashi%2C%20H.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Pressure%20Effect%20on%20Iron-Based%20Superconductor%20LaFeAsO%201%26%23x2212%3Bx%20H%20X%26%23x202F%3B%3A%20Peculiar%20Response%20of%201111-Type%20Structure.%20%3Ci%3EScientific%20Reports%3C%5C%2Fi%3E%20%3Cb%3E2016%3C%5C%2Fb%3E%2C%20%3Ci%3E6%3C%5C%2Fi%3E%20%281%29%2C%2039646.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fsrep39646%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fsrep39646%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Pressure%20effect%20on%20iron-based%20superconductor%20LaFeAsO%201%5Cu2212x%20H%20x%20%3A%20Peculiar%20response%20of%201111-type%20structure%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kensuke%22%2C%22lastName%22%3A%22Kobayashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jun-ichi%22%2C%22lastName%22%3A%22Yamaura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sachiko%22%2C%22lastName%22%3A%22Maki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hajime%22%2C%22lastName%22%3A%22Sagayama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Reiji%22%2C%22lastName%22%3A%22Kumai%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Youichi%22%2C%22lastName%22%3A%22Murakami%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroki%22%2C%22lastName%22%3A%22Takahashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22A%20systematic%20study%20of%20the%20crystal%20structure%20of%20a%20layered%20iron%20oxypnictide%20LaFeAsO1%5Cu2212xHx%20as%20a%20function%20of%20pressure%20was%20performed%20using%20synchrotron%20X-ray%20diffraction.%20This%20compound%20exhibits%20a%20unique%20phase%20diagram%20of%20two%20superconducting%20phases%20and%20two%20parent%20phases.%20We%20established%20that%20the%20As%5Cu2013Fe%5Cu2013As%20angle%20of%20the%20FeAs4%20tetrahedron%20widens%20on%20the%20application%20of%20pressure%20due%20to%20the%20interspace%20between%20the%20layers%20being%20nearly%20infilled%20by%20the%20large%20La%20and%20As%20atoms.%20Such%20rarely%20observed%20behaviour%20in%20iron%20pnictides%20implies%20that%20the%20FeAs4%20coordination%20deviates%20from%20the%20regular%20tetrahedron%20in%20the%20present%20systems.%20This%20breaks%20a%20widely%20accepted%20structural%20guide%20that%20the%20superconductivity%20favours%20the%20regular%20tetrahedron%2C%20albeit%20the%20superconducting%20transition%20temperature%20%28Tc%29%20increases%20from%2018%5Cu2009K%20at%20ambient%20pressure%20to%2052%5Cu2009K%20at%206%5Cu2009GPa%20for%20x%5Cu2009%3D%5Cu20090.2.%20In%20the%20phase%20diagram%2C%20the%20second%20parent%20phase%20at%20x%5Cu2009~%5Cu20090.5%20is%20suppressed%20by%20pressure%20as%20low%20as%20~1.5%5Cu2009GPa%20in%20contrast%20to%20the%20first%20parent%20phase%20at%20x%5Cu2009~%5Cu20090%2C%20which%20is%20robust%20against%20pressure.%20We%20suggest%20that%20certain%20spin-fluctuation%20from%20the%20second%20parent%20phase%20is%20strongly%20related%20to%20high-Tc%20under%20pressure.%22%2C%22date%22%3A%222016-12-22%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1038%5C%2Fsrep39646%22%2C%22ISSN%22%3A%222045-2322%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.nature.com%5C%2Farticles%5C%2Fsrep39646%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222021-04-23T02%3A36%3A43Z%22%7D%7D%5D%7D
(1)
Joonho B.; Satoru M.; Hideo H. アモルファスIGZO薄膜の水素とサブギャップ状態. Proceedings of the International Display Workshops (CD-ROM); 2016; Vol. 23rd, p ROMBUNNO.AMD7-4L.
(1)
Mizoguchi, H.; Okunaka, M.; Kitano, M.; Matsuishi, S.; Yokoyama, T.; Hosono, H. Hydride-Based Electride Material, LnH2 (Ln = La, Ce, or Y). Inorg. Chem. 2016, 55 (17), 8833–8838. https://doi.org/10.1021/acs.inorgchem.6b01369.
(1)
Hiraishi, M.; Kojima, K. M.; Miyazaki, M.; Yamauchi, I.; Okabe, H.; Koda, A.; Kadono, R.; Matsuishi, S.; Hosono, H. Cage Electron-Hydroxyl Complex State as Electron Donor in Mayenite. Phys. Rev. B 2016, 93 (12), 121201. https://doi.org/10.1103/PhysRevB.93.121201.
(1)
Iimura, S.; Matsuishi, S.; Hosono, H. Heavy Electron Doping Induced Antiferromagnetic Phase as the Parent for the Iron Oxypnictide Superconductor LaFeAsO1-xHx. Phys. Rev. B 2016, 94 (2), 024512. https://doi.org/10.1103/PhysRevB.94.024512.
(1)
MISHRA, S. K.; MITTAL, R.; R KRISHNA, P. S.; SASTRY, P. U.; CHAPLOT, S. L.; BABU, P. D.; MATSUISHI, S.; HOSONO, H. Thermal Expansion Behaviour and Phase Stability of AFe2As2 (A = Ca, Sr and Eu) Using Powder Diffraction Technique. Pramana - J Phys 2016, 86 (6), 1369–1381. https://doi.org/10.1007/s12043-016-1201-2.
(1)
Kitano, M.; Inoue, Y.; Ishikawa, H.; Yamagata, K.; Nakao, T.; Tada, T.; Matsuishi, S.; Yokoyama, T.; Hara, M.; Hosono, H. Essential Role of Hydride Ion in Ruthenium-Based Ammonia Synthesis Catalysts. Chem. Sci. 2016, 7 (7), 4036–4043. https://doi.org/10.1039/C6SC00767H.
(1)
Zhang, X.; Matsuishi, S.; Hosono, H. Critical Behavior and Magnetocaloric Effect in Layered Structure Tb2C. J. Phys. D: Appl. Phys. 2016, 49 (33), 335002. https://doi.org/10.1088/0022-3727/49/33/335002.
(1)
Kawaguchi, N.; Fujiwara, N.; Iimura, S.; Matsuishi, S.; Hosono, H. Experimental Evidence of Tc Enhancement without the Influence of Spin Fluctuations: NMR Study on LaFeAsO1-xHx under a Pressure of 3.0 GPa. Phys. Rev. B 2016, 94 (16), 161104. https://doi.org/10.1103/PhysRevB.94.161104.
(1)
Kobayashi, K.; Yamaura, J.; Iimura, S.; Maki, S.; Sagayama, H.; Kumai, R.; Murakami, Y.; Takahashi, H.; Matsuishi, S.; Hosono, H. Pressure Effect on Iron-Based Superconductor LaFeAsO 1−x H X : Peculiar Response of 1111-Type Structure. Scientific Reports 2016, 6 (1), 39646. https://doi.org/10.1038/srep39646.
244926
P5622579
2015
items
1
american-chemical-society-with-titles-sentence-case-doi
0
date
asc
year
6
https://www.mces.titech.ac.jp/authors/matsuishi/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-6901da677a6ff2919411f5f09eb4d0dc%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22RQPCWMAN%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Muraba%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMuraba%2C%20Y.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Hydrogen-Substituted%20Superconductors%20SmFeAsO%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%20Misidentified%20As%20Oxygen-Deficient%20SmFeAsO%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E.%20%3Ci%3EInorg.%20Chem.%3C%5C%2Fi%3E%20%3Cb%3E2015%3C%5C%2Fb%3E%2C%20%3Ci%3E54%3C%5C%2Fi%3E%20%2823%29%2C%2011567%26%23x2013%3B11573.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.5b02248%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.5b02248%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Hydrogen-Substituted%20Superconductors%20SmFeAsO%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%20Misidentified%20As%20Oxygen-Deficient%20SmFeAsO%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshinori%22%2C%22lastName%22%3A%22Muraba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20investigated%20the%20preferred%20electron%20dopants%20at%20the%20oxygen%20sites%20of%201111-type%20SmFeAsO%20by%20changing%20the%20atmospheres%20around%20the%20precursor%20with%20the%20composition%20of%20Sm%3AFe%3AAs%3AO%20%3D%201%3A1%3A1%3A1%20%3F%20x%20in%20high-pressure%20synthesis.%20Under%20H2O%20and%20H2%20atmospheres%2C%20hydrogens%20derived%20from%20H2O%20or%20H2%20molecules%20were%20introduced%20into%20the%20oxygen%20sites%20as%20a%20hydride%20ion%2C%20and%20SmFeAsO1%3FxHx%20was%20obtained.%20However%2C%20when%20the%20H2O%20and%20H2%20sources%20were%20removed%20from%20the%20synthetic%20process%2C%20nearly%20stoichiometric%20SmFeAsO%20was%20obtained%20and%20the%20maximum%20amount%20of%20oxygen%20vacancies%20introduced%20remained%20x%20%3D%200.05%284%29.%20Density%20functional%20theory%20calculations%20indicated%20that%20substitution%20of%20hydrogen%20in%20the%20form%20of%20H%3F%20is%20more%20stable%20than%20the%20formation%20of%20an%20oxygen%20vacancy%20at%20the%20oxygen%20site%20of%20SmFeAsO.%20These%20results%20strongly%20imply%20that%20oxygen-deficient%20SmFeAsO1%3Fx%20reported%20previously%20is%20SmFeAsO1%3FxHx%20with%20hydride%20ion%20incorporated%20unintentionally%20during%20high-pressure%20synthesis.%22%2C%22date%22%3A%2212%5Cu6708%207%2C%202015%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.inorgchem.5b02248%22%2C%22ISSN%22%3A%220020-1669%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.inorgchem.5b02248%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222023-09-11T06%3A37%3A10Z%22%7D%7D%2C%7B%22key%22%3A%22EKACPZC3%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bang%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EBang%2C%20J.%3B%20Matsuishi%2C%20S.%3B%20Maki%2C%20S.%3B%20Yamaura%2C%20J.%3B%20Hiraishi%2C%20M.%3B%20Takeshita%2C%20S.%3B%20Yamauchi%2C%20I.%3B%20Kojima%2C%20K.%20M.%3B%20Hosono%2C%20H.%20Low%20Dimensionalization%20of%20Magnetic%20Ordering%20in%20Sr%3Csub%3E2%3C%5C%2Fsub%3EVO%3Csub%3E4%3C%5C%2Fsub%3E%20by%20Hydride%20Ion%20Substitution.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2015%3C%5C%2Fb%3E%2C%20%3Ci%3E92%3C%5C%2Fi%3E%20%286%29%2C%20064414.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.92.064414%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.92.064414%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Low%20dimensionalization%20of%20magnetic%20ordering%20in%20Sr%3Csub%3E2%3C%5C%2Fsub%3EVO%3Csub%3E4%3C%5C%2Fsub%3E%20by%20hydride%20ion%20substitution%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joonho%22%2C%22lastName%22%3A%22Bang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sachiko%22%2C%22lastName%22%3A%22Maki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jun-ichi%22%2C%22lastName%22%3A%22Yamaura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masatoshi%22%2C%22lastName%22%3A%22Hiraishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Takeshita%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ichihiro%22%2C%22lastName%22%3A%22Yamauchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kenji%20M.%22%2C%22lastName%22%3A%22Kojima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Substitution%20of%20an%20oxygen%20anion%20with%20a%20hydrogen%20anion%20induced%20the%20low%20dimensionalization%20of%20magnetic%20ordering%20in%20a%20transition%20metal%20oxide%20Sr2VO4.%20Upon%20increasing%20x%20up%20to%20%5Cu223c1%20in%20Sr2VO4%5Cu2212xHx%2C%20the%20hydride%20ions%20were%20ordered%20linearly%2C%20and%20the%20magnetic%20susceptibility%20was%20simultaneously%20suppressed.%20It%20was%20found%20that%20this%20suppression%20was%20attributed%20to%20the%20formation%20of%20a%20quasi-one-dimensional%20antiferromagnetic%20spin%20chain%2C%20maintaining%20that%20each%20of%20the%20vanadium%20cations%20is%20two-dimensionally%20bridged%20by%20hydride%20and%20oxide%20ions.%20Density%20functional%20theory%20calculations%20demonstrate%20that%20the%20quasi-one-dimensional%20property%20is%20caused%20by%20much%20enhanced%20anisotropic%20exchange%20couplings%20%28J1%5C%2FJ2%5Cu223c6%29%20originating%20from%20the%20absence%20of%20%5Cu03c0%20bonding%20between%20H1s%20and%20V3d%20orbitals.%20Utilizing%20a%20hydride%20ion%20that%20has%20an%20ionic%20radius%20similar%20to%20an%20oxygen%20anion%20and%20only%20one%20energetically%20available%20orbital%20of%201s%20is%20a%20different%20approach%20to%20realization%20of%20magnetic%20low%20dimensionalization%20in%203d%20early%20transition%20metal%20oxides.%22%2C%22date%22%3A%228%5Cu6708%2011%2C%202015%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.92.064414%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.92.064414%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222019-04-15T02%3A54%3A11Z%22%7D%7D%2C%7B%22key%22%3A%22CB3M7USH%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Sakurai%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ESakurai%2C%20R.%3B%20Fujiwara%2C%20N.%3B%20Kawaguchi%2C%20N.%3B%20Yamakawa%2C%20Y.%3B%20Kontani%2C%20H.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Quantum%20Critical%20Behavior%20in%20Heavily%20Doped%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3EPnictide%20Superconductors%20Analyzed%20Using%20Nuclear%20Magnetic%20Resonance.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2015%3C%5C%2Fb%3E%2C%20%3Ci%3E91%3C%5C%2Fi%3E%20%286%29%2C%20064509.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.91.064509%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.91.064509%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Quantum%20critical%20behavior%20in%20heavily%20doped%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3Epnictide%20superconductors%20analyzed%20using%20nuclear%20magnetic%20resonance%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Sakurai%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Fujiwara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Kawaguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Yamakawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Kontani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20studied%20the%20quantum%20critical%20behavior%20of%20the%20second%20antiferromagnetic%20%28AF%29%20phase%20in%20the%20heavily%20electron-doped%20high-Tc%20pnictide%2C%20LaFeAsO1%5Cu2212xHx%2C%20by%20using%20a%2075As%20and%201H%20nuclear%20magnetic%20resonance%20%28NMR%29%20technique.%20In%20the%20second%20AF%20phase%2C%20we%20observed%20a%20spatially%20modulated%20spin-density-wave-like%20state%20up%20to%20x%3D0.6%20from%20the%20NMR%20spectral%20line%20shape%20and%20detected%20a%20low-energy%20excitation%20gap%20from%20the%20nuclear%20relaxation%20time%20T1%20of%2075As.%20The%20excitation%20gap%20closes%20at%20the%20AF%20quantum%20critical%20point%20%28QCP%29%20at%20x%5Cu22480.49.%20The%20superconducting%20phase%20in%20a%20lower-doping%20regime%20contacts%20the%20second%20AF%20phase%20only%20at%20the%20AF%20QCP%2C%20and%20both%20phases%20are%20segregated%20from%20each%20other.%20The%20absence%20of%20AF%20critical%20fluctuations%20and%20the%20enhancement%20of%20the%20in-plane%20electric%20anisotropy%20are%20key%20factors%20for%20the%20development%20of%20superconductivity.%22%2C%22date%22%3A%222%5Cu6708%2019%2C%202015%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.91.064509%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.91.064509%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A35%3A38Z%22%7D%7D%2C%7B%22key%22%3A%22MGWRWM5Z%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fujiwara%20et%20al.%22%2C%22parsedDate%22%3A%222015-01-01%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EFujiwara%2C%20N.%3B%20Kawaguchi%2C%20N.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Enhancement%20of%20Tc%20Due%20to%20Pressure%20Application%20in%20LaFeAsO%3Csub%3E1%26%23x2013%3B%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%20Studied%20by%20NMR.%20In%20%3Ci%3EPhysics%20Procedia%3C%5C%2Fi%3E%3B%2020th%20International%20Conference%20on%20Magnetism%2C%20ICM%202015%3B%202015%3B%20Vol.%2075%2C%20pp%2070%26%23x2013%3B76.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.phpro.2015.12.011%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.phpro.2015.12.011%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22conferencePaper%22%2C%22title%22%3A%22Enhancement%20of%20Tc%20Due%20to%20Pressure%20Application%20in%20LaFeAsO%3Csub%3E1%5Cu2013%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%20Studied%20by%20NMR%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Fujiwara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Kawaguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%20prototypical%20iron-based%20high-Tc%20pnictide%20LaFeAsO1%5Cu2013xHx%20has%20superconducting%20double%20domes%20in%20the%20electronic%20phase%20diagram.%20Pressure%20application%20merges%20the%20double%20domes%20into%20a%20single%20dome%2C%20and%20the%20minimum%20Tc%20of%2026K%20observed%20at%20x%3D0.2%20goes%20up%20to%2045K%20by%20applying%20a%20pressure%20of%203.0GPa.%2075As%20nuclear%20magnetic%20resonance%20was%20performed%20at%203.0GPa%20to%20investigate%20the%20high-Tc%20mechanism.%20The%20relaxation%20rate%20divided%20by%20temperature%2C%201%5C%2FT1T%20exhibits%20a%20plateau%20just%20above%20Tc%20and%20the%20value%20is%20enhanced%20by%20applying%20pressure.%20The%20plateau%20indicates%20that%201%5C%2FT1%20can%20be%20described%20by%20the%20Korringa%20relation%2C%20which%20suggests%20that%20a%20key%20factor%20to%20raise%20Tc%20is%20the%20density%20of%20states.%20So%20far%20as%20our%20results%20are%20concerned%2C%20spin%20fluctuations%20are%20not%20essential%20to%20achieve%20high%20Tc%20over%2045K.%22%2C%22date%22%3A%222015-01-01%22%2C%22proceedingsTitle%22%3A%22Physics%20Procedia%22%2C%22conferenceName%22%3A%2220th%20International%20Conference%20on%20Magnetism%2C%20ICM%202015%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.phpro.2015.12.011%22%2C%22ISBN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS1875389215016508%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222023-08-29T06%3A46%3A33Z%22%7D%7D%2C%7B%22key%22%3A%22HUFB8972%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Takahashi%20et%20al.%22%2C%22parsedDate%22%3A%222015-01-16%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ETakahashi%2C%20H.%3B%20Soeda%2C%20H.%3B%20Nukii%2C%20M.%3B%20Kawashima%2C%20C.%3B%20Nakanishi%2C%20T.%3B%20Iimura%2C%20S.%3B%20Muraba%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Superconductivity%20at%2052%20K%20in%20Hydrogen-Substituted%20LaFeAsO%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%20under%20High%20Pressure.%20%3Ci%3EScientific%20Reports%3C%5C%2Fi%3E%20%3Cb%3E2015%3C%5C%2Fb%3E%2C%20%3Ci%3E5%3C%5C%2Fi%3E%2C%207829.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fsrep07829%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fsrep07829%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Superconductivity%20at%2052%20K%20in%20hydrogen-substituted%20LaFeAsO%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%20under%20high%20pressure%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Takahashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Soeda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Nukii%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Kawashima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Nakanishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Muraba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222015-1-16%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1038%5C%2Fsrep07829%22%2C%22ISSN%22%3A%222045-2322%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.nature.com%5C%2Farticles%5C%2Fsrep07829%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222023-09-11T06%3A36%3A50Z%22%7D%7D%2C%7B%22key%22%3A%22CWG68G48%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hosono%20et%20al.%22%2C%22parsedDate%22%3A%222015-03-13%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHosono%2C%20H.%3B%20Kim%2C%20S.-W.%3B%20Matsuishi%2C%20S.%3B%20Tanaka%2C%20S.%3B%20Miyake%2C%20A.%3B%20Kagayama%2C%20T.%3B%20Shimizu%2C%20K.%20Superconductivity%20in%20Room-Temperature%20Stable%20Electride%20and%20High-Pressure%20Phases%20of%20Alkali%20Metals.%20%3Ci%3EPhilosophical%20Transactions%20of%20the%20Royal%20Society%20of%20London%20A%3A%20Mathematical%2C%20Physical%20and%20Engineering%20Sciences%3C%5C%2Fi%3E%20%3Cb%3E2015%3C%5C%2Fb%3E%2C%20%3Ci%3E373%3C%5C%2Fi%3E%20%282037%29%2C%2020140450.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1098%5C%2Frsta.2014.0450%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1098%5C%2Frsta.2014.0450%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Superconductivity%20in%20room-temperature%20stable%20electride%20and%20high-pressure%20phases%20of%20alkali%20metals%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sung-Wng%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shigeki%22%2C%22lastName%22%3A%22Tanaka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Atsushi%22%2C%22lastName%22%3A%22Miyake%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomoko%22%2C%22lastName%22%3A%22Kagayama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katsuya%22%2C%22lastName%22%3A%22Shimizu%22%7D%5D%2C%22abstractNote%22%3A%22S-band%20metals%20such%20as%20alkali%20and%20alkaline%20earth%20metals%20do%20not%20undergo%20a%20superconducting%20transition%20%28SCT%29%20at%20ambient%20pressure%2C%20but%20their%20high-pressure%20phases%20do.%20By%20contrast%2C%20room-temperature%20stable%20electride%20%5BCa24Al28O64%5D4%2B%5Cu22c54e%5Cu2212%20%28C12A7%3Ae%5Cu2212%29%20in%20which%20anionic%20electrons%20in%20the%20crystallographic%20sub-nanometer-size%20cages%20have%20high%20s-character%20exhibits%20SCT%20at%200.2%5Cu20130.4%20K%20at%20ambient%20pressure.%20In%20this%20paper%2C%20we%20report%20that%20crystal%20and%20electronic%20structures%20of%20C12A7%3Ae%5Cu2212%20are%20close%20to%20those%20of%20the%20high-pressure%20superconducting%20phase%20of%20alkali%20and%20alkaline%20earth%20metals%20and%20the%20SCT%20of%20both%20materials%20is%20induced%20when%20electron%20nature%20at%20Fermi%20energy%20%28EF%29%20switches%20from%20s-%20to%20sd-hybridized%20state.%22%2C%22date%22%3A%222015%5C%2F03%5C%2F13%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1098%5C%2Frsta.2014.0450%22%2C%22ISSN%22%3A%221364-503X%2C%201471-2962%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Frsta.royalsocietypublishing.org%5C%2Fcontent%5C%2F373%5C%2F2037%5C%2F20140450%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-07-15T01%3A03%3A49Z%22%7D%7D%2C%7B%22key%22%3A%22SCQT8HQ3%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Jeong%20et%20al.%22%2C%22parsedDate%22%3A%222015-04-01%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EJeong%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Bang%2C%20J.%3B%20Hosono%2C%20H.%20Crystal%20Structure%20and%20Physical%20Properties%20of%20New%20Transition%20Metal%20Based%20Pnictide%20Compounds%3A%20LaTM%3Csub%3E2%3C%5C%2Fsub%3EAsN%20%28TM%20%3D%20Fe%2C%20Co%2C%20and%20Ni%29.%20%3Ci%3EAPL%20Materials%3C%5C%2Fi%3E%20%3Cb%3E2015%3C%5C%2Fb%3E%2C%20%3Ci%3E3%3C%5C%2Fi%3E%20%284%29%2C%20041509.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4913395%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4913395%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Crystal%20structure%20and%20physical%20properties%20of%20new%20transition%20metal%20based%20pnictide%20compounds%3A%20LaTM%3Csub%3E2%3C%5C%2Fsub%3EAsN%20%28TM%20%3D%20Fe%2C%20Co%2C%20and%20Ni%29%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sehoon%22%2C%22lastName%22%3A%22Jeong%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joonho%22%2C%22lastName%22%3A%22Bang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22New%203d%20transition%20metal-based%20mixed-pnictide%20compounds%2C%20LaTM%202AsN%20%28TM%20%3D%20Fe%2C%20Co%2C%20and%20Ni%29%20are%20synthesized%20by%20solid%20state%20reactions%20under%20a%20high%20pressure%20of%202.5%20GPa.%20These%20compounds%20crystallize%20with%20an%20orthorhombic%20structure%20%28space%20group%20Cmcm%29%20containing%20four%20formula%20units%20per%20unit%20cell.%20The%20crystal%20structure%20consists%20of%20an%20anisotropic%20network%20of%20TMAs3N%20tetrahedra%20sharing%20As-As%20edges%20along%20the%20in-plane%20ac%20direction%20and%20N%20corners%20along%20the%20b-direction%2C%20forming%20a%20TM%20honeycomb%20lattice%20with%20a%20boat-shape%20conformation%20bridged%20by%20TM-N-TM%20linear%20bonds.%20The%20temperature%20dependences%20of%20the%20electrical%20resistivity%20and%20magnetic%20susceptibility%20indicate%20that%20these%20crystals%20are%20itinerant%20antiferromagnets%20exhibiting%20parasitic%20ferromagnetism%20with%20transition%20temperatures%20of%20560%2C%20260%2C%20and%20410%20K%20for%20TM%20%3D%20Fe%2C%20Co%2C%20and%20Ni%2C%20respectively.%20These%20compounds%20are%20expected%20to%20be%20parent%20materials%20for%20new%20superconductors.%22%2C%22date%22%3A%222015%5C%2F04%5C%2F01%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F1.4913395%22%2C%22ISSN%22%3A%222166-532X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fscitation.aip.org%5C%2Fcontent%5C%2Faip%5C%2Fjournal%5C%2Faplmater%5C%2F3%5C%2F4%5C%2F10.1063%5C%2F1.4913395%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T04%3A01%3A05Z%22%7D%7D%5D%7D
(1)
Muraba, Y.; Iimura, S.; Matsuishi, S.; Hosono, H. Hydrogen-Substituted Superconductors SmFeAsO1-xHx Misidentified As Oxygen-Deficient SmFeAsO1-x. Inorg. Chem. 2015, 54 (23), 11567–11573. https://doi.org/10.1021/acs.inorgchem.5b02248.
(1)
Bang, J.; Matsuishi, S.; Maki, S.; Yamaura, J.; Hiraishi, M.; Takeshita, S.; Yamauchi, I.; Kojima, K. M.; Hosono, H. Low Dimensionalization of Magnetic Ordering in Sr2VO4 by Hydride Ion Substitution. Phys. Rev. B 2015, 92 (6), 064414. https://doi.org/10.1103/PhysRevB.92.064414.
(1)
Sakurai, R.; Fujiwara, N.; Kawaguchi, N.; Yamakawa, Y.; Kontani, H.; Iimura, S.; Matsuishi, S.; Hosono, H. Quantum Critical Behavior in Heavily Doped LaFeAsO1-xHxPnictide Superconductors Analyzed Using Nuclear Magnetic Resonance. Phys. Rev. B 2015, 91 (6), 064509. https://doi.org/10.1103/PhysRevB.91.064509.
(1)
Fujiwara, N.; Kawaguchi, N.; Iimura, S.; Matsuishi, S.; Hosono, H. Enhancement of Tc Due to Pressure Application in LaFeAsO1–xHx Studied by NMR. In Physics Procedia; 20th International Conference on Magnetism, ICM 2015; 2015; Vol. 75, pp 70–76. https://doi.org/10.1016/j.phpro.2015.12.011.
(1)
Takahashi, H.; Soeda, H.; Nukii, M.; Kawashima, C.; Nakanishi, T.; Iimura, S.; Muraba, Y.; Matsuishi, S.; Hosono, H. Superconductivity at 52 K in Hydrogen-Substituted LaFeAsO1-xHx under High Pressure. Scientific Reports 2015, 5, 7829. https://doi.org/10.1038/srep07829.
(1)
Hosono, H.; Kim, S.-W.; Matsuishi, S.; Tanaka, S.; Miyake, A.; Kagayama, T.; Shimizu, K. Superconductivity in Room-Temperature Stable Electride and High-Pressure Phases of Alkali Metals. Philosophical Transactions of the Royal Society of London A: Mathematical, Physical and Engineering Sciences 2015, 373 (2037), 20140450. https://doi.org/10.1098/rsta.2014.0450.
(1)
Jeong, S.; Matsuishi, S.; Bang, J.; Hosono, H. Crystal Structure and Physical Properties of New Transition Metal Based Pnictide Compounds: LaTM2AsN (TM = Fe, Co, and Ni). APL Materials 2015, 3 (4), 041509. https://doi.org/10.1063/1.4913395.
244926
P5622579
2014
items
1
american-chemical-society-with-titles-sentence-case-doi
0
date
asc
year
6
https://www.mces.titech.ac.jp/authors/matsuishi/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-356861ca4d40a80ed670ed954eb661de%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22A5M7Q7IN%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Matsuishi%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMatsuishi%2C%20S.%3B%20Muramatsu%2C%20H.%3B%20Hosono%2C%20H.%20Photochemistry%20of%20Nanocage%20Ca%3Csub%3E12%3C%5C%2Fsub%3EAl%3Csub%3E14%26%23x2212%3B%3C%5C%2Fsub%3E%3Ci%3E%3Csub%3Ex%3C%5C%2Fsub%3E%3C%5C%2Fi%3ESi%3Ci%3E%3Csub%3Ex%3C%5C%2Fsub%3E%3C%5C%2Fi%3EO%3Csub%3E32%3C%5C%2Fsub%3ECl%3Csub%3E2%2B%3C%5C%2Fsub%3E%3Ci%3E%3Csub%3Ex%3C%5C%2Fsub%3E%3C%5C%2Fi%3E%20%28%3Ci%3Ex%3C%5C%2Fi%3E%20%3D%200.0%20and%203.4%29%20Crystals.%20%3Ci%3EChemistry%20Letters%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E43%3C%5C%2Fi%3E%20%288%29%2C%201371%26%23x2013%3B1373.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1246%5C%2Fcl.140423%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1246%5C%2Fcl.140423%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Photochemistry%20of%20Nanocage%20Ca%3Csub%3E12%3C%5C%2Fsub%3EAl%3Csub%3E14%5Cu2212%3C%5C%2Fsub%3E%3Ci%3E%3Csub%3Ex%3C%5C%2Fsub%3E%3C%5C%2Fi%3ESi%3Ci%3E%3Csub%3Ex%3C%5C%2Fsub%3E%3C%5C%2Fi%3EO%3Csub%3E32%3C%5C%2Fsub%3ECl%3Csub%3E2%2B%3C%5C%2Fsub%3E%3Ci%3E%3Csub%3Ex%3C%5C%2Fsub%3E%3C%5C%2Fi%3E%20%28%3Ci%3Ex%3C%5C%2Fi%3E%20%3D%200.0%20and%203.4%29%20Crystals%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroki%22%2C%22lastName%22%3A%22Muramatsu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20observed%20the%20photogenerated%20color%20centers%20in%20Ca12Al14%5Cu2212xSixO32Cl2%2Bx%20analogs%20of%20Ca12Al14O33%20%28C12A7%29%20crystals%20with%20crystallographic%20subnanometer-sized%20cages%20partially%20occupied%20by%20Cl%20ions.%20Excimer%20laser%20irradiation%20created%20electrons%20trapped%20in%20the%20cages%20and%20holes%20on%20nonbridging%20oxygen%202p%20orbitals%2C%20accompanied%20by%20the%20formation%20of%20O%5Cu2212%2C%20H0%2C%20and%20H%5Cu2212.%20These%20centers%20were%20gradually%20erased%20at%20room%20temperature%20in%20ca.%2030%20min.%20These%20results%20demonstrate%20that%20the%20cages%20in%20C12A7%20analogs%20act%20as%20traps%20for%20active%20anionic%20species%20and%20electrons%20generated%20by%20light%20excitation.%22%2C%22date%22%3A%222014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1246%5C%2Fcl.140423%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T01%3A41%3A38Z%22%7D%7D%2C%7B%22key%22%3A%22ZTUTQQNU%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Ishida%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EIshida%2C%20J.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20%20and%20H.%20Comparison%20of%20Impurity%20Effect%20between%20Two%20T%3Csub%3Ec%3C%5C%2Fsub%3E%20Domes%20in%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E.%20%3Ci%3EJ.%20Phys.%3A%20Condens.%20Matter%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E26%3C%5C%2Fi%3E%20%2843%29%2C%20435702.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F0953-8984%5C%2F26%5C%2F43%5C%2F435702%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F0953-8984%5C%2F26%5C%2F43%5C%2F435702%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Comparison%20of%20impurity%20effect%20between%20two%20T%3Csub%3Ec%3C%5C%2Fsub%3E%20domes%20in%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Junichi%22%2C%22lastName%22%3A%22Ishida%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22and%20Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Hydrogen-doped%20LaFeAsO%201%5Cu2212%20x%20H%20x%20system%20has%20a%20unique%202-dome%20structure.%20The%20effects%20of%20Zn%20impurities%20on%20the%20first%20and%20second%20superconducting%20domes%20in%20LaFe%201%5Cu2212%20y%20Zn%20y%20AsO%201%5Cu2212%20x%20H%20x%20%28%20x%20%3D%200.10%20for%20the%20first%20superconducting%20phase%20%28SC1%29%20and%200.35%20for%20the%20second%20superconducting%20phase%20%28SC2%29%29%20are%20examined%20by%20electrical%20resistivity%2C%20Hall%20effect%20and%20magnetization%20measurements.%20Substitution%20with%20Zn%20strongly%20suppresses%20the%20critical%20temperature%20%28%20T%20c%20%29%20and%20behaves%20as%20a%20nonmagnetic%20impurity.%20The%20suppression%20rates%20are%3A%2017%284%29%20K%5C%2F%25%20%28SC1%29%20and%206.9%285%29%20K%5C%2F%25%20%28SC2%29.%20It%20was%20considered%20that%20Zn%20impurities%20induced%20Anderson%20localization%2C%20which%20triggered%20the%20disappearance%20of%20the%20superconductivity%2C%20but%20no%20decisive%20conclusions%20on%20the%20dominant%20pairing%20symmetry%20for%20each%20dome%20were%20obtained.%22%2C%22date%22%3A%222014%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1088%5C%2F0953-8984%5C%2F26%5C%2F43%5C%2F435702%22%2C%22ISSN%22%3A%220953-8984%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fstacks.iop.org%5C%2F0953-8984%5C%2F26%5C%2Fi%3D43%5C%2Fa%3D435702%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A51%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22F5ZXTC9D%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hiraishi%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHiraishi%2C%20M.%3B%20Iimura%2C%20S.%3B%20Kojima%2C%20K.%20M.%3B%20Yamaura%2C%20J.%3B%20Hiraka%2C%20H.%3B%20Ikeda%2C%20K.%3B%20Miao%2C%20P.%3B%20Ishikawa%2C%20Y.%3B%20Torii%2C%20S.%3B%20Miyazaki%2C%20M.%3B%20Yamauchi%2C%20I.%3B%20Koda%2C%20A.%3B%20Ishii%2C%20K.%3B%20Yoshida%2C%20M.%3B%20Mizuki%2C%20J.%3B%20Kadono%2C%20R.%3B%20Kumai%2C%20R.%3B%20Kamiyama%2C%20T.%3B%20Otomo%2C%20T.%3B%20Murakami%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Bipartite%20Magnetic%20Parent%20Phases%20in%20the%20Iron%20Oxypnictide%20Superconductor.%20%3Ci%3ENat%20Phys%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E10%3C%5C%2Fi%3E%20%284%29%2C%20300%26%23x2013%3B303.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fnphys2906%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fnphys2906%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Bipartite%20magnetic%20parent%20phases%20in%20the%20iron%20oxypnictide%20superconductor%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Hiraishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%20M.%22%2C%22lastName%22%3A%22Kojima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Yamaura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hiraka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Ikeda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Miao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Ishikawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Torii%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Miyazaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22I.%22%2C%22lastName%22%3A%22Yamauchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Koda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Ishii%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Yoshida%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Mizuki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Kadono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Kumai%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Kamiyama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Otomo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Murakami%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22High-temperature%20superconductivity%20appears%20as%20a%20consequence%20of%20doping%20charge%20carriers%20into%20an%20undoped%20parent%20compound%20exhibiting%20antiferromagnetic%20order%3B%20therefore%2C%20ground-state%20properties%20of%20the%20parent%20compound%20are%20highly%20relevant%20to%20the%20superconducting%20state.%20On%20the%20basis%20of%20this%20logic%2C%20spin%20fluctuations%20have%20been%20considered%20as%20the%20origin%20of%20pairing%20of%20the%20superconducting%20electrons%20in%20the%20cuprates.%20As%20possible%20pairing%20mechanisms%2C%20there%20is%20growing%20interest%20in%20unconventional%20spin%20fluctuations%20or%20advanced%20orbital%20fluctuations%20owing%20to%20the%20characteristic%20multi-orbital%20states%20in%20iron%20pnictides.%20Here%2C%20we%20report%20the%20discovery%20of%20an%20antiferromagnetic%20phase%20as%20well%20as%20a%20unique%20structural%20transition%20in%20electron-overdoped%20LaFeAsO1%5Cu2212xHx%20%28x%20%5Cu223c%200.5%29%2C%20whereby%20a%20second%20parent%20phase%20is%20uncovered%2C%20albeit%20heavily%20doped.%20The%20unprecedented%20two-dome%20superconducting%20phases%20observed%20in%20this%20material%20can%20be%20interpreted%20as%20a%20consequence%20of%20the%20carrier%20doping%20starting%20from%20the%20original%20x%20%5Cu223c%200%20and%20additional%20x%20%5Cu223c%200.5%20parent%20phases%20towards%20the%20intermediate%20region.%20The%20bipartite%20parent%20phases%20with%20distinct%20physical%20properties%20in%20the%20second%20magnetic%20phase%20provide%20us%20with%20an%20interesting%20example%20to%20illustrate%20the%20intimate%20interplay%20between%20the%20magnetic%20interaction%2C%20structural%20change%20and%20orbital%20degree%20of%20freedom%20in%20iron%20pnictide%20superconductors.%22%2C%22date%22%3A%224%5Cu6708%202014%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1038%5C%2Fnphys2906%22%2C%22ISSN%22%3A%221745-2473%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.nature.com%5C%2Fnphys%5C%2Fjournal%5C%2Fv10%5C%2Fn4%5C%2Ffull%5C%2Fnphys2906.html%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222014-05-15T12%3A51%3A33Z%22%7D%7D%2C%7B%22key%22%3A%22BCQHRBMX%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Muraba%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMuraba%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Enhancing%20the%20Three-Dimensional%20Electronic%20Structure%20in%201111-Type%20Iron%20Arsenide%20Superconductors%20by%20H%20Substitution.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E89%3C%5C%2Fi%3E%20%289%29%2C%20094501.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.89.094501%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.89.094501%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Enhancing%20the%20three-dimensional%20electronic%20structure%20in%201111-type%20iron%20arsenide%20superconductors%20by%20H%20substitution%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshinori%22%2C%22lastName%22%3A%22Muraba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%201111-type%20iron%20arsenide%20hydride%20CaFe1%5Cu2212xCoxAsH%20was%20synthesized%20by%20high-pressure%20solid-state%20reaction%2C%20and%20its%20electronic%20structure%20and%20superconducting%20properties%20were%20investigated.%20Bulk%20superconductivity%20was%20observed%20at%20x%20%3D%200.09%5Cu20130.26.%20A%20maximum%20superconducting%20critical%20temperature%20%28Tmaxc%29%20of%2023%20K%20was%20observed%20at%20x%20%3D%200.09.%20These%20values%20are%20in%20agreement%20with%20those%20of%20CaFe1%5Cu2212xCoxAsF.%20The%20calculated%20Fermi%20surface%20of%20CaFeAsH%20has%20a%20small%20three-dimensional%20%283D%29%20hole%20pocket%20around%20the%20%5Cu0393%20point.%20This%20is%20a%20result%20of%20weak%20covalent%20bonding%20between%20the%20As%204p%20and%20H%201s%20orbitals.%20No%20such%20covalency%20exists%20in%20CaFeAsF%2C%20because%20the%20energy%20level%20of%20the%20F%202p%20orbital%20is%20sufficiently%20deep%20to%20inhibit%20overlap%20with%20the%20As%204p%20orbital.%20The%20similar%20superconductivities%20of%20CaFe1%5Cu2212xCoxAsH%20and%20CaFe1%5Cu2212xCoxAsF%20are%20explained%20with%20the%20nesting%20scenario.%20The%20small%203D%20hole%20pocket%20of%20CaFe1%5Cu2212xCoxAsH%20does%20not%20significantly%20contribute%20to%20electron%20excitation.%20These%20findings%20encourage%20exploration%20of%20hydrogen-containing%201111-type%20iron-based%20materials%20with%20lower%20anisotropies%20and%20higher%20Tc%20applicable%20to%20superconducting%20wires%20and%20tapes.%22%2C%22date%22%3A%223%5Cu6708%203%2C%202014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.89.094501%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.89.094501%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222016-04-15T01%3A45%3A44Z%22%7D%7D%2C%7B%22key%22%3A%22UXIM884B%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Tada%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ETada%2C%20T.%3B%20Takemoto%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20High-Throughput%20Ab%20Initio%20Screening%20for%20Two-Dimensional%20Electride%20Materials.%20%3Ci%3EInorg.%20Chem.%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E53%3C%5C%2Fi%3E%20%2819%29%2C%2010347%26%23x2013%3B10358.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fic501362b%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fic501362b%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22High-Throughput%20ab%20Initio%20Screening%20for%20Two-Dimensional%20Electride%20Materials%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomofumi%22%2C%22lastName%22%3A%22Tada%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Seiji%22%2C%22lastName%22%3A%22Takemoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22High-throughput%20ab%20initio%20screening%20of%20approximately%2034000%20materials%20in%20the%20Materials%20Project%20was%20conducted%20to%20identify%20two-dimensional%20%282D%29%20electride%20materials%2C%20which%20are%20composed%20of%20cationic%20layers%20and%20anionic%20electrons%20confined%20in%20a%202D%20empty%20space.%20The%20screening%20was%20based%20on%20three%20indicators%3A%20%281%29%20a%20positive%20total%20formal%20charge%20per%20formula%20unit%3B%20%282%29%20layered%20structures%20for%20two-dimensionality%3B%20%283%29%20empty%20spaces%20between%20the%20layer%20units.%20Three%20nitrides%2C%20Ca2N%2C%20Sr2N%2C%20and%20Ba2N%2C%20and%20the%20carbide%20Y2C%20were%20identified%20as%202D%20electrides%2C%20where%20Ca2N%20is%20the%20only%20experimentally%20confirmed%202D%20electride%20%28Lee%2C%20K.%3B%20et%20al.%20Nature%202013%2C%20494%2C%20336%3F341%29.%20Electron%20density%20analysis%20using%20ionic%20radii%20revealed%20a%20smaller%20number%20of%20anionic%20electrons%20in%20Y2C%20than%20those%20in%20the%20three%20nitrides%20as%20a%20result%20of%20the%20partial%20occupation%20of%20the%20anionic%20electrons%20in%20the%20d%20orbitals%20of%20Y.%20In%20addition%2C%20no%20candidates%20were%20identified%20from%20the%20p-block%20elements%2C%20and%20thus%20the%20ab%20initio%20screening%20indicates%20that%20the%20s-block%20elements%20%28i.e.%2C%20alkali%20or%20alkaline-earth%20metals%29%20are%20highly%20preferable%20as%20cation%20elements.%20To%20go%20beyond%20the%20database%20screening%2C%20a%20tailored%20modeling%20was%20conducted%20to%20determine%20unexplored%20compounds%20including%20the%20s-block%20elements%20that%20are%20suitable%20for%202D%20electrides.%20The%20tailored%20modeling%20found%20that%20%281%29%20K2Cl%2C%20K2Br%2C%20Rb2Cl%2C%20and%20Rb2Br%20dialkali%20halides%20are%20highly%20plausible%20candidates%2C%20%282%29%20Li2F%20and%20Na2Cl%20dialkali%20halides%20are%20highly%20challenging%20candidates%2C%20and%20%283%29%20the%20Cs2O1%3FxFx%20halogen-doped%20dialkali%20oxide%20is%20a%20promising%20candidate.%22%2C%22date%22%3A%2210%5Cu6708%206%2C%202014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Fic501362b%22%2C%22ISSN%22%3A%220020-1669%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Fic501362b%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T01%3A40%3A45Z%22%7D%7D%2C%7B%22key%22%3A%22CB486RWH%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Matsuishi%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMatsuishi%2C%20S.%3B%20Maruyama%2C%20T.%3B%20Iimura%2C%20S.%3B%20Hosono%2C%20H.%20Controlling%20Factors%20of%20%24T%3Csub%3Ec%3C%5C%2Fsub%3E%20Dome%20Structure%20in%201111-Type%20Iron%20Arsenide%20Superconductors.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E89%3C%5C%2Fi%3E%20%289%29%2C%20094510.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.89.094510%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.89.094510%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Controlling%20factors%20of%20%24T%3Csub%3Ec%3C%5C%2Fsub%3E%20dome%20structure%20in%201111-type%20iron%20arsenide%20superconductors%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takuya%22%2C%22lastName%22%3A%22Maruyama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20investigated%20the%20effects%20of%20phosphorus%20substitution%20on%20the%20shape%20of%20the%20Tc%28x%29%20dome%20in%201111-type%20SmFeAs1%5Cu2212yPyO1%5Cu2212xHx%20%280%3Cx%3C0.5%29.%20Hydride%20ion%20substitution%20of%20oxide%20sites%20%28O2%5Cu2212%5Cu2192H%5Cu2212%29%20exerts%20a%20chemical%20pressure%20effect%2C%20i.e.%2C%20a%20structural%20reduction%20of%20the%20Pn%5Cu2212Fe%5Cu2212Pn%20angle%20%5Cu03b1%20%28Pn%3DP%2CAs%29%20and%20also%20dopes%20electrons%20into%20the%20FePn%20layer%20to%20induce%20superconductivity.%20Isovalent%20phosphorus%20substitution%20%28P3%5Cu2212%5Cu2192As3%5Cu2212%29%20can%20induce%20only%20a%20chemical%20pressure%20effect%2C%20i.e.%2C%20an%20increase%20of%20%5Cu03b1%20for%20La%20substitution%20of%20Sm%20sites.%20As%20y%20increases%20from%200.0%20to%200.5%2C%20the%20single%20Tc%20dome%20gradually%20splits%20into%20two%20domes%2C%20similar%20to%20those%20of%20LaFeAsO1%5Cu2212xHx%20with%20a%20Tc%20valley%20at%20x%5Cu22480.16.%20We%20found%20that%20the%20Tc%20valley%20is%20located%20around%20%28x%2C%5Cu03b1%29%5Cu2248%280.16%2C113%5Cu00b0%29%20for%20both%20of%20the%20SmFeAs1%5Cu2212yPyO1%5Cu2212xHx%20and%20LaFeAsO1%5Cu2212xHx%20series%2C%20irrespective%20of%20changes%20in%20the%20Pn%20anion%20and%20Ln%20cation%20species.%20This%20result%20suggests%20that%20suppression%20of%20Tc%20leads%20to%20the%20emergence%20of%20a%20Tc%20valley%20when%20both%20the%20shape%20of%20FePn4%20tetrahedra%20represented%20by%20%5Cu03b1%20and%20electron-doping%20level%20of%20x%20meet%20the%20above%20criterion%20in%201111-type%20iron%20oxypnictide%20superconductors.%22%2C%22date%22%3A%223%5Cu6708%2011%2C%202014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.89.094510%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.89.094510%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A50%3A33Z%22%7D%7D%2C%7B%22key%22%3A%2222SF4B97%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Suzuki%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ESuzuki%2C%20K.%3B%20Usui%2C%20H.%3B%20Iimura%2C%20S.%3B%20Sato%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Kuroki%2C%20K.%20Model%20of%20the%20Electronic%20Structure%20of%20Electron-Doped%20Iron-Based%20Superconductors%3A%20Evidence%20for%20Enhanced%20Spin%20Fluctuations%20by%20Diagonal%20Electron%20Hopping.%20%3Ci%3EPhys.%20Rev.%20Lett.%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E113%3C%5C%2Fi%3E%20%282%29%2C%20027002.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevLett.113.027002%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevLett.113.027002%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Model%20of%20the%20Electronic%20Structure%20of%20Electron-Doped%20Iron-Based%20Superconductors%3A%20Evidence%20for%20Enhanced%20Spin%20Fluctuations%20by%20Diagonal%20Electron%20Hopping%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katsuhiro%22%2C%22lastName%22%3A%22Suzuki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hidetomo%22%2C%22lastName%22%3A%22Usui%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshiyasu%22%2C%22lastName%22%3A%22Sato%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazuhiko%22%2C%22lastName%22%3A%22Kuroki%22%7D%5D%2C%22abstractNote%22%3A%22We%20present%20a%20theoretical%20understanding%20of%20the%20superconducting%20phase%20diagram%20of%20the%20electron-doped%20iron%20pnictides.%20We%20show%20that%2C%20besides%20the%20Fermi%20surface%20nesting%2C%20a%20peculiar%20motion%20of%20electrons%2C%20where%20the%20next%20nearest%20neighbor%20%28diagonal%29%20hoppings%20between%20iron%20sites%20dominate%20over%20the%20nearest%20neighbor%20ones%2C%20plays%20an%20important%20role%20in%20the%20enhancement%20of%20the%20spin%20fluctuation%20and%20thus%20superconductivity.%20In%20the%20highest%20Tc%20materials%2C%20the%20crossover%20between%20the%20Fermi%20surface%20nesting%20and%20this%20%5Cu201cprioritized%20diagonal%20motion%5Cu201d%20regime%20occurs%20smoothly%20with%20doping%2C%20while%20in%20relatively%20low%20Tc%20materials%2C%20the%20two%20regimes%20are%20separated%20and%20therefore%20results%20in%20a%20double%20dome%20Tc%20phase%20diagram.%22%2C%22date%22%3A%227%5Cu6708%2011%2C%202014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevLett.113.027002%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevLett.113.027002%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T04%3A03%3A29Z%22%7D%7D%2C%7B%22key%22%3A%228BE6SAD7%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Muraba%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMuraba%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20La-Substituted%20CaFeAsH%20Superconductor%20with%20%3Ci%3ET%3C%5C%2Fi%3E%3Csub%3Ec%3C%5C%2Fsub%3E%20%3D%2047%20K.%20%3Ci%3EJ.%20Phys.%20Soc.%20Jpn.%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E83%3C%5C%2Fi%3E%20%283%29%2C%20033705.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.7566%5C%2FJPSJ.83.033705%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.7566%5C%2FJPSJ.83.033705%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22La-Substituted%20CaFeAsH%20Superconductor%20with%20%3Ci%3ET%3C%5C%2Fi%3E%3Csub%3Ec%3C%5C%2Fsub%3E%20%3D%2047%20K%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshinori%22%2C%22lastName%22%3A%22Muraba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22La-substituted%20CaFeAsH%2C%20%28Ca1%5Cu2212xLax%29FeAsH%2C%20were%20synthesized%20by%20the%20solid%20state%20reaction%20at%201173%20K%20under%20high%20pressure%20of%202.5%20GPa.%20The%20%5Cu03c1%5Cu2013T%20anomaly%20corresponding%20to%20tetragonal%20to%20orthorhombic%20structural%20transition%20was%20suppressed%20by%20La-substitution%20and%20then%20the%20superconductivity%20was%20observed%20at%20an%20electron%20doping%20content%20of%20Ne%20%3E%200.05.%20The%20maximum%20onset%20Tc%20of%2047.4%20K%20was%20reached%20for%20Ne%20%3D%200.18%2C%20which%20is%20significant%20increase%20compared%20to%2023%20K%20achieved%20by%20direct%20electron%20doping%20to%20the%20FeAs-layer%20via%20Co-substitution%20to%20the%20Fe-site.%20This%20value%20of%20Tc%20value%20fits%20well%20to%20the%20phenomenological%20relation%20between%20Tc%20and%20the%20bond%20angle%20of%20As%5Cu2013Fe%5Cu2013As%20in%20indirectly%20electron%20doped%20LnFeAsO%20%28Ln%20%3D%20Lanthanide%29.%20These%20results%20indicate%20that%20the%20electron%20was%20doped%20via%20the%20indirect%20mode%20through%20the%20aliovalent%20ion%20substitution%20to%20CaH-layer%20%28Ca2%2B%20%5Cu2192%20La3%2B%20%2B%20e%5Cu2212%29.%22%2C%22date%22%3A%222%5Cu6708%2018%2C%202014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.7566%5C%2FJPSJ.83.033705%22%2C%22ISSN%22%3A%220031-9015%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fjournals.jps.jp%5C%2Fdoi%5C%2Fabs%5C%2F10.7566%5C%2FJPSJ.83.033705%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222023-09-11T06%3A37%3A20Z%22%7D%7D%2C%7B%22key%22%3A%22TX556AJR%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bang%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EBang%2C%20J.%3B%20Matsuishi%2C%20S.%3B%20Hiraka%2C%20H.%3B%20Fujisaki%2C%20F.%3B%20Otomo%2C%20T.%3B%20Maki%2C%20S.%3B%20Yamaura%2C%20J.%3B%20Kumai%2C%20R.%3B%20Murakami%2C%20Y.%3B%20Hosono%2C%20H.%20Hydrogen%20Ordering%20and%20New%20Polymorph%20of%20Layered%20Perovskite%20Oxyhydrides%3A%20Sr%3Csub%3E2%3C%5C%2Fsub%3EVO%3Csub%3E4-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E.%20%3Ci%3EJ.%20Am.%20Chem.%20Soc.%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E136%3C%5C%2Fi%3E%20%2820%29%2C%207221%26%23x2013%3B7224.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fja502277r%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fja502277r%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Hydrogen%20Ordering%20and%20New%20Polymorph%20of%20Layered%20Perovskite%20Oxyhydrides%3A%20Sr%3Csub%3E2%3C%5C%2Fsub%3EVO%3Csub%3E4-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joonho%22%2C%22lastName%22%3A%22Bang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Haruhiro%22%2C%22lastName%22%3A%22Hiraka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fumika%22%2C%22lastName%22%3A%22Fujisaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshiya%22%2C%22lastName%22%3A%22Otomo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sachiko%22%2C%22lastName%22%3A%22Maki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jun-ichi%22%2C%22lastName%22%3A%22Yamaura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Reiji%22%2C%22lastName%22%3A%22Kumai%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Youichi%22%2C%22lastName%22%3A%22Murakami%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Compositionally%20tunable%20vanadium%20oxyhydrides%20Sr2VO4%3FxHx%20%280%20%5Cu2264%20x%20%5Cu2264%201.01%29%20without%20considerable%20anion%20vacancy%20were%20synthesized%20by%20high-pressure%20solid-state%20reaction.%20The%20crystal%20structures%20and%20their%20properties%20were%20characterized%20by%20powder%20neutron%20diffraction%2C%20synchrotron%20X-ray%20diffraction%2C%20thermal%20desorption%20spectroscopy%2C%20and%20first-principles%20density%20functional%20theory%20%28DFT%29%20calculations.%20The%20hydrogen%20anions%20selectively%20replaced%20equatorial%20oxygen%20sites%20in%20the%20VO6%20layers%20via%20statistical%20substitution%20of%20hydrogen%20in%20the%20low%20x%20region%20%28x%20%3C%200.2%29.%20A%20new%20orthorhombic%20phase%20%28Immm%29%20with%20an%20almost%20entirely%20hydrogen-ordered%20structure%20formed%20from%20the%20K2NiF4-type%20tetragonal%20phase%20with%20x%20%3E%200.7.%20Based%20on%20the%20DFT%20calculations%2C%20the%20degree%20of%20oxygen%5C%2Fhydrogen%20anion%20ordering%20is%20strongly%20correlated%20with%20the%20bonding%20interaction%20between%20vanadium%20and%20the%20ligands.%22%2C%22date%22%3A%225%5Cu6708%2021%2C%202014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Fja502277r%22%2C%22ISSN%22%3A%220002-7863%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Fja502277r%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A41%3A10Z%22%7D%7D%2C%7B%22key%22%3A%22G8GGQ94G%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Zhang%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EZhang%2C%20X.%3B%20Xiao%2C%20Z.%3B%20Lei%2C%20H.%3B%20Toda%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Kamiya%2C%20T.%3B%20Ueda%2C%20S.%3B%20Hosono%2C%20H.%20Two-Dimensional%20Transition-Metal%20Electride%20Y%3Csub%3E2%3C%5C%2Fsub%3EC.%20%3Ci%3EChem.%20Mater.%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E26%3C%5C%2Fi%3E%20%2822%29%2C%206638%26%23x2013%3B6643.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fcm503512h%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fcm503512h%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Two-Dimensional%20Transition-Metal%20Electride%20Y%3Csub%3E2%3C%5C%2Fsub%3EC%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xiao%22%2C%22lastName%22%3A%22Zhang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zewen%22%2C%22lastName%22%3A%22Xiao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hechang%22%2C%22lastName%22%3A%22Lei%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshitake%22%2C%22lastName%22%3A%22Toda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshio%22%2C%22lastName%22%3A%22Kamiya%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shigenori%22%2C%22lastName%22%3A%22Ueda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Electrides%20are%20ionic%20crystals%20in%20which%20the%20anionic%20electrons%20are%20confined%20to%20interstitial%20subnanometer-sized%20spaces.%20At%20present%2C%20the%20reported%20electrides%20only%20consist%20of%20main-group%20elements.%20Here%2C%20we%20report%20a%20layered-structure%20transition-metal%20hypocarbide%20electride%2C%20Y2C%2C%20with%20quasi-two-dimensional%20%28quasi-2D%29%20anionic%20electrons%20confined%20in%20the%20interlayer%20space.%20Physical%20properties%20measurements%20reveal%20polycrystalline%20Y2C%20exhibits%20semimetallic%20behavior%2C%20and%20paramagnetism%20with%20an%20effective%20magnetic%20moment%20of%20%3F0.6%20%3FB%5C%2FY%2C%20because%20of%20the%20existence%20of%20localized%20d-electrons.%20Photoelectron%20spectroscopy%20measurements%20illustrate%20the%20work%20function%20of%20polycrystalline%20Y2C%20is%202.9%20eV%2C%20lower%20than%20Y%20metal%2C%20revealing%20the%20loosely%20bound%20nature%20of%20the%20anionic%20electrons.%20Density%20functional%20theory%20calculations%20indicate%20the%20density%20of%20states%20at%20the%20Fermi%20level%20originates%20from%20the%20states%20at%20interstitial%20sites%20and%20the%20Y%204d-orbitals%2C%20supporting%20the%20confinement%20of%20anionic%20electrons%20within%20the%20interlayer%20space.%20These%20results%20demonstrate%20that%20Y2C%20is%20a%20quasi-2D%20electride%20in%20term%20of%20%5BY2C%5D1.8%2B%5Cu00b71.8e%3F%2C%20and%20the%20coexistence%20of%20the%20anionic%20electrons%20and%20the%20Y%204d-electrons%20leads%20to%20the%20semimetallic%20behavior.%22%2C%22date%22%3A%2211%5Cu6708%2025%2C%202014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Fcm503512h%22%2C%22ISSN%22%3A%220897-4756%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Fcm503512h%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A39%3A51Z%22%7D%7D%2C%7B%22key%22%3A%22228U78X7%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Xiao%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EXiao%2C%20Z.%3B%20Ran%2C%20F.-Y.%3B%20Hiramatsu%2C%20H.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Kamiya%2C%20T.%20Epitaxial%20Growth%20and%20Electronic%20Structure%20of%20a%20Layered%20Zinc%20Pnictide%20Semiconductor%2C%20%26%23x3B2%3B-BaZn%3Csub%3E2%3C%5C%2Fsub%3EAs%3Csub%3E2%3C%5C%2Fsub%3E.%20%3Ci%3EThin%20Solid%20Films%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E559%3C%5C%2Fi%3E%2C%20100%26%23x2013%3B104.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.tsf.2013.10.135%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.tsf.2013.10.135%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Epitaxial%20growth%20and%20electronic%20structure%20of%20a%20layered%20zinc%20pnictide%20semiconductor%2C%20%5Cu03b2-BaZn%3Csub%3E2%3C%5C%2Fsub%3EAs%3Csub%3E2%3C%5C%2Fsub%3E%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zewen%22%2C%22lastName%22%3A%22Xiao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fan-Yong%22%2C%22lastName%22%3A%22Ran%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hidenori%22%2C%22lastName%22%3A%22Hiramatsu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshio%22%2C%22lastName%22%3A%22Kamiya%22%7D%5D%2C%22abstractNote%22%3A%22BaZn2As2%20is%20expected%20for%20a%20good%20p-type%20semiconductor%20and%20has%20two%20crystalline%20phases%20of%20an%20orthorhombic%20%5Cu03b1%20phase%20and%20a%20higher-symmetry%20tetragonal%20%5Cu03b2%20phase.%20Here%2C%20we%20report%20that%20high-quality%20epitaxial%20films%20of%20the%20tetragonal%20%5Cu03b2-BaZn2As2%20were%20grown%20on%20single-crystal%20MgO%20%28001%29%20substrates%20by%20a%20reactive%20solid-phase%20epitaxy%20technique.%20Out-of-plane%20and%20in-plane%20epitaxial%20relationships%20between%20the%20film%20and%20the%20substrate%20were%20BaZn2As2%20%2800%20l%29%5C%2F%5C%2FMgO%20%28001%29%20and%20BaZn2As2%20%5B200%5D%5C%2F%5C%2FMgO%20%5B200%5D%2C%20respectively.%20The%20full-widths%20at%20half%20maximum%20were%200.082%5Cu00b0%20for%20a%20008%20out-of-plane%20rocking%20curve%20and%200.342%5Cu00b0%20for%20a%20200%20in-plane%20rocking%20curve.%20A%20step-and-terrace%20structure%20was%20observed%20by%20atomic%20force%20microscopy.%20The%20band%20gap%20of%20%5Cu03b2-BaZn2As2%20was%20evaluated%20to%20be%20around%200.2%20eV%2C%20which%20is%20much%20smaller%20than%20that%20of%20a%20family%20compound%20LaZnOAs%20%281.5%20eV%29.%20Density%20functional%20theory%20calculation%20using%20the%20Heyd%5Cu2013Scuseria%5Cu2013Ernzerhof%20hybrid%20functionals%20supports%20the%20small%20band%20gap.%22%2C%22date%22%3A%225%5Cu6708%2030%2C%202014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.tsf.2013.10.135%22%2C%22ISSN%22%3A%220040-6090%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS0040609013017513%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A40%3A08Z%22%7D%7D%2C%7B%22key%22%3A%226NSMBAKV%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Suzuki%20et%20al.%22%2C%22parsedDate%22%3A%222014-01-01%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ESuzuki%2C%20K.%3B%20Usui%2C%20H.%3B%20Iimura%2C%20S.%3B%20Sato%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Kuroki%2C%20K.%20Theoretical%20Analysis%20on%20the%20Band%20Structure%20Variance%20of%20the%20Electron%20Doped%201111%20Iron-Based%20Superconductors.%20In%20%3Ci%3EPhysics%20Procedia%3C%5C%2Fi%3E%3B%20Proceedings%20of%20the%2026th%20International%20Symposium%20on%20Superconductivity%20%28ISS%202013%29%3B%202014%3B%20Vol.%2058%2C%20pp%2038%26%23x2013%3B41.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.phpro.2014.09.010%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.phpro.2014.09.010%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22conferencePaper%22%2C%22title%22%3A%22Theoretical%20Analysis%20on%20the%20Band%20Structure%20Variance%20of%20the%20Electron%20Doped%201111%20Iron-based%20Superconductors%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Suzuki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Usui%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Sato%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Kuroki%22%7D%5D%2C%22abstractNote%22%3A%22We%20perform%20first%20principles%20band%20calculation%20of%20electron%20doped%20iron-based%20superconductors%20adopting%20the%20virtual%20crystal%20approximation.%20We%20find%20that%20when%20electrons%20are%20doped%20by%20element%20substitution%20in%20the%20blocking%20layer%2C%20the%20band%20structure%20near%20the%20Fermi%20level%20is%20affected%20due%20to%20the%20increase%20of%20the%20positive%20charge%20in%20the%20layer.%20On%20the%20other%20hand%2C%20when%20Fe%20in%20the%20conducting%20layer%20is%20substituted%20by%20Co%2C%20the%20band%20structure%20is%20barely%20affected.%20This%20difference%20should%20be%20a%20key%20factor%20in%20understanding%20the%20phase%20diagram%20of%20the%20heavily%20doped%20electron%20doped%20systems%20LnFeAsO1-xHx.%22%2C%22date%22%3A%222014-01-01%22%2C%22proceedingsTitle%22%3A%22Physics%20Procedia%22%2C%22conferenceName%22%3A%22%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.phpro.2014.09.010%22%2C%22ISBN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS1875389214003678%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222022-10-04T02%3A50%3A35Z%22%7D%7D%2C%7B%22key%22%3A%227FPZHNH3%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Jeong%20et%20al.%22%2C%22parsedDate%22%3A%222014-05-01%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EJeong%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Lee%2C%20K.%3B%20Toda%2C%20Y.%3B%20Kim%2C%20S.%20W.%3B%20Hosono%2C%20H.%20Superconductivity%20of%20Ca%3Csub%3E2%3C%5C%2Fsub%3EInN%20with%20a%20Layered%20Structure%20Embedding%20an%20Anionic%20Indium%20Chain%20Array.%20%3Ci%3ESupercond.%20Sci.%20Technol.%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E27%3C%5C%2Fi%3E%20%285%29%2C%20055005.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F0953-2048%5C%2F27%5C%2F5%5C%2F055005%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F0953-2048%5C%2F27%5C%2F5%5C%2F055005%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Superconductivity%20of%20Ca%3Csub%3E2%3C%5C%2Fsub%3EInN%20with%20a%20layered%20structure%20embedding%20an%20anionic%20indium%20chain%20array%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sehoon%22%2C%22lastName%22%3A%22Jeong%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kimoon%22%2C%22lastName%22%3A%22Lee%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshitake%22%2C%22lastName%22%3A%22Toda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sung%20Wng%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20the%20emergence%20of%20superconductivity%20in%20Ca2InN%20consisting%20of%20a%20two-dimensional%20%282D%29%20array%20of%20zigzag%20indium%20chains%20embedded%20between%20Ca2N%20layers.%20A%20sudden%20drop%20of%20resistivity%20and%20a%20specific%20heat%20%28Cp%29%20jump%20attributed%20to%20the%20superconducting%20transition%20were%20observed%20at%200.6%20K.%20The%20Sommerfeld%20coefficient%20%5Cu03b3%20%3D%204.24%20mJ%20mol%5Cu22121K%5Cu22122%20and%20Debye%20temperature%20%5Cu0398D%20%3D%20322%20K%20were%20determined%20from%20the%20Cp%20of%20the%20normal%20conducting%20state%20and%20the%20superconducting%20volume%20fraction%20was%20estimated%20to%20be%20%5Cu223c80%25%20from%20the%20Cp%20jump%2C%20assuming%20a%20BCS-type%20weak%20coupling.%20Density%20functional%20theory%20calculations%20demonstrated%20that%20the%20electronic%20bands%20near%20the%20Fermi%20level%20%28EF%29%20are%20mainly%20derived%20from%20In%205p%20orbitals%20with%20%5Cu03c0%20and%20%5Cu03c3%20bonding%20states%20and%20the%20Fermi%20surface%20is%20composed%20of%20cylindrical%20parts%2C%20corresponding%20to%20the%20quasi-2D%20electronic%20state%20of%20the%20In-chain%20array.%20By%20integrating%20the%20projected%20density%20of%20states%20of%20the%20In%5Cu2013p%20component%20up%20to%20EF%2C%20a%20valence%20electron%20population%20of%20%5Cu223c1.6%20electrons%5C%2FIn%20was%20calculated%2C%20indicating%20that%20partially%20anionic%20state%20of%20In.%20The%20In%203d%20binding%20energies%20observed%20in%20Ca2InN%20by%20x-ray%20photoemission%20spectroscopy%20were%20negatively%20shifted%20from%20that%20in%20In%20metal.%20The%20superconductivity%20of%20Ca2InN%20is%20associated%20with%20the%20p%5Cu2013p%20bonding%20states%20of%20the%20anionic%20In%20layer.%22%2C%22date%22%3A%222014-05-01%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1088%5C%2F0953-2048%5C%2F27%5C%2F5%5C%2F055005%22%2C%22ISSN%22%3A%220953-2048%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fiopscience.iop.org%5C%2F0953-2048%5C%2F27%5C%2F5%5C%2F055005%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A50%3A47Z%22%7D%7D%2C%7B%22key%22%3A%226EYMAJ6V%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Xiao%20et%20al.%22%2C%22parsedDate%22%3A%222014-10-22%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EXiao%2C%20Z.%3B%20Hiramatsu%2C%20H.%3B%20Ueda%2C%20S.%3B%20Toda%2C%20Y.%3B%20Ran%2C%20F.-Y.%3B%20Guo%2C%20J.%3B%20Lei%2C%20H.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Kamiya%2C%20T.%20Narrow%20Bandgap%20in%20%26%23x3B2%3B-BaZn2As2%20and%20Its%20Chemical%20Origins.%20%3Ci%3EJ.%20Am.%20Chem.%20Soc.%3C%5C%2Fi%3E%20%3Cb%3E2014%3C%5C%2Fb%3E%2C%20%3Ci%3E136%3C%5C%2Fi%3E%20%2842%29%2C%2014959%26%23x2013%3B14965.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fja507890u%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fja507890u%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Narrow%20Bandgap%20in%20%5Cu03b2-BaZn2As2%20and%20Its%20Chemical%20Origins%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zewen%22%2C%22lastName%22%3A%22Xiao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hidenori%22%2C%22lastName%22%3A%22Hiramatsu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shigenori%22%2C%22lastName%22%3A%22Ueda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshitake%22%2C%22lastName%22%3A%22Toda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fan-Yong%22%2C%22lastName%22%3A%22Ran%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jiangang%22%2C%22lastName%22%3A%22Guo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hechang%22%2C%22lastName%22%3A%22Lei%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshio%22%2C%22lastName%22%3A%22Kamiya%22%7D%5D%2C%22abstractNote%22%3A%22%5Cu03b2-BaZn2As2%20is%20known%20to%20be%20a%20p-type%20semiconductor%20with%20the%20layered%20crystal%20structure%20similar%20to%20that%20of%20LaZnAsO%2C%20leading%20to%20the%20expectation%20that%20%5Cu03b2-BaZn2As2%20and%20LaZnAsO%20have%20similar%20bandgaps%3B%20however%2C%20the%20bandgap%20of%20%5Cu03b2-BaZn2As2%20%28previously%20reported%20value%20%5Cu223c0.2%20eV%29%20is%201%20order%20of%20magnitude%20smaller%20than%20that%20of%20LaZnAsO%20%281.5%20eV%29.%20In%20this%20paper%2C%20the%20reliable%20bandgap%20value%20of%20%5Cu03b2-BaZn2As2%20is%20determined%20to%20be%200.23%20eV%20from%20the%20intrinsic%20region%20of%20the%20temperature%20dependence%20of%20electrical%20conductivity.%20The%20origins%20of%20this%20narrow%20bandgap%20are%20discussed%20based%20on%20the%20chemical%20bonding%20nature%20probed%20by%206%20keV%20hard%20X-ray%20photoemission%20spectroscopy%2C%20hybrid%20density%20functional%20calculations%2C%20and%20the%20ligand%20theory.%20One%20origin%20is%20the%20direct%20As%5Cu2013As%20hybridization%20between%20adjacent%20%5BZnAs%5D%20layers%2C%20which%20leads%20to%20a%20secondary%20splitting%20of%20As%204p%20levels%20and%20raises%20the%20valence%20band%20maximum.%20The%20other%20is%20that%20the%20nonbonding%20Ba%205dx2%5Cu2013y2%20orbitals%20form%20an%20unexpectedly%20deep%20conduction%20band%20minimum%20%28CBM%29%20in%20%5Cu03b2-BaZn2As2%20although%20the%20CBM%20of%20LaZnAsO%20is%20formed%20mainly%20of%20Zn%204s.%20These%20two%20origins%20provide%20a%20quantitative%20explanation%20for%20the%20bandgap%20difference%20between%20%5Cu03b2-BaZn2As2%20and%20LaZnAsO.%22%2C%22date%22%3A%222014-10-22%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Fja507890u%22%2C%22ISSN%22%3A%220002-7863%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fja507890u%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-10-04T06%3A35%3A56Z%22%7D%7D%5D%7D
(1)
Matsuishi, S.; Muramatsu, H.; Hosono, H. Photochemistry of Nanocage Ca12Al14−xSixO32Cl2+x (x = 0.0 and 3.4) Crystals. Chemistry Letters 2014, 43 (8), 1371–1373. https://doi.org/10.1246/cl.140423.
(1)
Ishida, J.; Iimura, S.; Matsuishi, S.; Hosono, and H. Comparison of Impurity Effect between Two Tc Domes in LaFeAsO1-xHx. J. Phys.: Condens. Matter 2014, 26 (43), 435702. https://doi.org/10.1088/0953-8984/26/43/435702.
(1)
Hiraishi, M.; Iimura, S.; Kojima, K. M.; Yamaura, J.; Hiraka, H.; Ikeda, K.; Miao, P.; Ishikawa, Y.; Torii, S.; Miyazaki, M.; Yamauchi, I.; Koda, A.; Ishii, K.; Yoshida, M.; Mizuki, J.; Kadono, R.; Kumai, R.; Kamiyama, T.; Otomo, T.; Murakami, Y.; Matsuishi, S.; Hosono, H. Bipartite Magnetic Parent Phases in the Iron Oxypnictide Superconductor. Nat Phys 2014, 10 (4), 300–303. https://doi.org/10.1038/nphys2906.
(1)
Muraba, Y.; Matsuishi, S.; Hosono, H. Enhancing the Three-Dimensional Electronic Structure in 1111-Type Iron Arsenide Superconductors by H Substitution. Phys. Rev. B 2014, 89 (9), 094501. https://doi.org/10.1103/PhysRevB.89.094501.
(1)
Tada, T.; Takemoto, S.; Matsuishi, S.; Hosono, H. High-Throughput Ab Initio Screening for Two-Dimensional Electride Materials. Inorg. Chem. 2014, 53 (19), 10347–10358. https://doi.org/10.1021/ic501362b.
(1)
Matsuishi, S.; Maruyama, T.; Iimura, S.; Hosono, H. Controlling Factors of $Tc Dome Structure in 1111-Type Iron Arsenide Superconductors. Phys. Rev. B 2014, 89 (9), 094510. https://doi.org/10.1103/PhysRevB.89.094510.
(1)
Suzuki, K.; Usui, H.; Iimura, S.; Sato, Y.; Matsuishi, S.; Hosono, H.; Kuroki, K. Model of the Electronic Structure of Electron-Doped Iron-Based Superconductors: Evidence for Enhanced Spin Fluctuations by Diagonal Electron Hopping. Phys. Rev. Lett. 2014, 113 (2), 027002. https://doi.org/10.1103/PhysRevLett.113.027002.
(1)
Muraba, Y.; Matsuishi, S.; Hosono, H. La-Substituted CaFeAsH Superconductor with Tc = 47 K. J. Phys. Soc. Jpn. 2014, 83 (3), 033705. https://doi.org/10.7566/JPSJ.83.033705.
(1)
Bang, J.; Matsuishi, S.; Hiraka, H.; Fujisaki, F.; Otomo, T.; Maki, S.; Yamaura, J.; Kumai, R.; Murakami, Y.; Hosono, H. Hydrogen Ordering and New Polymorph of Layered Perovskite Oxyhydrides: Sr2VO4-xHx. J. Am. Chem. Soc. 2014, 136 (20), 7221–7224. https://doi.org/10.1021/ja502277r.
(1)
Zhang, X.; Xiao, Z.; Lei, H.; Toda, Y.; Matsuishi, S.; Kamiya, T.; Ueda, S.; Hosono, H. Two-Dimensional Transition-Metal Electride Y2C. Chem. Mater. 2014, 26 (22), 6638–6643. https://doi.org/10.1021/cm503512h.
(1)
Xiao, Z.; Ran, F.-Y.; Hiramatsu, H.; Matsuishi, S.; Hosono, H.; Kamiya, T. Epitaxial Growth and Electronic Structure of a Layered Zinc Pnictide Semiconductor, β-BaZn2As2. Thin Solid Films 2014, 559, 100–104. https://doi.org/10.1016/j.tsf.2013.10.135.
(1)
Suzuki, K.; Usui, H.; Iimura, S.; Sato, Y.; Matsuishi, S.; Hosono, H.; Kuroki, K. Theoretical Analysis on the Band Structure Variance of the Electron Doped 1111 Iron-Based Superconductors. In Physics Procedia; Proceedings of the 26th International Symposium on Superconductivity (ISS 2013); 2014; Vol. 58, pp 38–41. https://doi.org/10.1016/j.phpro.2014.09.010.
(1)
Jeong, S.; Matsuishi, S.; Lee, K.; Toda, Y.; Kim, S. W.; Hosono, H. Superconductivity of Ca2InN with a Layered Structure Embedding an Anionic Indium Chain Array. Supercond. Sci. Technol. 2014, 27 (5), 055005. https://doi.org/10.1088/0953-2048/27/5/055005.
(1)
Xiao, Z.; Hiramatsu, H.; Ueda, S.; Toda, Y.; Ran, F.-Y.; Guo, J.; Lei, H.; Matsuishi, S.; Hosono, H.; Kamiya, T. Narrow Bandgap in β-BaZn2As2 and Its Chemical Origins. J. Am. Chem. Soc. 2014, 136 (42), 14959–14965. https://doi.org/10.1021/ja507890u.
244926
P5622579
2013
items
1
american-chemical-society-with-titles-sentence-case-doi
0
date
asc
year
6
https://www.mces.titech.ac.jp/authors/matsuishi/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-c2ad6ec68de13a366b9282ed5f6ab688%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22EI262USF%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hosono%20and%20Matsuishi%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHosono%2C%20H.%3B%20Matsuishi%2C%20S.%20Superconductivity%20Induced%20by%20Hydrogen%20Anion%20Substitution%20in%201111-Type%20Iron%20Arsenides.%20%3Ci%3ECurrent%20Opinion%20in%20Solid%20State%20and%20Materials%20Science%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E17%3C%5C%2Fi%3E%20%282%29%2C%2049%26%23x2013%3B58.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.cossms.2013.03.004%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.cossms.2013.03.004%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Superconductivity%20induced%20by%20hydrogen%20anion%20substitution%20in%201111-type%20iron%20arsenides%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%5D%2C%22abstractNote%22%3A%22Hydrogen%20is%20the%20simplest%20bipolar%20element%20and%20its%20valence%20state%20can%20be%20controlled%20from%20%2B1%20to%20%5Cu22121.%20We%20synthesized%20the%201111-type%20iron%20arsenides%20CaFeAsH%20and%20LnFeAsO1%5Cu2212xHx%20%28Ln%20%3D%20lanthanide%3B%200%20%5Cu2a7d%20x%20%5Cu2a7d%200.5%29%20with%20the%20ZrCuSiAs%20type%20structure%20by%20a%20high-pressure%20synthesis%20method.%20The%20position%20and%20valence%20state%20of%20the%20substituted%20H%20were%20determined%20by%20neutron%20diffraction%20and%20density%20functional%20theory%20calculations.%20The%20close%20similarity%20in%20the%20structural%20and%20electrical%20properties%20of%20CaFeAsH%20and%20CaFeAsF%20indicated%20the%20formation%20of%20the%20hydride%20ion%20%28H%5Cu2212%29%2C%20which%20is%20isovalent%20with%20the%20fluoride%20ion%20%28F%5Cu2212%29%2C%20in%20the%201111-type%20iron%20arsenides.%20When%20some%20of%20the%20O2%5Cu2212%20ions%20in%20LnFeAsO%20are%20replaced%20by%20H%5Cu2212%2C%20superconductivity%20is%20induced%20by%20electron%20doping%20to%20the%20FeAs-layer%20to%20maintain%20charge%20neutrality.%20Since%20the%20substitution%20limit%20of%20hydrogen%20in%20LnFeAsO%20%28x%20%5Cu2248%200.5%29%20is%20much%20higher%20than%20that%20of%20fluorine%20%28x%20%5Cu2248%200.2%29%2C%20the%20hydrogen%20substitution%20technique%20provides%20an%20effective%20pathway%20for%20high-density%20electron-doping%2C%20making%20it%20possible%20to%20draw%20the%20complete%20electronic%20phase%20diagram%20of%20LnFeAsO.%20The%20x%5Cu2013T%20diagrams%20of%20LnFeAsO1%5Cu2212xHx%20%28Ln%20%3D%20La%2C%20Ce%2C%20Sm%2C%20Gd%29%20have%20a%20wide%20superconducting%20%28SC%29%20region%20spanning%20the%20range%20x%20%3D%200.04%5Cu20130.4%2C%20which%20is%20far%20from%20the%20parent%20antiferromagnetic%20region%20near%20x%20%3D%200.0.%20For%20LaFeAsO1%5Cu2212xHx%2C%20another%20SC%20dome%20region%20was%20found%20in%20the%20range%20x%20%3D%20%5Cu223c0.2%20to%20%5Cu223c0.5%20with%20a%20maximum%20Tc%20%3D%2036%20K%2C%20in%20addition%20to%20a%20conventional%20SC%20dome%20located%20at%20x%20%5Cu223c%200.08%20with%20maximum%20Tc%20%3D%2029%20K.%20Density%20functional%20theory%20calculations%20performed%20for%20LaFeAsO1%5Cu2212xHx%20indicated%20that%20the%20newly%20observed%20Tc%20is%20correlated%20with%20the%20appearance%20of%20degeneration%20of%20the%20Fe%203d%20bands%20%28dxy%2C%20dyz%20and%20dzx%29%2C%20which%20is%20caused%20not%20only%20by%20regularization%20of%20the%20tetrahedral%20shape%20of%20FeAs4%20due%20to%20chemical%20pressure%20effects%20but%20also%20by%20selective%20band%20occupation%20with%20doped%20electrons.%20In%20this%20article%2C%20we%20review%20the%20recent%20progress%20of%20superconductivity%20in%201111-type%20iron%20%28oxy%29arsenides%20and%20related%20compounds%20induced%20by%20hydrogen%20anion%20substitution.%22%2C%22date%22%3A%224%5Cu6708%202013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.cossms.2013.03.004%22%2C%22ISSN%22%3A%221359-0286%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS135902861300017X%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222014-12-22T02%3A24%3A17Z%22%7D%7D%2C%7B%22key%22%3A%22TNTRCURC%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Iimura%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EIimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Miyakawa%2C%20M.%3B%20Taniguchi%2C%20T.%3B%20Suzuki%2C%20K.%3B%20Usui%2C%20H.%3B%20Kuroki%2C%20K.%3B%20Kajimoto%2C%20R.%3B%20Nakamura%2C%20M.%3B%20Inamura%2C%20Y.%3B%20Ikeuchi%2C%20K.%3B%20Ji%2C%20S.%3B%20Hosono%2C%20H.%20Switching%20of%20Intra-Orbital%20Spin%20Excitations%20in%20Electron-Doped%20Iron%20Pnictide%20Superconductors.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E88%3C%5C%2Fi%3E%20%286%29%2C%20060501.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.88.060501%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.88.060501%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Switching%20of%20intra-orbital%20spin%20excitations%20in%20electron-doped%20iron%20pnictide%20superconductors%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masashi%22%2C%22lastName%22%3A%22Miyakawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takashi%22%2C%22lastName%22%3A%22Taniguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katsuhiro%22%2C%22lastName%22%3A%22Suzuki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hidetomo%22%2C%22lastName%22%3A%22Usui%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazuhiko%22%2C%22lastName%22%3A%22Kuroki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ryoichi%22%2C%22lastName%22%3A%22Kajimoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mitsutaka%22%2C%22lastName%22%3A%22Nakamura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yasuhiro%22%2C%22lastName%22%3A%22Inamura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazuhiko%22%2C%22lastName%22%3A%22Ikeuchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sungdae%22%2C%22lastName%22%3A%22Ji%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20investigate%20the%20doping%20dependence%20of%20the%20magnetic%20excitations%20in%20the%20two-superconducting-dome%20system%20LaFeAsO1%5Cu2212xDx.%20Using%20inelastic%20neutron%20scattering%2C%20spin%20fluctuations%20at%20different%20wave%20numbers%20were%20observed%20under%20both%20superconducting%20domes%20around%20x%20%3D%200.1%20and%200.4%20but%20vanished%20at%20x%20%3D%200.2%20corresponding%20to%20the%20Tc%20valley.%20Theoretical%20calculations%20indicate%20that%20the%20characteristic%20doping%20dependence%20of%20the%20spin%20fluctuations%20is%20rationally%20explained%20as%20a%20consequence%20of%20the%20switching%20of%20the%20two%20intra-orbital%20nestings%20within%20Fe-3dYZ%2CZX%20and%20Fe-3dX2-Y2%20by%20electron%20doping.%20The%20present%20results%20imply%20that%20the%20multiorbital%20nature%20plays%20an%20important%20role%20in%20the%20doping%20and%5C%2For%20material%20dependence%20of%20the%20Tc%20of%20the%20iron%20pnictide%20superconductors.%22%2C%22date%22%3A%228%5Cu6708%201%2C%202013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.88.060501%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.88.060501%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T01%3A51%3A32Z%22%7D%7D%2C%7B%22key%22%3A%223TJ5UT4E%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Park%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EPark%2C%20S.-W.%3B%20Mizoguchi%2C%20H.%3B%20Kodama%2C%20K.%3B%20Shamoto%2C%20S.%3B%20Otomo%2C%20T.%3B%20Matsuishi%2C%20S.%3B%20Kamiya%2C%20T.%3B%20Hosono%2C%20H.%20Magnetic%20Structure%20and%20Electromagnetic%20Properties%20of%20LnCrAsO%20with%20a%20ZrCuSiAs-Type%20Structure%20%28Ln%20%3D%20La%2C%20Ce%2C%20Pr%2C%20and%20Nd%29.%20%3Ci%3EInorg.%20Chem.%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E52%3C%5C%2Fi%3E%20%2823%29%2C%2013363%26%23x2013%3B13368.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fic401487q%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fic401487q%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Magnetic%20Structure%20and%20Electromagnetic%20Properties%20of%20LnCrAsO%20with%20a%20ZrCuSiAs-type%20Structure%20%28Ln%20%3D%20La%2C%20Ce%2C%20Pr%2C%20and%20Nd%29%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sang-Won%22%2C%22lastName%22%3A%22Park%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Mizoguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katsuaki%22%2C%22lastName%22%3A%22Kodama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shin-ichi%22%2C%22lastName%22%3A%22Shamoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshiya%22%2C%22lastName%22%3A%22Otomo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshio%22%2C%22lastName%22%3A%22Kamiya%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20the%20synthesis%2C%20structure%2C%20and%20electromagnetic%20properties%20of%20Cr-based%20layered%20oxyarsenides%20LnCrAsO%20%28Ln%20%3D%20La%2C%20Ce%2C%20Pr%2C%20and%20Nd%29%20with%20a%20ZrCuSiAs-type%20structure.%20All%20LnCrAsO%20samples%20showed%20metallic%20electronic%20conduction.%20Electron%20doping%20in%20LaCrAsO%20by%20Mn-substitution%20for%20the%20Cr%20sites%20gave%20rise%20to%20a%20metal%5Cu2013insulator%20transition.%20Analysis%20of%20powder%20neutron%20diffraction%20data%20revealed%20that%20LaCrAsO%20had%20G-type%20antiferromagnetic%20%28AFM%29%20ordering%2C%20i.e.%2C%20a%20checkerboard-type%20AFM%20ordering%20in%20the%20CrAs%20plane%20and%20antiparallel%20spin%20coupling%20between%20the%20adjacent%20CrAs%20planes%2C%20at%20300%20K%20with%20a%20large%20spin%20moment%20of%201.57%20%5Cu03bcB%20along%20the%20c%20axis.%20The%20magnetic%20susceptibility%20of%20LaCrAsO%20was%20very%20small%20%28on%20the%20order%20of%2010%5Cu20133%20emu%5C%2Fmol%29%20and%20showed%20a%20broad%20hump%20at%20%5Cu223c550%20K.%20First-principles%20density%20functional%20theory%20calculations%20of%20LaCrAsO%20explained%20its%20crystal%20structure%20and%20metallic%20nature%20well%2C%20but%20could%20not%20replicate%20the%20antiparallel%20spin%20coupling%20between%20the%20CrAs%20layers.%20The%20electronic%20structure%20of%20LaCrAsO%20is%20discussed%20with%20regard%20to%20those%20of%20related%20compounds%20LaFeAsO%20and%20LaMnAsO.%22%2C%22date%22%3A%2212%5Cu6708%202%2C%202013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Fic401487q%22%2C%22ISSN%22%3A%220020-1669%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fpubs.acs.org%5C%2Fdoi%5C%2Fabs%5C%2F10.1021%5C%2Fic401487q%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222017-02-16T03%3A37%3A47Z%22%7D%7D%2C%7B%22key%22%3A%22PRN4KDEB%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hanna%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHanna%2C%20T.%3B%20Matsuishi%2C%20S.%3B%20Kodama%2C%20K.%3B%20Otomo%2C%20T.%3B%20Shamoto%2C%20S.%3B%20Hosono%2C%20H.%20From%20Antiferromagnetic%20Insulator%20to%20Ferromagnetic%20Metal%3A%20Effects%20of%20Hydrogen%20Substitution%20in%20LaMnAsO.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E87%3C%5C%2Fi%3E%20%282%29%2C%20020401.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.87.020401%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.87.020401%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22From%20antiferromagnetic%20insulator%20to%20ferromagnetic%20metal%3A%20Effects%20of%20hydrogen%20substitution%20in%20LaMnAsO%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Taku%22%2C%22lastName%22%3A%22Hanna%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katsuaki%22%2C%22lastName%22%3A%22Kodama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshiya%22%2C%22lastName%22%3A%22Otomo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shin-ichi%22%2C%22lastName%22%3A%22Shamoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Manganese%20oxyarsenide%20hydrides%20LaMnAsO1%5Cu2212xHx%20%28x%3D0%5Cu22120.73%29%20were%20synthesized%20by%20a%20solid-state%20reaction%20under%20a%20high%20pressure%20of%202%20GPa.%20The%20hydride%20ions%20H%5Cu2212%20in%20O2%5Cu2212%20sites%20induced%20an%20insulator-to-metal%20conversion%20and%20suppressed%20the%20antiferromagnetic%20ordering%20of%20Mn%20spins.%20Instead%2C%20ferromagnetism%20with%20negative%20magnetoresistance%20was%20observed.%20The%20Curie%20temperature%20and%20saturated%20moment%20per%20Mn%20increased%20with%20x%20up%20to%20264%20K%20and%201.5%5Cu03bcB%2C%20respectively%2C%20at%20x%3D0.73.%20These%20results%20indicate%20that%20H%5Cu2212%20donate%20conduction%20electrons%20to%20the%20MnAs%20layer%2C%20mediating%20a%20direct%20ferromagnetic%20interaction%20between%20Mn%20atoms.%22%2C%22date%22%3A%221%5Cu6708%202%2C%202013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.87.020401%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.87.020401%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T01%3A53%3A11Z%22%7D%7D%2C%7B%22key%22%3A%22554BSJFR%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Suzuki%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ESuzuki%2C%20K.%3B%20Usui%2C%20H.%3B%20Kuroki%2C%20K.%3B%20Iimura%2C%20S.%3B%20Sato%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Robust%20Spin%20Fluctuations%20and%20S%26%23xB1%3B%20Pairing%20in%20the%20Heavily%20Electron%20Doped%20Iron-Based%20Superconductors.%20%3Ci%3EJ.%20Phys.%20Soc.%20Jpn.%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E82%3C%5C%2Fi%3E%20%288%29%2C%20083702.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.7566%5C%2FJPSJ.82.083702%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.7566%5C%2FJPSJ.82.083702%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Robust%20Spin%20Fluctuations%20and%20s%5Cu00b1%20Pairing%20in%20the%20Heavily%20Electron%20Doped%20Iron-Based%20Superconductors%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katsuhiro%22%2C%22lastName%22%3A%22Suzuki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hidetomo%22%2C%22lastName%22%3A%22Usui%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kazuhiko%22%2C%22lastName%22%3A%22Kuroki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshiyasu%22%2C%22lastName%22%3A%22Sato%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20theoretically%20study%20the%20spin%20fluctuation%20and%20superconductivity%20in%20La1111%20and%20Sm1111%20iron-based%20superconductors%20for%20a%20wide%20range%20of%20electron%20doping.%20When%20we%20take%20into%20account%20the%20band%20structure%20variation%20by%20electron%20doping%2C%20the%20hole%20Fermi%20surface%20originating%20from%20the%20dX2%5Cu2212Y2dX2%5Cu2212Y2d_%7BX%5E%7B2%7D-Y%5E%7B2%7D%7D%20orbital%20turns%20out%20to%20be%20robust%20against%20electron%20doping%2C%20and%20this%20gives%20rise%20to%20large%20spin%20fluctuations%20and%20consequently%20s%5Cu00b1s%5Cu00b1s%5C%5Cpm%20pairing%20even%20in%20the%20heavily%20doped%20regime.%20The%20stable%20hole%20Fermi%20surface%20is%20larger%20for%20Sm1111%20than%20for%20La1111%2C%20which%20can%20be%20considered%20as%20the%20origin%20of%20the%20apparent%20difference%20in%20the%20phase%20diagram.%22%2C%22date%22%3A%227%5Cu6708%204%2C%202013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.7566%5C%2FJPSJ.82.083702%22%2C%22ISSN%22%3A%220031-9015%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fjournals.jps.jp%5C%2Fdoi%5C%2Fabs%5C%2F10.7566%5C%2FJPSJ.82.083702%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T01%3A52%3A07Z%22%7D%7D%2C%7B%22key%22%3A%229JMAQXRN%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Price%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EPrice%2C%20S.%3B%20Su%2C%20Y.%3B%20Xiao%2C%20Y.%3B%20T.%20Adroja%2C%20D.%3B%20Guidi%2C%20T.%3B%20Mittal%2C%20R.%3B%20Nandi%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Br%26%23xFC%3Bckel%2C%20T.%20Evidence%20of%20Spin%20Resonance%20Signal%20in%20Oxygen%20Free%20Superconducting%20CaFe%3Csub%3E0.88%3C%5C%2Fsub%3ECo%3Csub%3E0.12%3C%5C%2Fsub%3EAsF%3A%20An%20Inelastic%20Neutron%20Scattering%20Study.%20%3Ci%3EJ.%20Phys.%20Soc.%20Jpn.%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E82%3C%5C%2Fi%3E%20%2810%29%2C%20104716.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.7566%5C%2FJPSJ.82.104716%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.7566%5C%2FJPSJ.82.104716%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Evidence%20of%20Spin%20Resonance%20Signal%20in%20Oxygen%20Free%20Superconducting%20CaFe%3Csub%3E0.88%3C%5C%2Fsub%3ECo%3Csub%3E0.12%3C%5C%2Fsub%3EAsF%3A%20An%20Inelastic%20Neutron%20Scattering%20Study%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephen%22%2C%22lastName%22%3A%22Price%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yixi%22%2C%22lastName%22%3A%22Su%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yinguo%22%2C%22lastName%22%3A%22Xiao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Devashibhai%22%2C%22lastName%22%3A%22T.%20Adroja%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tatiana%22%2C%22lastName%22%3A%22Guidi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ranjan%22%2C%22lastName%22%3A%22Mittal%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shibabrata%22%2C%22lastName%22%3A%22Nandi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Br%5Cu00fcckel%22%7D%5D%2C%22abstractNote%22%3A%22The%20spin%20excitation%20spectrum%20of%20optimally%20doped%20superconducting%20CaFe0.88Co0.12AsF%20%28Tc%5Cu223c22Tc%5Cu223c22T_%7B%5C%5Ctext%7Bc%7D%7D%5C%5Csim%2022%20K%29%20was%20studied%20by%20means%20of%20time-of-flight%20%28ToF%29%20inelastic%20neutron%20scattering%20experiments%20on%20a%20powder%20sample%20for%20temperatures%20above%20and%20below%20TcTcT_%7B%5C%5Ctext%7Bc%7D%7D%20and%20energies%20up%20to%2015%20meV.%20In%20the%20superconducting%20state%2C%20the%20spin%20resonance%20signal%20is%20observed%20as%20an%20enhancement%20of%20spectral%20weight%20of%20particle%20hole%20excitations%20of%20approximately%201.5%20times%20relative%20to%20normal%20state%20excitations.%20The%20resonance%20energy%20ER%5Cu223c7ER%5Cu223c7E_%7B%5C%5Ctext%7BR%7D%7D%5C%5Csim%207%20meV%20scales%20to%20TcTcT_%7B%5C%5Ctext%7Bc%7D%7D%20via%203.7%20kBTckBTck_%7B%5C%5Ctext%7BB%7D%7DT_%7B%5C%5Ctext%7Bc%7D%7D%20which%20is%20in%20reasonable%20agreement%20to%20the%20scaling%20relation%20reported%20for%20other%20Fe-based%20compositions.%20For%20energies%20below%205%20meV%20the%20spectrum%20of%20spin%20flip%20particle%20hole%20excitations%20in%20the%20superconducting%20state%20exhibits%20a%20strong%20reduction%20in%20spectral%20weight%2C%20indicating%20the%20opening%20of%20the%20spin%20gap.%20Nonetheless%2C%20a%20complete%20suppression%20of%20magnetic%20response%20cannot%20be%20observed.%20In%20contrast%2C%20the%20normal%20state%20spin%20excitations%20are%20not%20gapped%20and%20strongly%20two%20dimensional%20spin%20fluctuations%20persist%20up%20to%20temperatures%20at%20least%20as%20high%20as%20150%20K.%22%2C%22date%22%3A%229%5Cu6708%2020%2C%202013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.7566%5C%2FJPSJ.82.104716%22%2C%22ISSN%22%3A%220031-9015%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fjournals.jps.jp%5C%2Fdoi%5C%2Fabs%5C%2F10.7566%5C%2FJPSJ.82.104716%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A41%3A55Z%22%7D%7D%2C%7B%22key%22%3A%22PN854CG5%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Lee%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ELee%2C%20K.%3B%20Kim%2C%20S.%20W.%3B%20Toda%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Dicalcium%20Nitride%20as%20a%20Two-Dimensional%20Electride%20with%20an%20Anionic%20Electron%20Layer.%20%3Ci%3ENature%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E494%3C%5C%2Fi%3E%20%287437%29%2C%20336%26%23x2013%3B340.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fnature11812%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fnature11812%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Dicalcium%20nitride%20as%20a%20two-dimensional%20electride%20with%20an%20anionic%20electron%20layer%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kimoon%22%2C%22lastName%22%3A%22Lee%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sung%20Wng%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshitake%22%2C%22lastName%22%3A%22Toda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Recent%20studies%20suggest%20that%20electrides%5Cu2014ionic%20crystals%20in%20which%20electrons%20serve%20as%20anions%5Cu2014are%20not%20exceptional%20materials%20but%20rather%20a%20generalized%20form%2C%20particularly%20under%20high%20pressure.%20The%20topology%20of%20the%20cavities%20confining%20anionic%20electrons%20determines%20their%20physical%20properties.%20At%20present%2C%20reported%20confining%20sites%20consist%20only%20of%20zero-dimensional%20cavities%20or%20weakly%20linked%20channels.%20Here%20we%20report%20a%20layered-structure%20electride%20of%20dicalcium%20nitride%2C%20Ca2N%2C%20which%20possesses%20two-dimensionally%20confined%20anionic%20electrons%20whose%20concentration%20agrees%20well%20with%20that%20for%20the%20chemical%20formula%20of%20%5BCa2N%5D%2B%5Cu00b7e%5Cu2212.%20Two-dimensional%20transport%20characteristics%20are%20demonstrated%20by%20a%20high%20electron%20mobility%20%28520%20cm2%20V%5Cu22121%20s%5Cu22121%29%20and%20long%20mean%20scattering%20time%20%280.6%20picoseconds%29%20with%20a%20mean%20free%20path%20of%200.12%20micrometres.%20The%20quadratic%20temperature%20dependence%20of%20the%20resistivity%20up%20to%20120%20Kelvin%20indicates%20the%20presence%20of%20an%20electron%5Cu2013electron%20interaction.%20A%20striking%20anisotropic%20magnetoresistance%20behaviour%20with%20respect%20to%20the%20direction%20of%20magnetic%20field%20%28negative%20for%20the%20field%20perpendicular%20to%20the%20conducting%20plane%20and%20positive%20for%20the%20field%20parallel%20to%20it%29%20is%20observed%2C%20confirming%20diffusive%20two-dimensional%20transport%20in%20dense%20electron%20layers.%20Additionally%2C%20band%20calculations%20support%20confinement%20of%20anionic%20electrons%20within%20the%20interlayer%20space%2C%20and%20photoemission%20measurements%20confirm%20anisotropic%20low%20work%20functions%20of%203.5%20and%202.6%20electronvolts%2C%20revealing%20the%20loosely%20bound%20nature%20of%20the%20anionic%20electrons.%20We%20conclude%20that%20Ca2N%20is%20a%20two-dimensional%20electride%20in%20terms%20of%20%5BCa2N%5D%2B%5Cu00b7e%5Cu2212.%22%2C%22date%22%3A%222%5Cu6708%2021%2C%202013%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1038%5C%2Fnature11812%22%2C%22ISSN%22%3A%220028-0836%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.nature.com%5C%2Fnature%5C%2Fjournal%5C%2Fv494%5C%2Fn7437%5C%2Ffull%5C%2Fnature11812.html%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222014-11-02T18%3A22%3A47Z%22%7D%7D%2C%7B%22key%22%3A%22JWI4CTZ8%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Guo%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EGuo%2C%20J.%3B%20Yamaura%2C%20J.%3B%20Lei%2C%20H.%3B%20Matsuishi%2C%20S.%3B%20Qi%2C%20Y.%3B%20Hosono%2C%20H.%20Superconductivity%20in%20Ba%3Csub%3En%2B2%3C%5C%2Fsub%3EIr%3Csub%3E4n%3C%5C%2Fsub%3EGe%3Csub%3E12n%2B4%3C%5C%2Fsub%3E%20%28N%3D1%2C2%29%20with%20Cage%20Structure%20and%20Softening%20of%20Low-Lying%20Localized%20Mode.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E88%3C%5C%2Fi%3E%20%2814%29%2C%20140507.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.88.140507%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.88.140507%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Superconductivity%20in%20Ba%3Csub%3En%2B2%3C%5C%2Fsub%3EIr%3Csub%3E4n%3C%5C%2Fsub%3EGe%3Csub%3E12n%2B4%3C%5C%2Fsub%3E%20%28n%3D1%2C2%29%20with%20cage%20structure%20and%20softening%20of%20low-lying%20localized%20mode%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jiangang%22%2C%22lastName%22%3A%22Guo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jun-ichi%22%2C%22lastName%22%3A%22Yamaura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hechang%22%2C%22lastName%22%3A%22Lei%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yanpeng%22%2C%22lastName%22%3A%22Qi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20on%20new%20superconductors%20Ban%2B2Ir4nGe12n%2B4%20%28n%20%3D%201%2C%202%29%20with%20critical%20temperatures%20Tc%20%3D%206.1%20and%203.2%20K%2C%20respectively%2C%20along%20with%20their%20crystal%20structures%2C%20electron%20transport%2C%20and%20specific%20heat.%20The%20compounds%20are%20composed%20of%20alternating%20Ba%40Ir8Ge16%20and%20Ba%40Ir2Ge16%20cages%2C%20both%20of%20which%20are%20larger%20in%20the%20n%20%3D%201%20sample%20than%20in%20the%20n%20%3D%202%20sample.%20The%20normal-state%20heat%20capacity%20reveals%20two%20low-lying%20vibration%20modes%20associated%20with%20guest%20Ba%20cations%2C%20and%20both%20characteristic%20temperatures%20in%20Ba3Ir4Ge16%20are%20smaller%20than%20those%20in%20Ba4Ir8Ge28.%20Meanwhile%2C%20the%20density%20functional%20theory%20calculations%20reveal%20that%20the%20Ge-4p%20bands%20dominated%20the%20Fermi%20level%20in%20both%20samples.%20We%20propose%20that%20the%20softening%20of%20localized%20phonons%20due%20to%20expansion%20of%20the%20cage%20strengthens%20the%20electron-phonon%20coupling%20between%20Ba%20cations%20and%20Ge%20anions%2C%20leading%20to%20the%20higher%20Tc%20in%20Ba3Ir4Ge16.%22%2C%22date%22%3A%2210%5Cu6708%2023%2C%202013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.88.140507%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.88.140507%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A42%3A57Z%22%7D%7D%2C%7B%22key%22%3A%228JUAITCD%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fujiwara%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EFujiwara%2C%20N.%3B%20Tsutsumi%2C%20S.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Yamakawa%2C%20Y.%3B%20Kontani%2C%20H.%20Detection%20of%20Antiferromagnetic%20Ordering%20in%20Heavily%20Doped%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E%20Pnictide%20Superconductors%20Using%20Nuclear-Magnetic-Resonance%20Techniques.%20%3Ci%3EPhys.%20Rev.%20Lett.%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E111%3C%5C%2Fi%3E%20%289%29%2C%20097002.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevLett.111.097002%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevLett.111.097002%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Detection%20of%20Antiferromagnetic%20Ordering%20in%20Heavily%20Doped%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E%20Pnictide%20Superconductors%20Using%20Nuclear-Magnetic-Resonance%20Techniques%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Fujiwara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Tsutsumi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Yamakawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Kontani%22%7D%5D%2C%22abstractNote%22%3A%22We%20studied%20double%20superconducting%20%28SC%29%20domes%20in%20LaFeAsO1%5Cu2212xHx%20by%20using%20As75%20and%20H1%20nuclear-magnetic-resonance%20techniques%20and%20unexpectedly%20discovered%20that%20a%20new%20antiferromagnetic%20%28AF%29%20phase%20follows%20the%20double%20SC%20domes%20on%20further%20H%20doping%2C%20forming%20a%20symmetric%20alignment%20of%20AF%20and%20SC%20phases%20in%20the%20electronic%20phase%20diagram.%20We%20demonstrated%20that%20the%20new%20AF%20ordering%20originates%20from%20the%20nesting%20between%20electron%20pockets%2C%20unlike%20the%20nesting%20between%20electron%20and%20hole%20pockets%2C%20as%20seen%20in%20the%20majority%20of%20undoped%20pnictides.%20The%20new%20AF%20ordering%20is%20derived%20from%20the%20features%20common%20to%20high-Tc%20pnictides%3B%20however%2C%20it%20has%20not%20been%20reported%20so%20far%20for%20other%20high-Tc%20pnictides%20because%20of%20their%20poor%20electron%20doping%20capability.%22%2C%22date%22%3A%228%5Cu6708%2026%2C%202013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevLett.111.097002%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevLett.111.097002%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A52%3A20Z%22%7D%7D%2C%7B%22key%22%3A%22VEWHXE7M%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22%5Cu677e%5Cu77f3%20%5Cu8061%20and%20%5Cu7d30%5Cu91ce%20%5Cu79c0%5Cu96c4%22%2C%22parsedDate%22%3A%222013-03%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3E%26%23x677E%3B%26%23x77F3%3B%20%26%23x8061%3B%3B%20%26%23x7D30%3B%26%23x91CE%3B%20%26%23x79C0%3B%26%23x96C4%3B.%20%26%23x9244%3B%26%23x7CFB%3B%26%23x8D85%3B%26%23x4F1D%3B%26%23x5C0E%3B%26%23x4F53%3B.%20In%20%26%23x8D85%3B%26%23x4F1D%3B%26%23x5C0E%3B%26%23x73FE%3B%26%23x8C61%3B%26%23x3068%3B%26%23x9AD8%3B%26%23x6E29%3B%26%23x8D85%3B%26%23x4F1D%3B%26%23x5C0E%3B%26%23x4F53%3B%3B%20%26%23x30A8%3B%26%23x30CC%3B%26%23x30FB%3B%26%23x30C6%3B%26%23x30A3%3B%26%23x30FC%3B%26%23x30FB%3B%26%23x30A8%3B%26%23x30B9%3B%2C%202013%3B%20pp%2072%26%23x2013%3B79.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22bookSection%22%2C%22title%22%3A%22%5Cu9244%5Cu7cfb%5Cu8d85%5Cu4f1d%5Cu5c0e%5Cu4f53%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22name%22%3A%22%5Cu677e%5Cu77f3%20%5Cu8061%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22name%22%3A%22%5Cu7d30%5Cu91ce%20%5Cu79c0%5Cu96c4%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22bookTitle%22%3A%22%5Cu8d85%5Cu4f1d%5Cu5c0e%5Cu73fe%5Cu8c61%5Cu3068%5Cu9ad8%5Cu6e29%5Cu8d85%5Cu4f1d%5Cu5c0e%5Cu4f53%22%2C%22date%22%3A%222013%5C%2F3%22%2C%22language%22%3A%22%22%2C%22ISBN%22%3A%22978-4-86469-057-7%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.nts-book.co.jp%5C%2Fitem%5C%2Fdetail%5C%2Fsummary%5C%2Fbuturi%5C%2F20130300_73.html%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-10-04T02%3A35%3A25Z%22%7D%7D%2C%7B%22key%22%3A%227UQA4WPA%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fujiwara%20et%20al.%22%2C%22parsedDate%22%3A%222013-04-26%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EFujiwara%2C%20N.%3B%20Matsuishi%2C%20S.%3B%20Kamihara%2C%20Y.%3B%20Hosono%2C%20H.%20Homogeneous%20Coexistence%20in%20CaFe%3Csub%3E1-x%3C%5C%2Fsub%3ECo%3Csub%3Ex%3C%5C%2Fsub%3EAsF%20and%20Phase%20Segregation%20in%26%23xA0%3B%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EF%3Csub%3Ex%3C%5C%2Fsub%3E%26%23xA0%3B%20Studied%20via%20NMR.%20%3Ci%3EJ%20Supercond%20Nov%20Magn%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E26%3C%5C%2Fi%3E%20%288%29%2C%202689%26%23x2013%3B2692.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs10948-013-2161-0%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs10948-013-2161-0%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Homogeneous%20Coexistence%20in%20CaFe%3Csub%3E1-x%3C%5C%2Fsub%3ECo%3Csub%3Ex%3C%5C%2Fsub%3EAsF%20and%20Phase%20Segregation%20in%20%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EF%3Csub%3Ex%3C%5C%2Fsub%3E%20%20Studied%20via%20NMR%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Fujiwara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Kamihara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22In%20iron-based%20pnictides%2C%20one%20of%20the%20interesting%20topics%20is%20homogeneous%20coexistence%20or%20phase%20segregation%20at%20the%20boundary%20between%20antiferromagnetic%20%28AF%29%20and%20superconducting%20%28SC%29%20phases.%20We%20addressed%20this%20problem%20on%20a%20microscopic%20level%20by%20means%20of%2075As%20NMR%20measurements%20in%20LaFeAsO1%5Cu2212x%20F%20x%20%28x%3D0.026%29%20%28La1111%29%2C%20and%20CaFe1%5Cu2212x%20Co%20x%20AsF%20%28x%3D0.06%29%20%28Ca1111%29%20having%20an%20intermediate%20electronic%20phase%20diagram%20between%20Ba%28Fe1%5Cu2212x%20Co%20x%20%292As2%20and%20the%20La1111%20series.%20NMR%20spectra%20for%206%20%25%20Co-doped%20Ca1111%20samples%20were%20very%20similar%20to%20those%20for%20the%20undoped%20samples%20even%20below%20T%20c%20%2C%20suggesting%20homogeneous%20coexistence%20of%20the%20AF%20and%20SC%20states.%20For%202.6%20%25%20F-doped%20La1111%20samples%2C%20AF%20and%20paramagnetic%20%28PM%29%20domains%20coexist%20at%20ambient%20pressure%2C%20and%20AF%20and%20SC%20domains%20coexist%20at%203.0%20GPa.%20The%20coexistence%20of%20domains%20is%20explained%20by%20considering%20a%20SC%20dome%20separated%20from%20the%20AF%20phase%20in%20the%20phase%20diagram.%20The%20homogeneous%20coexistence%20support%20S%20%5Cu00b1-wave%20superconductivity%2C%20whereas%20separation%20of%20the%20AF%20and%20SC%20phases%20gives%20credence%20to%20S%20%2B%2B-wave%20superconductivity.%22%2C%22date%22%3A%222013%5C%2F04%5C%2F26%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1007%5C%2Fs10948-013-2161-0%22%2C%22ISSN%22%3A%221557-1939%2C%201557-1947%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.springer.com%5C%2Farticle%5C%2F10.1007%5C%2Fs10948-013-2161-0%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A53%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22F72XMFCP%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Funabiki%20et%20al.%22%2C%22parsedDate%22%3A%222013-06-13%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EFunabiki%2C%20F.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Local%20Structure%20around%20Rare-Earth%20Ions%20in%20B%3Csub%3E2%3C%5C%2Fsub%3EO%3Csub%3E3%3C%5C%2Fsub%3E%20Glass%20at%20High%20Pressure.%20%3Ci%3EJournal%20of%20Applied%20Physics%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E113%3C%5C%2Fi%3E%20%2822%29%2C%20223508.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4811185%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4811185%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Local%20structure%20around%20rare-earth%20ions%20in%20B%3Csub%3E2%3C%5C%2Fsub%3EO%3Csub%3E3%3C%5C%2Fsub%3E%20glass%20at%20high%20pressure%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fuji%22%2C%22lastName%22%3A%22Funabiki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Melt%20quenching%20of%20B2O3%20with%20less%20than%2025%20mol.%20%25%20rare-earth%20oxide%20%28RE%202O3%29%20at%20ambient%20pressure%20results%20in%20a%20milky%20white%20glass%20because%20of%20liquid-liquid%20phase%20separation%20into%20B2O3%20and%20RE%202O3%5Cu00b73B2O%20phases.%20In%20contrast%2C%20we%20have%20found%20that%20melt%20quenching%20under%20GPa-order%20pressure%20realizes%20a%20transparent%20RE-doped%20B2O3%20glass.%20This%20study%20investigates%20the%20local%20structure%20around%20the%20RE%20ions%20in%20the%20B2O3%20glass%20prepared%20at%203%20GPa%20using%20optical%20measurements%20and%20electron-spin-echo%20envelope%20modulation%20spectroscopy.%20It%20is%20shown%20that%20the%20RE-rich%20microparticles%20disappear%20and%20the%20RE%20ions%20are%20isolated%20from%20each%20other%20in%20a%20highly%20symmetric%20crystal%20field%20formed%20by%20triangular%20and%20tetrahedral%20boron%20units.%20This%20result%20is%20consistent%20with%20that%20extrapolated%20from%20the%20data%20for%20RE-doped%20sodium%20borate%20glasses.%22%2C%22date%22%3A%222013%5C%2F06%5C%2F13%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F1.4811185%22%2C%22ISSN%22%3A%220021-8979%2C%201089-7550%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fscitation.aip.org%5C%2Fcontent%5C%2Faip%5C%2Fjournal%5C%2Fjap%5C%2F113%5C%2F22%5C%2F10.1063%5C%2F1.4811185%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A51%3A27Z%22%7D%7D%2C%7B%22key%22%3A%22AA7W3TDN%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fujiwara%20et%20al.%22%2C%22parsedDate%22%3A%222013-07-09%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EFujiwara%2C%20N.%3B%20Kamihara%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Homogeneous%20Coexistence%20and%20Phase%20Segregation%20in%201111%20Iron-Based%20Pnictides%20Studied%20via%20NMR.%20%3Ci%3EJournal%20of%20the%20Korean%20Physical%20Society%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E62%3C%5C%2Fi%3E%20%2812%29%2C%202004%26%23x2013%3B2006.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3938%5C%2Fjkps.62.2004%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3938%5C%2Fjkps.62.2004%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Homogeneous%20coexistence%20and%20phase%20segregation%20in%201111%20iron-based%20pnictides%20studied%20via%20NMR%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Naoki%22%2C%22lastName%22%3A%22Fujiwara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoichi%22%2C%22lastName%22%3A%22Kamihara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20performed%2075As%20and%2051Co%20nuclear%20magnetic%20resonance%20%28NMR%29%20measurements%20on%20LaFeAsO1%5Cu2212x%20F%20x%20%28La1111%29%2C%20a%20prototype%20of%20iron-based%20superconductors%2C%20and%20on%20Ca%28Fe1%5Cu2212x%20Co%20x%20%29AsF%20%28Ca1111%29%2C%20which%20has%20a%20small%20overlap%20between%20the%20antiferromagnetic%20%28AF%29%20and%20superconducting%20%28SC%29%20domes%20in%20the%20electronic%20phase%20diagram.%20We%20found%20in%20the%20Ca1111%20series%20that%20AF%20and%20SC%20states%20coexist%20homogeneously%20in%20the%20overlapped%20region%2C%20while%20in%20the%20La1111%20series%2C%20we%20found%20that%20paramagnetic%20%28PM%29%20and%20SC%20domains%20coexist%20around%20the%20AF-SC%20phase%20boundary.%20The%20coexistence%20of%20these%20domains%20indicates%20that%20the%20AF%20and%20SC%20domes%20segregate%20from%20each%20other%20in%20the%20electronic%20phase%20diagram.%22%2C%22date%22%3A%222013%5C%2F07%5C%2F09%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.3938%5C%2Fjkps.62.2004%22%2C%22ISSN%22%3A%220374-4884%2C%201976-8524%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.springer.com%5C%2Farticle%5C%2F10.3938%5C%2Fjkps.62.2004%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T01%3A52%3A31Z%22%7D%7D%2C%7B%22key%22%3A%22IVXSM53U%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Tanaka%20et%20al.%22%2C%22parsedDate%22%3A%222013-08-01%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ETanaka%2C%20S.%3B%20Kato%2C%20T.%3B%20Miyake%2C%20A.%3B%20Kagayama%2C%20T.%3B%20Shimizu%2C%20K.%3B%20Kim%2C%20S.%20W.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Strong%20Enhancement%20of%20Superconductivity%20in%20Inorganic%20Electride%2012CaO%26%23xB7%3B7Al%3Csub%3E2%3C%5C%2Fsub%3EO%3Csub%3E3%3C%5C%2Fsub%3E%3AE%26%23x2212%3B%20under%20High%20Pressure.%20%3Ci%3EJournal%20of%20the%20Korean%20Physical%20Society%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E63%3C%5C%2Fi%3E%20%283%29%2C%20477%26%23x2013%3B480.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3938%5C%2Fjkps.63.477%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3938%5C%2Fjkps.63.477%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Strong%20enhancement%20of%20superconductivity%20in%20inorganic%20electride%2012CaO%5Cu00b77Al%3Csub%3E2%3C%5C%2Fsub%3EO%3Csub%3E3%3C%5C%2Fsub%3E%3Ae%5Cu2212%20under%20high%20pressure%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shigeki%22%2C%22lastName%22%3A%22Tanaka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomoki%22%2C%22lastName%22%3A%22Kato%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Atsushi%22%2C%22lastName%22%3A%22Miyake%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomoko%22%2C%22lastName%22%3A%22Kagayama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katsuya%22%2C%22lastName%22%3A%22Shimizu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sung%20Wng%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20present%20the%20results%20of%20the%20pressure%20dependence%20of%20the%20superconductivity%20of%20the%20inorganic%20electride%2012CaO%5Cu00b77Al2O3%3Ae%5Cu2212%20%28C12A7%3Ae%5Cu2212%29%20single%20crystal%20through%20the%20ac-susceptibility%20measurement%20under%20high%20pressure.%20C12A7%3Ae%5Cu2212%20has%20the%20cage%20structure%20and%20the%20density%20of%20states%20derived%20from%20the%20cages%20may%20play%20an%20important%20role%20in%20the%20superconductivity.%20The%20superconducting%20transition%20temperature%20%28T%20c%29%20is%20%5Cu223c%200.2%20K%20at%20ambient%20pressure%20and%20monotonically%20increases%20up%20to%201.79%20K%20at%204.7%20GPa.%20The%20upper%20critical%20field%20H%20c2%20and%20%5Cu2212dH%20c2%5C%2FdT%20at%20T%20c%2C%20in%20proportion%20to%20the%20density%20of%20states%20%28DOS%29%20at%20Fermi%20energy%20becomes%20larger%20under%20high%20pressure.%20The%20superconductivity%20in%20C12A7%3Ae%5Cu2212%20is%20mediated%20by%20the%20electron-phonon%20interaction%2C%20and%20the%20increase%20of%20Tc%20with%20pressure%20may%20arise%20from%20a%20peak%20structure%20of%20the%20DOS%20of%20cage%20conduction%20band.%22%2C%22date%22%3A%222013%5C%2F08%5C%2F01%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.3938%5C%2Fjkps.63.477%22%2C%22ISSN%22%3A%220374-4884%2C%201976-8524%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.springer.com%5C%2Farticle%5C%2F10.3938%5C%2Fjkps.63.477%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A41%3A27Z%22%7D%7D%2C%7B%22key%22%3A%228M4PNS29%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hanna%20et%20al.%22%2C%22parsedDate%22%3A%222013-09-30%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EHanna%2C%20T.%3B%20Muraba%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Superconductivity%20in%201111-Type%20CaFeAsF%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EInduced%20by%20Selective%20Hydrogen%20Elimination.%20%3Ci%3EApplied%20Physics%20Letters%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E103%3C%5C%2Fi%3E%20%2814%29%2C%20142601.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4823505%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4823505%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Superconductivity%20in%201111-type%20CaFeAsF%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3Einduced%20by%20selective%20hydrogen%20elimination%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Taku%22%2C%22lastName%22%3A%22Hanna%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshinori%22%2C%22lastName%22%3A%22Muraba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%20difference%20in%20thermal%20stability%20of%20F%5Cu2212%20and%20H%5Cu2212%20in%201111-type%20iron%20based%20superconductors%20allows%20selective%20hydrogen%20elimination%20from%20non-superconductive%20CaFeAsF0.8H0.2%20by%20thermal%20annealing.%20The%20analyzed%20chemical%20composition%20of%20the%20resulting%20samples%20indicates%20that%20incorporated%20hydrogen%20was%20selectively%20eliminated%20by%20thermal%20annealing%20at%20553%20K%20for%2072%20h.%20The%20resulting%20hydrogen-eliminated%20sample%20shows%20bulk%20superconductivity%20with%20T%20c%20%3D%2029%20K.%20This%20technique%20may%20be%20used%20for%20indirect%20electron%20doping%20for%20AeFeAeF%20%28Ae%2C%20alkali-earth%20metal%29%20iron%20based%20superconductor%20described%20by%20CaFeAsF1%5Cu2212%20x%20H%20x%20%5Cu2192%20CaFeAsF1%5Cu2212%20x%20%2B%20xe%20%5Cu2212%20%2B%201%5C%2F2xH2%20%5Cu2191.%22%2C%22date%22%3A%222013%5C%2F09%5C%2F30%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F1.4823505%22%2C%22ISSN%22%3A%220003-6951%2C%201077-3118%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fscitation.aip.org%5C%2Fcontent%5C%2Faip%5C%2Fjournal%5C%2Fapl%5C%2F103%5C%2F14%5C%2F10.1063%5C%2F1.4823505%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222023-09-06T03%3A34%3A08Z%22%7D%7D%2C%7B%22key%22%3A%22X8F6K5DD%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fujiwara%20et%20al.%22%2C%22parsedDate%22%3A%222013-11-10%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EFujiwara%2C%20N.%3B%20Iimura%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Yamakawa%2C%20Y.%3B%20Kontani%2C%20H.%20NMR%20Study%20on%20a%20Pnictide%20Superconductor%26%23xA0%3B%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E%26%23xA0%3B%20in%20a%20H-Overdoped%20Regime%3A%20Revival%20of%20Antiferromagnetic%20Fluctuations.%20%3Ci%3EJ%20Supercond%20Nov%20Magn%3C%5C%2Fi%3E%20%3Cb%3E2013%3C%5C%2Fb%3E%2C%20%3Ci%3E27%3C%5C%2Fi%3E%20%284%29%2C%20933%26%23x2013%3B936.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs10948-013-2413-z%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs10948-013-2413-z%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22NMR%20Study%20on%20a%20Pnictide%20Superconductor%20%20LaFeAsO%3Csub%3E1-x%3C%5C%2Fsub%3EH%3Csub%3Ex%3C%5C%2Fsub%3E%20%20in%20a%20H-Overdoped%20Regime%3A%20Revival%20of%20Antiferromagnetic%20Fluctuations%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Fujiwara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Yamakawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Kontani%22%7D%5D%2C%22abstractNote%22%3A%22An%20electron-doped%20high-T%20c%20pnictide%20LaFeAsO1%5Cu2212x%20H%20x%20is%20recently%20known%20for%20having%20double%20superconducting%20%28SC%29%20domes%20in%20the%20phase%20diagram.%20We%20have%20performed%20nuclear%20magnetic%20resonance%20%28NMR%29%20measurements%20in%20an%20H-overdoped%20regime%20to%20investigate%20the%20second%20SC%20dome%20on%20a%20microscopic%20level.%20We%20unexpectedly%20discovered%20that%20the%20linewidths%20of%20both%2075As%20and%201H%20spectra%20broaden%20at%20low%20temperatures%20for%20the%2058%20and%2062.5%20%25%20H-doped%20samples%2C%20indicating%20that%20the%20antiferromagnetic%20%28AF%29%20ordering%20returns%20in%20the%20heavily%20H-doped%20regime.%20The%20finding%20itself%20is%20rare%20because%20an%20excess%20carrier%20doping%20tends%20to%20cause%20Fermi-liquid%20behavior%20in%20strongly%20correlated%20electron%20systems.%20We%20demonstrate%20that%20the%20new%20AF%20ordering%20originates%20from%20the%20nesting%20between%20electron%20pockets.%22%2C%22date%22%3A%222013%5C%2F11%5C%2F10%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1007%5C%2Fs10948-013-2413-z%22%2C%22ISSN%22%3A%221557-1939%2C%201557-1947%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.springer.com%5C%2Farticle%5C%2F10.1007%5C%2Fs10948-013-2413-z%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A53%3A18Z%22%7D%7D%5D%7D
(1)
Hosono, H.; Matsuishi, S. Superconductivity Induced by Hydrogen Anion Substitution in 1111-Type Iron Arsenides. Current Opinion in Solid State and Materials Science 2013, 17 (2), 49–58. https://doi.org/10.1016/j.cossms.2013.03.004.
(1)
Iimura, S.; Matsuishi, S.; Miyakawa, M.; Taniguchi, T.; Suzuki, K.; Usui, H.; Kuroki, K.; Kajimoto, R.; Nakamura, M.; Inamura, Y.; Ikeuchi, K.; Ji, S.; Hosono, H. Switching of Intra-Orbital Spin Excitations in Electron-Doped Iron Pnictide Superconductors. Phys. Rev. B 2013, 88 (6), 060501. https://doi.org/10.1103/PhysRevB.88.060501.
(1)
Park, S.-W.; Mizoguchi, H.; Kodama, K.; Shamoto, S.; Otomo, T.; Matsuishi, S.; Kamiya, T.; Hosono, H. Magnetic Structure and Electromagnetic Properties of LnCrAsO with a ZrCuSiAs-Type Structure (Ln = La, Ce, Pr, and Nd). Inorg. Chem. 2013, 52 (23), 13363–13368. https://doi.org/10.1021/ic401487q.
(1)
Hanna, T.; Matsuishi, S.; Kodama, K.; Otomo, T.; Shamoto, S.; Hosono, H. From Antiferromagnetic Insulator to Ferromagnetic Metal: Effects of Hydrogen Substitution in LaMnAsO. Phys. Rev. B 2013, 87 (2), 020401. https://doi.org/10.1103/PhysRevB.87.020401.
(1)
Suzuki, K.; Usui, H.; Kuroki, K.; Iimura, S.; Sato, Y.; Matsuishi, S.; Hosono, H. Robust Spin Fluctuations and S± Pairing in the Heavily Electron Doped Iron-Based Superconductors. J. Phys. Soc. Jpn. 2013, 82 (8), 083702. https://doi.org/10.7566/JPSJ.82.083702.
(1)
Price, S.; Su, Y.; Xiao, Y.; T. Adroja, D.; Guidi, T.; Mittal, R.; Nandi, S.; Matsuishi, S.; Hosono, H.; Brückel, T. Evidence of Spin Resonance Signal in Oxygen Free Superconducting CaFe0.88Co0.12AsF: An Inelastic Neutron Scattering Study. J. Phys. Soc. Jpn. 2013, 82 (10), 104716. https://doi.org/10.7566/JPSJ.82.104716.
(1)
Lee, K.; Kim, S. W.; Toda, Y.; Matsuishi, S.; Hosono, H. Dicalcium Nitride as a Two-Dimensional Electride with an Anionic Electron Layer. Nature 2013, 494 (7437), 336–340. https://doi.org/10.1038/nature11812.
(1)
Guo, J.; Yamaura, J.; Lei, H.; Matsuishi, S.; Qi, Y.; Hosono, H. Superconductivity in Ban+2Ir4nGe12n+4 (N=1,2) with Cage Structure and Softening of Low-Lying Localized Mode. Phys. Rev. B 2013, 88 (14), 140507. https://doi.org/10.1103/PhysRevB.88.140507.
(1)
Fujiwara, N.; Tsutsumi, S.; Iimura, S.; Matsuishi, S.; Hosono, H.; Yamakawa, Y.; Kontani, H. Detection of Antiferromagnetic Ordering in Heavily Doped LaFeAsO1-xHx Pnictide Superconductors Using Nuclear-Magnetic-Resonance Techniques. Phys. Rev. Lett. 2013, 111 (9), 097002. https://doi.org/10.1103/PhysRevLett.111.097002.
(1)
松石 聡; 細野 秀雄. 鉄系超伝導体. In 超伝導現象と高温超伝導体; エヌ・ティー・エス, 2013; pp 72–79.
(1)
Fujiwara, N.; Matsuishi, S.; Kamihara, Y.; Hosono, H. Homogeneous Coexistence in CaFe1-xCoxAsF and Phase Segregation in LaFeAsO1-xFx Studied via NMR. J Supercond Nov Magn 2013, 26 (8), 2689–2692. https://doi.org/10.1007/s10948-013-2161-0.
(1)
Funabiki, F.; Matsuishi, S.; Hosono, H. Local Structure around Rare-Earth Ions in B2O3 Glass at High Pressure. Journal of Applied Physics 2013, 113 (22), 223508. https://doi.org/10.1063/1.4811185.
(1)
Fujiwara, N.; Kamihara, Y.; Matsuishi, S.; Hosono, H. Homogeneous Coexistence and Phase Segregation in 1111 Iron-Based Pnictides Studied via NMR. Journal of the Korean Physical Society 2013, 62 (12), 2004–2006. https://doi.org/10.3938/jkps.62.2004.
(1)
Tanaka, S.; Kato, T.; Miyake, A.; Kagayama, T.; Shimizu, K.; Kim, S. W.; Matsuishi, S.; Hosono, H. Strong Enhancement of Superconductivity in Inorganic Electride 12CaO·7Al2O3:E− under High Pressure. Journal of the Korean Physical Society 2013, 63 (3), 477–480. https://doi.org/10.3938/jkps.63.477.
(1)
Hanna, T.; Muraba, Y.; Matsuishi, S.; Hosono, H. Superconductivity in 1111-Type CaFeAsF1-xHxInduced by Selective Hydrogen Elimination. Applied Physics Letters 2013, 103 (14), 142601. https://doi.org/10.1063/1.4823505.
(1)
Fujiwara, N.; Iimura, S.; Matsuishi, S.; Hosono, H.; Yamakawa, Y.; Kontani, H. NMR Study on a Pnictide Superconductor LaFeAsO1-xHx in a H-Overdoped Regime: Revival of Antiferromagnetic Fluctuations. J Supercond Nov Magn 2013, 27 (4), 933–936. https://doi.org/10.1007/s10948-013-2413-z.
244926
P5622579
2012
items
1
american-chemical-society-with-titles-sentence-case-doi
0
date
asc
year
6
https://www.mces.titech.ac.jp/authors/matsuishi/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-c69d263970bbe910afc55753709ceae7%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22M6PAJDSP%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kitano%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EKitano%2C%20M.%3B%20Inoue%2C%20Y.%3B%20Yamazaki%2C%20Y.%3B%20Hayashi%2C%20F.%3B%20Kanbara%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Yokoyama%2C%20T.%3B%20Kim%2C%20S.-W.%3B%20Hara%2C%20M.%3B%20Hosono%2C%20H.%20Ammonia%20Synthesis%20Using%20a%20Stable%20Electride%20as%20an%20Electron%20Donor%20and%20Reversible%20Hydrogen%20Store.%20%3Ci%3ENat%20Chem%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E4%3C%5C%2Fi%3E%20%2811%29%2C%20934%26%23x2013%3B940.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fnchem.1476%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fnchem.1476%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ammonia%20synthesis%20using%20a%20stable%20electride%20as%20an%20electron%20donor%20and%20reversible%20hydrogen%20store%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masaaki%22%2C%22lastName%22%3A%22Kitano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yasunori%22%2C%22lastName%22%3A%22Inoue%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Youhei%22%2C%22lastName%22%3A%22Yamazaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fumitaka%22%2C%22lastName%22%3A%22Hayashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shinji%22%2C%22lastName%22%3A%22Kanbara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshiharu%22%2C%22lastName%22%3A%22Yokoyama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sung-Wng%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michikazu%22%2C%22lastName%22%3A%22Hara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Industrially%2C%20the%20artificial%20fixation%20of%20atmospheric%20nitrogen%20to%20ammonia%20is%20carried%20out%20using%20the%20Haber%5Cu2013Bosch%20process%2C%20but%20this%20process%20requires%20high%20temperatures%20and%20pressures%2C%20and%20consumes%20more%20than%201%25%20of%20the%20world%27s%20power%20production.%20Therefore%20the%20search%20is%20on%20for%20a%20more%20environmentally%20benign%20process%20that%20occurs%20under%20milder%20conditions.%20Here%2C%20we%20report%20that%20a%20Ru-loaded%20electride%20%5BCa24Al28O64%5D4%2B%28e%5Cu2212%294%20%28Ru%5C%2FC12A7%3Ae%5Cu2212%29%2C%20which%20has%20high%20electron-donating%20power%20and%20chemical%20stability%2C%20works%20as%20an%20efficient%20catalyst%20for%20ammonia%20synthesis.%20Highly%20efficient%20ammonia%20synthesis%20is%20achieved%20with%20a%20catalytic%20activity%20that%20is%20an%20order%20of%20magnitude%20greater%20than%20those%20of%20other%20previously%20reported%20Ru-loaded%20catalysts%20and%20with%20almost%20half%20the%20reaction%20activation%20energy.%20Kinetic%20analysis%20with%20infrared%20spectroscopy%20reveals%20that%20C12A7%3Ae%5Cu2212%20markedly%20enhances%20N2%20dissociation%20on%20Ru%20by%20the%20back%20donation%20of%20electrons%20and%20that%20the%20poisoning%20of%20ruthenium%20surfaces%20by%20hydrogen%20adatoms%20can%20be%20suppressed%20effectively%20because%20of%20the%20ability%20of%20C12A7%3Ae%5Cu2212%20to%20store%20hydrogen%20reversibly.%22%2C%22date%22%3A%2211%5Cu6708%202012%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1038%5C%2Fnchem.1476%22%2C%22ISSN%22%3A%221755-4330%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.nature.com%5C%2Fnchem%5C%2Fjournal%5C%2Fv4%5C%2Fn11%5C%2Ffull%5C%2Fnchem.1476.html%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222014-03-25T10%3A00%3A01Z%22%7D%7D%2C%7B%22key%22%3A%22DZ5A6M7G%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Liu%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ELiu%2C%20X.%3B%20Matsuishi%2C%20S.%3B%20Fujitsu%2C%20S.%3B%20Hosono%2C%20H.%20MgFeGe%20as%20an%20Isoelectronic%20and%20Isostructural%20Analog%20of%20the%20Superconductor%20LiFeAs.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E85%3C%5C%2Fi%3E%20%2810%29%2C%20104403.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.85.104403%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.85.104403%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22MgFeGe%20as%20an%20isoelectronic%20and%20isostructural%20analog%20of%20the%20superconductor%20LiFeAs%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xiaofeng%22%2C%22lastName%22%3A%22Liu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Fujitsu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22MgFeGe%20with%20a%20CeFeSi-type%20structure%20was%20synthesized%20by%20high-pressure%20method%2C%20and%20its%20electrical%20transport%2C%20magnetic%20properties%2C%20and%20electronic%20structure%20were%20investigated.%20It%20is%20found%20that%20MgFeGe%20has%20the%20smallest%20c%3Cmath%3E%3Cmi%20_moz-math-font-style%3D%5C%22italic%5C%22%3Ec%3C%5C%2Fmi%3E%3C%5C%2Fmath%3E%5C%2Fa%3Cmath%3E%3Cmi%20_moz-math-font-style%3D%5C%22italic%5C%22%3Ea%3C%5C%2Fmi%3E%3C%5C%2Fmath%3E%20%281.65%29%20ratio%20and%20the%20shortest%20in-plane%20Fe-Fe%20distance%20%282.75%20%5Cu00c5%29%20among%20CeFeSi-type%20and%20ThCr2%3Cmath%3E%3Cmsub%3E%3Cmrow%3E%3C%5C%2Fmrow%3E%3Cmn%3E2%3C%5C%2Fmn%3E%3C%5C%2Fmsub%3E%3C%5C%2Fmath%3ESi2%3Cmath%3E%3Cmsub%3E%3Cmrow%3E%3C%5C%2Fmrow%3E%3Cmn%3E2%3C%5C%2Fmn%3E%3C%5C%2Fmsub%3E%3C%5C%2Fmath%3E-type%20rare-earth%20iron%20silicides%20and%20germanides%20containing%20square%20lattice%20of%20iron.%20Further%20measurements%20demonstrate%20that%20this%20compound%20exhibits%20metallic%20conduction%20and%20Pauli%20paramagnetism%20from%20room%20temperature%20down%20to%202%20K.%20From%20density%20functional%20theory%20calculations%20it%20is%20revealed%20that%20MgFeGe%20favors%20the%20same%20antiferromagnetic%20ground%20state%20magnetic%20configuration%20as%20LiFeAs.%20Moreover%2C%20considerable%20resemblance%20in%20the%20band%20dispersion%2C%20density%20of%20state%2C%20and%20Fermi%20surface%20was%20confirmed%20between%20MgFeGe%20and%20its%20isoelectronic%20superconducting%20counterpart%20LiFeAs.%20The%20results%2C%20however%2C%20suggest%20that%20the%20presence%20of%20the%20basic%20structural%20and%20electronic%20features%20of%20iron-based%20superconductors%20in%20MgFeGe%20does%20not%20necessarily%20lead%20to%20superconductivity%2C%20and%20further%20investigation%20is%20therefore%20still%20deserved%20to%20understand%20the%20related%20mechanisms.%22%2C%22date%22%3A%223%5Cu6708%208%2C%202012%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.85.104403%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.85.104403%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222013-12-24T21%3A36%3A01Z%22%7D%7D%2C%7B%22key%22%3A%22EZQ6BHP4%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Guo%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EGuo%2C%20J.%3B%20Qi%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Tc%20Maximum%20in%20Solid%20Solution%20of%20Pyrite%20IrSe%3Csub%3E2%3C%5C%2Fsub%3E%26%23x2013%3BRhSe%3Csub%3E2%3C%5C%2Fsub%3E%20Induced%20by%20Destabilization%20of%20Anion%20Dimers.%20%3Ci%3EJ.%20Am.%20Chem.%20Soc.%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E134%3C%5C%2Fi%3E%20%2849%29%2C%2020001%26%23x2013%3B20004.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fja309724w%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fja309724w%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Tc%20Maximum%20in%20Solid%20Solution%20of%20Pyrite%20IrSe%3Csub%3E2%3C%5C%2Fsub%3E%5Cu2013RhSe%3Csub%3E2%3C%5C%2Fsub%3E%20Induced%20by%20Destabilization%20of%20Anion%20Dimers%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jiangang%22%2C%22lastName%22%3A%22Guo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yanpeng%22%2C%22lastName%22%3A%22Qi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20have%20established%20a%20well-defined%20dome-shaped%20Tc%20curve%20in%20Ir0.94%3FxRhxSe2%20superconductors.%20The%20maximum%20Tconset%20of%209.6%20K%20was%20obtained%20at%20x%20%3D%200.36%2C%20at%20which%20the%20Se%3FSe%20separation%20in%20the%20dimer%20anion%20is%20the%20longest.%20Simultaneously%2C%20the%20destabilization%20of%20Se%3FSe%20dimers%20accompanied%20by%20partial%20electron%20transfer%20from%20the%20Ir%5C%2FRh%20to%20the%20chalcogenide%20ions%20resulted%20in%20the%20emergence%20of%20optimal%20Tc.%22%2C%22date%22%3A%2212%5Cu6708%2012%2C%202012%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Fja309724w%22%2C%22ISSN%22%3A%220002-7863%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Fja309724w%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A55%3A46Z%22%7D%7D%2C%7B%22key%22%3A%22K7Q7KSAM%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Daicho%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EDaicho%2C%20H.%3B%20Iwasaki%2C%20T.%3B%20Enomoto%2C%20K.%3B%20Sasaki%2C%20Y.%3B%20Maeno%2C%20Y.%3B%20Shinomiya%2C%20Y.%3B%20Aoyagi%2C%20S.%3B%20Nishibori%2C%20E.%3B%20Sakata%2C%20M.%3B%20Sawa%2C%20H.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20A%20Novel%20Phosphor%20for%20Glareless%20White%20Light-Emitting%20Diodes.%20%3Ci%3ENat%20Commun%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E3%3C%5C%2Fi%3E%2C%201132.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fncomms2138%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fncomms2138%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22A%20novel%20phosphor%20for%20glareless%20white%20light-emitting%20diodes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hisayoshi%22%2C%22lastName%22%3A%22Daicho%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takeshi%22%2C%22lastName%22%3A%22Iwasaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kiminori%22%2C%22lastName%22%3A%22Enomoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yasutaka%22%2C%22lastName%22%3A%22Sasaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yuzo%22%2C%22lastName%22%3A%22Maeno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yu%22%2C%22lastName%22%3A%22Shinomiya%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shinobu%22%2C%22lastName%22%3A%22Aoyagi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Eiji%22%2C%22lastName%22%3A%22Nishibori%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Makoto%22%2C%22lastName%22%3A%22Sakata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Sawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%20luminous%20efficiency%20of%20white%20light-emitting%20diodes%2C%20which%20are%20used%20as%20light%20sources%20for%20next-generation%20illumination%2C%20is%20continuously%20improving.%20Presently%20available%20white%20light-emitting%20diodes%20emit%20with%20extremely%20high%20luminance%20because%20their%20emission%20areas%20are%20much%20smaller%20than%20those%20of%20conventional%20light%20sources.%20Consequently%2C%20white%20light-emitting%20diodes%20produce%20a%20glare%20that%20is%20uncomfortable%20to%20the%20human%20eye.%20Here%20we%20report%20a%20yellow-emitting%20phosphor%2C%20the%20Eu2%2B-doped%20chlorometasilicate%20%28Ca1-x-y%2CSrx%2CEuy%297%28SiO3%296Cl2%2C%20which%20can%20be%20used%20to%20create%20glareless%20white%20light-emitting%20diodes.%20The%20%28Ca1-x-y%2CSrx%2CEuy%297%28SiO3%296Cl2%20exhibits%20a%20large%20Stokes%20shift%2C%20efficiently%20converting%20violet%20excitation%20light%20to%20yellow%20luminescence%2C%20and%20phosphors%20based%20on%20this%20host%20material%20have%20much%20less%20blue%20absorption%20than%20other%20phosphors.%20We%20used%20crystal%20structure%20analysis%20to%20determine%20the%20origin%20of%20the%20desired%20luminescence%2C%20and%20we%20used%20%28Ca1-x-y%2CSrx%2CEuy%297%28SiO3%296Cl2%20and%20a%20blue-emitting%20phosphor%20in%20combination%20with%20a%20violet%20chip%20to%20fabricate%20glareless%20white%20light-emitting%20diodes%20that%20have%20large%20emission%20areas%20and%20are%20suitable%20for%20general%20illumination.%22%2C%22date%22%3A%2210%5Cu6708%2016%2C%202012%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1038%5C%2Fncomms2138%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.nature.com%5C%2Fncomms%5C%2Fjournal%5C%2Fv3%5C%2Fn10%5C%2Ffull%5C%2Fncomms2138.html%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222018-05-02T05%3A23%3A31Z%22%7D%7D%2C%7B%22key%22%3A%22ZI6RNVU7%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Liu%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ELiu%2C%20X.%3B%20Matsuishi%2C%20S.%3B%20Fujitsu%2C%20S.%3B%20Ishigaki%2C%20T.%3B%20Kamiyama%2C%20T.%3B%20Hosono%2C%20H.%20Layered%20Hydride%20CaNiGeH%20with%20a%20ZrCuSiAs-Type%20Structure%3A%20Crystal%20Structure%2C%20Chemical%20Bonding%2C%20and%20Magnetism%20Induced%20by%20Mn%20Doping.%20%3Ci%3EJ.%20Am.%20Chem.%20Soc.%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E134%3C%5C%2Fi%3E%20%2828%29%2C%2011687%26%23x2013%3B11694.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fja3026104%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fja3026104%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Layered%20Hydride%20CaNiGeH%20with%20a%20ZrCuSiAs-type%20Structure%3A%20Crystal%20Structure%2C%20Chemical%20Bonding%2C%20and%20Magnetism%20Induced%20by%20Mn%20Doping%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xiaofeng%22%2C%22lastName%22%3A%22Liu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Fujitsu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toru%22%2C%22lastName%22%3A%22Ishigaki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takashi%22%2C%22lastName%22%3A%22Kamiyama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Stimulated%20by%20the%20discovery%20of%20the%20iron%20oxypnictide%20superconductor%20with%20ZrCuSiAs-type%20structure%20in%202008%2C%20extensive%20exploration%20of%20its%20isostructural%20and%20isoelectronic%20compounds%20has%20started.%20These%20compounds%2C%20including%20oxides%2C%20fluorides%2C%20and%20hydrides%2C%20can%20all%20be%20simply%20recognized%20as%20valence%20compounds%20for%20which%20the%20octet%20rule%20is%20valid.%20We%20report%20herein%20the%20first%20example%20of%20a%20ZrCuSiAs-type%20hydride%2C%20CaNiGeH%2C%20which%20violates%20the%20octet%20rule.%20This%20hydride%20was%20synthesized%20by%20hydrogenation%20of%20the%20CeFeSi-type%20compound%20CaNiGe%20under%20pressurized%20hydrogen.%20Powder%20diffraction%20and%20theoretical%20simulation%20confirm%20that%20H%20enters%20into%20the%20interstitial%20position%20of%20the%20Ca4%20tetrahedron%2C%20leading%20to%20notable%20anisotropic%20expansion%20of%20the%20unit%20cell%20along%20the%20c%20axis.%20Density%20functional%20theory%20calculations%20indicate%20the%20modification%20of%20the%20chemical%20bonding%20and%20formation%20of%20ionic%20Ca%3FH%20bond%20as%20a%20result%20of%20hydrogen%20insertion.%20Furthermore%2C%20CaNiGeH%20shows%20Pauli%20paramagnetism%20and%20metallic%20conduction%20similar%20to%20that%20of%20CaNiGe%2C%20but%20its%20carrier%20type%20changes%20to%20hole%20and%20the%20carrier%20density%20is%20drastically%20reduced%20as%20compared%20to%20CaNiGe.%20Mn-doping%20at%20the%20Ni%20site%20introduces%20magnetism%20to%20both%20the%20parent%20compound%20and%20the%20hydride.%20The%20measurement%20demonstrates%20that%20hydrogenation%20of%20CaNi1%3FxMnxGe%20reduces%20ferromagnetic%20ordering%20of%20Mn%20ions%20and%20induces%20huge%20magnetic%20hysteresis%2C%20whereas%20the%20spin%20glass%20state%20observed%20for%20the%20parent%20compound%20is%20preserved%20in%20the%20hydride.%20The%20hydrogenation-induced%20changes%20in%20the%20electric%20and%20magnetic%20properties%20are%20interpreted%20in%20terms%20of%20development%20of%20two-dimensionality%20in%20crystal%20structure%20as%20well%20as%20electronic%20state.%22%2C%22date%22%3A%227%5Cu6708%2018%2C%202012%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Fja3026104%22%2C%22ISSN%22%3A%220002-7863%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Fja3026104%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222013-01-04T14%3A41%3A25Z%22%7D%7D%2C%7B%22key%22%3A%22VBCCBTHG%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Matsuishi%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMatsuishi%2C%20S.%3B%20Hanna%2C%20T.%3B%20Muraba%2C%20Y.%3B%20Kim%2C%20S.%20W.%3B%20Kim%2C%20J.%20E.%3B%20Takata%2C%20M.%3B%20Shamoto%2C%20S.%3B%20Smith%2C%20R.%20I.%3B%20Hosono%2C%20H.%20Structural%20Analysis%20and%20Superconductivity%20of%20CeFeAsO%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E85%3C%5C%2Fi%3E%20%281%29%2C%20014514.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.85.014514%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.85.014514%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Structural%20analysis%20and%20superconductivity%20of%20CeFeAsO%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Taku%22%2C%22lastName%22%3A%22Hanna%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshinori%22%2C%22lastName%22%3A%22Muraba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sung%20Wng%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jung%20Eun%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masaki%22%2C%22lastName%22%3A%22Takata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shin-ich%22%2C%22lastName%22%3A%22Shamoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ronald%20I.%22%2C%22lastName%22%3A%22Smith%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20performed%20the%20neutron%20powder%20diffraction%20%28NPD%29%20and%20synchrotron%20x-ray%20diffraction%20measurements%20on%20CeFeAsO1%5Cu2212x%28D%2CH%29x%20%28x%20%3D%200.0%20%5Cu2212%200.48%29%20as%20a%20representative%20of%201111-type%20family%20of%20iron-based%20superconductors%20LnFeAsO1%5Cu2212xHx%20%28Ln%20%3D%20lanthanoid%29.%20Deuterated%20and%20hydrogenated%20samples%20%28CeFeAsO1%5Cu2212xDx%20and%20CeFeAsO1%5Cu2212xHx%29%20were%20synthesized%20by%20the%20solid-state%20reaction%20of%20a%20metal%20oxide%2C%20arsenides%2C%20and%20a%20hydride%20and%20a%20deuteride%20source%20under%20an%20applied%20pressure%20of%202%20GPa.%20No%20distinct%20differences%20were%20found%20between%20the%20structural%20and%20superconducting%20properties%20of%20the%20hydride%20and%20deuteride%20samples.%20Rietveld%20analyses%20of%20the%20NPD%20patterns%20demonstrated%20that%20deuterium%20exclusively%20substitutes%20on%20the%20oxygen%20sites%20in%20the%201111-type%20structures%20according%20to%20the%20nominal%20composition.%20Bulk%20superconductivity%20was%20observed%20over%20a%20wide%20x%20region%20%280.1%20%3C%20x%20%3C%200.4%29%20and%20the%20superconducting%20dome%20had%20a%20rather%20flat%20shape%20with%20a%20maximum%20Tc%20%3D%2047%20K%20at%20around%20x%20%3D%200.25.%20It%20was%20concluded%20from%20density%20functional%20theory%20calculations%20and%20comparison%20with%20the%20superconducting%20dome%20of%20the%20fluorine-substituted%20system%20that%20the%20charge%20state%20of%20the%20hydrogen%20substituting%20the%20oxygen%20sites%20was%20%5Cu22121.%20The%20relationship%20between%20the%20lattice%20parameter%20a%20and%20Tc%20in%20our%20samples%20prepared%20from%20metal%20hydrides%20is%20almost%20the%20same%20as%20that%20reported%20previously%20for%20samples%20prepared%20from%20cerium%20hydroxide.%20These%20results%20strongly%20suggest%20that%20H%5Cu2212%20ions%20exclusively%20occupy%20the%20oxygen%20sites%20in%20both%20samples%2C%20regardless%20of%20the%20hydrogen%20species%20in%20the%20starting%20material.%22%2C%22date%22%3A%221%5Cu6708%2019%2C%202012%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.85.014514%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.85.014514%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222023-09-06T03%3A36%3A03Z%22%7D%7D%2C%7B%22key%22%3A%22B4QEZHJT%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Qi%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EQi%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Guo%2C%20J.%3B%20Mizoguchi%2C%20H.%3B%20Hosono%2C%20H.%20Superconductivity%20in%20Defective%20Pyrite-Type%20Iridium%20Chalcogenides%20Ir%3Csub%3Ex%3C%5C%2Fsub%3ECh%3Csub%3E2%3C%5C%2Fsub%3E%20%28Ch%3DSe%20and%20Te%29.%20%3Ci%3EPhys.%20Rev.%20Lett.%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E109%3C%5C%2Fi%3E%20%2821%29%2C%20217002.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevLett.109.217002%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevLett.109.217002%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Superconductivity%20in%20Defective%20Pyrite-Type%20Iridium%20Chalcogenides%20Ir%3Csub%3Ex%3C%5C%2Fsub%3ECh%3Csub%3E2%3C%5C%2Fsub%3E%20%28Ch%3DSe%20and%20Te%29%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yanpeng%22%2C%22lastName%22%3A%22Qi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jiangang%22%2C%22lastName%22%3A%22Guo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Mizoguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20superconductivity%20in%20defective%20pyrite-type%20iridium%20chalcogenides%20IrxCh2%20%28Ch%3DSe%20and%20Te%29.%20Maximum%20values%20of%20Tc%20of%206.4%20K%20for%20Ir0.91Se2%20and%204.7%20K%20for%20Ir0.93Te2%20were%20observed.%20It%20was%20found%20that%20Ir0.75Ch2%20%28Ir3Ch8%29%20is%20close%20to%20the%20boundary%20between%20metallic%20and%20insulating%20states%20and%20IrxCh2%20systems%20undergo%20nonmetal%20to%20metal%20transitions%20as%20x%20increases.%20On%20the%20basis%20of%20density%20functional%20theory%20calculations%20and%20the%20observed%20large%20variation%20in%20the%20Ch-Ch%20distance%20with%20x%2C%20we%20suggest%20that%20Ir0.75Ch2%20%28Ir3Ch8%29%20is%20the%20parent%20compound%20for%20the%20present%20superconductors.%22%2C%22date%22%3A%2211%5Cu6708%2020%2C%202012%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevLett.109.217002%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevLett.109.217002%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A55%3A19Z%22%7D%7D%2C%7B%22key%22%3A%222EVXUCGX%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Tsutsumi%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ETsutsumi%2C%20S.%3B%20Fujiwara%2C%20N.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Spin%20Density%20Wave%20and%20Superconductivity%20in%20CaFe%3Csub%3E1-x%3C%5C%2Fsub%3ECo%3Csub%3Ex%3C%5C%2Fsub%3EAsF%20Studied%20by%20Nuclear%20Magnetic%20Resonance.%20%3Ci%3EPhys.%20Rev.%20B%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E86%3C%5C%2Fi%3E%20%286%29%2C%20060515.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.86.060515%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.86.060515%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Spin%20density%20wave%20and%20superconductivity%20in%20CaFe%3Csub%3E1-x%3C%5C%2Fsub%3ECo%3Csub%3Ex%3C%5C%2Fsub%3EAsF%20studied%20by%20nuclear%20magnetic%20resonance%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Tsutsumi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Fujiwara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22We%20performed%20nuclear%20magnetic%20resonance%20measurements%20to%20investigate%20the%20evolution%20of%20spin-density-wave%20%28SDW%29%20and%20superconducting%20%28SC%29%20states%20upon%20electron%20doping%20in%20CaFe1%5Cu2212xCoxAsF%2C%20which%20exhibits%20an%20intermediate%20phase%20diagram%20between%20those%20of%20LaFeAsO1%5Cu2212xFx%20and%20Ba%28Fe1%5Cu2212xCox%292As2.%20We%20found%20that%20homogeneous%20coexistence%20of%20the%20incommensurate%20SDW%20and%20SC%20states%20occurs%20only%20in%20a%20narrow%20doping%20region%20around%20the%20crossover%20regime%2C%20which%20supports%20S%2B%5Cu2212-wave%20symmetry.%20However%2C%20only%20the%20structural%20phase%20transition%20survives%20upon%20further%20doping%2C%20which%20agrees%20with%20predictions%20from%20orbital%20fluctuation%20theory.%20The%20transitional%20features%20upon%20electron%20doping%20imply%20that%20both%20spin%20and%20orbital%20fluctuations%20are%20involved%20in%20the%20superconducting%20mechanism.%22%2C%22date%22%3A%228%5Cu6708%2029%2C%202012%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.86.060515%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.86.060515%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222016-04-15T03%3A53%3A55Z%22%7D%7D%2C%7B%22key%22%3A%22U3VVU4WB%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Takahashi%20et%20al.%22%2C%22parsedDate%22%3A%222012-05-10%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ETakahashi%2C%20H.%3B%20Tomita%2C%20T.%3B%20Soeda%2C%20H.%3B%20Ebata%2C%20M.%3B%20Okuma%2C%20K.%3B%20Hanna%2C%20T.%3B%20Muraba%2C%20Y.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20High-Pressure%20Studies%20for%20Hydrogen%20Substituted%20CaFeAsF%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%20and%20SmFeAsO%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E.%20%3Ci%3EJ%20Supercond%20Nov%20Magn%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E25%3C%5C%2Fi%3E%20%285%29%2C%201293%26%23x2013%3B1296.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs10948-012-1597-y%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs10948-012-1597-y%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22High-Pressure%20Studies%20for%20Hydrogen%20Substituted%20CaFeAsF%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%20and%20SmFeAsO%3Csub%3E1-%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3EH%3Csub%3E%3Ci%3Ex%3C%5C%2Fi%3E%3C%5C%2Fsub%3E%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Takahashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Tomita%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Soeda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Ebata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Okuma%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Hanna%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Muraba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Recently%20hydrogen%20substituted%20CaFeAsF1%5Cu2212x%20H%20x%20and%20SmFeAsO1%5Cu2212x%20H%20x%20have%20been%20successfully%20synthesized.%20Hydrogen%20atoms%20are%20incorporated%20as%20H%5Cu2212%20ions%20at%20the%20F%5Cu2212%20sites.%20However%2C%20H%20substitution%20for%20non-superconducting%20CaFeAsF%20does%20not%20induce%20superconductivity%20because%20of%20isovalent%20substitution.%20Since%20CaFeAsF%20is%20known%20to%20exhibit%20superconductivity%20under%20high%20pressure%2C%20electrical%20resistivity%20and%20X-ray%20diffraction%20measurements%20have%20been%20carried%20out%20for%20CaFeAsH%20under%20high%20pressure%20in%20order%20to%20study%20the%20superconductivity%20for%20the%20material%20having%20Ca%5Cu2013H%20layer.%20Electrical%20resistivity%20measurements%20also%20have%20been%20done%20for%20SmFeAsO1%5Cu2212x%20H%20x%20from%20under-doped%20to%20over-doped%20region%20%28x%3D0.5%29.%22%2C%22date%22%3A%222012%5C%2F05%5C%2F10%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1007%5C%2Fs10948-012-1597-y%22%2C%22ISSN%22%3A%221557-1939%2C%201557-1947%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Flink.springer.com%5C%2Farticle%5C%2F10.1007%5C%2Fs10948-012-1597-y%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222024-11-13T03%3A02%3A40Z%22%7D%7D%2C%7B%22key%22%3A%22A2G2S7AD%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Mishra%20et%20al.%22%2C%22parsedDate%22%3A%222012-06-09%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMishra%2C%20S.%20K.%3B%20Mittal%2C%20R.%3B%20Sastry%2C%20P.%20U.%3B%20Chaplot%2C%20S.%20L.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20High%20Temperature%20Structural%20Phase%20Transitions%20in%20FeAs%20Based%20Compounds.%20In%20%3Ci%3EAIP%20Conference%20Proceedings%3C%5C%2Fi%3E%3B%20American%20Institute%20of%20Physics%2C%202012%3B%20Vol.%201447%2C%20pp%2095%26%23x2013%3B96.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4709898%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4709898%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22conferencePaper%22%2C%22title%22%3A%22High%20temperature%20structural%20phase%20transitions%20in%20FeAs%20based%20compounds%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%20K.%22%2C%22lastName%22%3A%22Mishra%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Mittal%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%20U.%22%2C%22lastName%22%3A%22Sastry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%20L.%22%2C%22lastName%22%3A%22Chaplot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222012-06-09%22%2C%22proceedingsTitle%22%3A%22AIP%20Conference%20Proceedings%22%2C%22conferenceName%22%3A%22%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F1.4709898%22%2C%22ISBN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Faip.scitation.org%5C%2Fdoi%5C%2F10.1063%5C%2F1.4709898%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-10-04T02%3A58%3A19Z%22%7D%7D%2C%7B%22key%22%3A%22SUREIAJG%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Ryu%20et%20al.%22%2C%22parsedDate%22%3A%222012-07-01%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ERyu%2C%20G.%3B%20Kim%2C%20S.%20W.%3B%20Mizoguchi%2C%20H.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Superconductivity%20in%20a%20PbFCl-Type%20Pnictide%3A%20NbSiAs.%20%3Ci%3EEPL%20%28Europhysics%20Letters%29%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E99%3C%5C%2Fi%3E%20%282%29%2C%2027002.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1209%5C%2F0295-5075%5C%2F99%5C%2F27002%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1209%5C%2F0295-5075%5C%2F99%5C%2F27002%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Superconductivity%20in%20a%20PbFCl-type%20pnictide%3A%20NbSiAs%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gihun%22%2C%22lastName%22%3A%22Ryu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sung%20Wng%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroshi%22%2C%22lastName%22%3A%22Mizoguchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222012-07-01%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1209%5C%2F0295-5075%5C%2F99%5C%2F27002%22%2C%22ISSN%22%3A%220295-5075%2C%201286-4854%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fiopscience.iop.org%5C%2F0295-5075%5C%2F99%5C%2F27002%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222012-08-09T14%3A16%3A42Z%22%7D%7D%2C%7B%22key%22%3A%22PCUXBV8H%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Iimura%20et%20al.%22%2C%22parsedDate%22%3A%222012-07-10%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EIimura%2C%20S.%3B%20Matuishi%2C%20S.%3B%20Sato%2C%20H.%3B%20Hanna%2C%20T.%3B%20Muraba%2C%20Y.%3B%20Kim%2C%20S.%20W.%3B%20Kim%2C%20J.%20E.%3B%20Takata%2C%20M.%3B%20Hosono%2C%20H.%20Two-Dome%20Structure%20in%20Electron-Doped%20Iron%20Arsenide%20Superconductors.%20%3Ci%3ENature%20Communications%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E3%3C%5C%2Fi%3E%2C%20943.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fncomms1913%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fncomms1913%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Two-dome%20structure%20in%20electron-doped%20iron%20arsenide%20superconductors%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soshi%22%2C%22lastName%22%3A%22Iimura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hikaru%22%2C%22lastName%22%3A%22Sato%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Taku%22%2C%22lastName%22%3A%22Hanna%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshinori%22%2C%22lastName%22%3A%22Muraba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sung%20Wng%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jung%20Eun%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masaki%22%2C%22lastName%22%3A%22Takata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Iron%20arsenide%20superconductors%20based%20on%20the%20material%20LaFeAsO1%5Cu2212xFx%20are%20characterized%20by%20a%20two-dimensional%20Fermi%20surface%20%28FS%29%20consisting%20of%20hole%20and%20electron%20pockets%20yielding%20structural%20and%20antiferromagnetic%20transitions%20at%20x%3D0.%20Electron%20doping%20by%20substituting%20O2%5Cu2212%20with%20F%5Cu2212%20suppresses%20these%20transitions%20and%20gives%20rise%20to%20superconductivity%20with%20a%20maximum%20Tc%20of%2026%20K%20at%20x%3D0.1.%20However%2C%20the%20over-doped%20region%20cannot%20be%20accessed%20due%20to%20the%20poor%20solubility%20of%20F%5Cu2212%20above%20x%3D0.2.%20Here%20we%20overcome%20this%20problem%20by%20doping%20LaFeAsO%20with%20hydrogen.%20We%20report%20the%20phase%20diagram%20of%20LaFeAsO1%5Cu2212xHx%20%28x%3C0.53%29%20and%2C%20in%20addition%20to%20the%20conventional%20superconducting%20dome%20seen%20in%20LaFeAsO1%5Cu2212xFx%2C%20we%20find%20a%20second%20dome%20in%20the%20range%200.21%3Cx%3C0.53%2C%20with%20a%20maximum%20Tc%20of%2036%20K%20at%20x%3D0.3.%20Density%20functional%20theory%20calculations%20reveal%20that%20the%20three%20Fe%203d%20bands%20%28xy%2C%20yz%20and%20zx%29%20become%20degenerate%20at%20x%3D0.36%2C%20whereas%20the%20FS%20nesting%20is%20weakened%20monotonically%20with%20x.%20These%20results%20imply%20that%20the%20band%20degeneracy%20has%20an%20important%20role%20to%20induce%20high%20Tc.%5CnView%20full%20text%22%2C%22date%22%3A%222012-07-10%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1038%5C%2Fncomms1913%22%2C%22ISSN%22%3A%222041-1723%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.nature.com%5C%2Fncomms%5C%2Fjournal%5C%2Fv3%5C%2Fn7%5C%2Fabs%5C%2Fncomms1913.html%3FWT.ec_id%3DNCOMMS-20120710%22%2C%22collections%22%3A%5B%22P5622579%22%2C%22CTGLM3Q9%22%5D%2C%22dateModified%22%3A%222016-04-15T01%3A57%3A30Z%22%7D%7D%2C%7B%22key%22%3A%22UPE6P2EN%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Mishra%20et%20al.%22%2C%22parsedDate%22%3A%222012-07-30%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMishra%2C%20S.%20K.%3B%20Mittal%2C%20R.%3B%20Chaplot%2C%20S.%20L.%3B%20Ovsyannikov%2C%20S.%20V.%3B%20Trots%2C%20D.%20M.%3B%20Dubrovinsky%2C%20L.%3B%20Su%2C%20Y.%3B%20Brueckel%2C%20T.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%3B%20Garbarino%2C%20G.%20Pressure-Driven%20Phase%20Transition%20in%20CaFeAsF%20at%2040%20and%20300%20K.%20In%20%3Ci%3EJournal%20of%20Physics%3A%20Conference%20Series%3C%5C%2Fi%3E%3B%20Mumbai%2C%202012%3B%20Vol.%20377%2C%20p%20012034.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1742-6596%5C%2F377%5C%2F1%5C%2F012034%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1742-6596%5C%2F377%5C%2F1%5C%2F012034%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22conferencePaper%22%2C%22title%22%3A%22Pressure-driven%20Phase%20Transition%20in%20CaFeAsF%20at%2040%20and%20300%20K%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S%20K%22%2C%22lastName%22%3A%22Mishra%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R%22%2C%22lastName%22%3A%22Mittal%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S%20L%22%2C%22lastName%22%3A%22Chaplot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S%20V%22%2C%22lastName%22%3A%22Ovsyannikov%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D%20M%22%2C%22lastName%22%3A%22Trots%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L%22%2C%22lastName%22%3A%22Dubrovinsky%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y%22%2C%22lastName%22%3A%22Su%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Th%22%2C%22lastName%22%3A%22Brueckel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H%22%2C%22lastName%22%3A%22Hosono%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G%22%2C%22lastName%22%3A%22Garbarino%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222012-07-30%22%2C%22proceedingsTitle%22%3A%22Journal%20of%20Physics%3A%20Conference%20Series%22%2C%22conferenceName%22%3A%2223rd%20International%20Conference%20on%20High%20Pressure%20Science%20and%20Technology%20%28AIRAPT-23%29%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1088%5C%2F1742-6596%5C%2F377%5C%2F1%5C%2F012034%22%2C%22ISBN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fiopscience.iop.org%5C%2F1742-6596%5C%2F377%5C%2F1%5C%2F012034%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-10-04T03%3A10%3A25Z%22%7D%7D%2C%7B%22key%22%3A%22JFBW6QIH%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Matsuishi%20et%20al.%22%2C%22parsedDate%22%3A%222012-08-01%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EMatsuishi%2C%20S.%3B%20Nakamura%2C%20A.%3B%20Muraba%2C%20Y.%3B%20Hosono%2C%20H.%20Hydrogen%20Substitution%20Effect%20on%20the%20Superconductivity%20of%20LnNiAsO%20%28Ln%20%3D%20La%26%23x2013%3BNd%29.%20%3Ci%3ESupercond.%20Sci.%20Technol.%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E25%3C%5C%2Fi%3E%20%288%29%2C%20084017.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F0953-2048%5C%2F25%5C%2F8%5C%2F084017%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F0953-2048%5C%2F25%5C%2F8%5C%2F084017%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Hydrogen%20substitution%20effect%20on%20the%20superconductivity%20of%20LnNiAsO%20%28Ln%20%3D%20La%5Cu2013Nd%29%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Atsushi%22%2C%22lastName%22%3A%22Nakamura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshinori%22%2C%22lastName%22%3A%22Muraba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222012-08-01%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1088%5C%2F0953-2048%5C%2F25%5C%2F8%5C%2F084017%22%2C%22ISSN%22%3A%220953-2048%2C%201361-6668%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fiopscience.iop.org%5C%2F0953-2048%5C%2F25%5C%2F8%5C%2F084017%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222013-01-07T03%3A51%3A34Z%22%7D%7D%2C%7B%22key%22%3A%22VLDFAMME%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Funabiki%20et%20al.%22%2C%22parsedDate%22%3A%222012-09-01%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EFunabiki%2C%20F.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Elucidation%20of%20Codoping%20Effect%20in%20Cu2%2B-Containing%20Sodium%20Borate%20Glass.%20In%20%3Ci%3EJournal%20of%20Non-Crystalline%20Solids%3C%5C%2Fi%3E%3B%20Proceedings%20of%3B%20Nara%2C%202012%3B%20Vol.%20358%2C%20pp%202446%26%23x2013%3B2449.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jnoncrysol.2011.12.059%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jnoncrysol.2011.12.059%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22conferencePaper%22%2C%22title%22%3A%22Elucidation%20of%20codoping%20effect%20in%20Cu2%2B-containing%20sodium%20borate%20glass%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fuji%22%2C%22lastName%22%3A%22Funabiki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Satoru%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22Sodium%20borate%20glass%20containing%20Cu2%2B%20ions%20was%20codoped%20with%20a%20variety%20of%20metallic%20or%20nonmetallic%20cations%2C%20and%20the%20ligand%20field%20around%20Cu2%2B%20was%20examined%20by%20optical%20absorption%20and%20electron%20paramagnetic%20resonance%20spectroscopies.%20Glasses%20of%200.1CuO%5Cu00b75Na2O%5Cu00b795B2O3%2B2MOx%20were%20prepared%20by%20a%20melt%20quenching%20method.%20The%20observed%20strengthening%20of%20the%20ligand%20field%20%28defined%20as%20the%20blueshift%20of%20Cu2%2B-optical%20absorption%20band%29%20was%20in%20the%20order%3A%20P5%2B%3CSi4%2B%3DLa3%2B%20%28No%20effect%29%3CAl3%2B%3DTi4%2B%3DGa3%2B%3DNb5%2B%3CY3%2B%3CZr4%2B%3CHf4%2B.%20We%20found%20that%20metallic%20cations%20having%20high%20field%20strength%20%28Z%5C%2Fr%29%20and%20high%20ionicity%2C%20Zr4%2B%20and%20Hf4%2B%2C%20induce%20a%20large%20change%20in%20the%20local%20structure%20around%20Cu2%2B%2C%20while%20cations%20with%20high%20Z%5C%2Fr%20but%20low%20ionicity%20have%20almost%20no%20effect%20on%20the%20ligand%20field.%22%2C%22date%22%3A%222012-09-01%22%2C%22proceedingsTitle%22%3A%22Journal%20of%20Non-Crystalline%20Solids%22%2C%22conferenceName%22%3A%22The%2024th%20International%20Conference%20on%20Amorphous%20and%20Nanocrystalline%20Semiconductors%20%28ICANS%2024%29%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jnoncrysol.2011.12.059%22%2C%22ISBN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS0022309311007691%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-10-04T03%3A32%3A19Z%22%7D%7D%2C%7B%22key%22%3A%22K5ETIVN2%22%2C%22library%22%3A%7B%22id%22%3A244926%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fujitsu%20et%20al.%22%2C%22parsedDate%22%3A%222012-11-01%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%281%29%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EFujitsu%2C%20S.%3B%20Matsuishi%2C%20S.%3B%20Hosono%2C%20H.%20Iron%20Based%20Superconductors%20Processing%20and%20Properties.%20%3Ci%3EInternational%20Materials%20Reviews%3C%5C%2Fi%3E%20%3Cb%3E2012%3C%5C%2Fb%3E%2C%20%3Ci%3E57%3C%5C%2Fi%3E%20%286%29%2C%20311%26%23x2013%3B327.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1179%5C%2F1743280412Y.0000000004%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1179%5C%2F1743280412Y.0000000004%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Iron%20based%20superconductors%20processing%20and%20properties%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S%22%2C%22lastName%22%3A%22Fujitsu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S%22%2C%22lastName%22%3A%22Matsuishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H%22%2C%22lastName%22%3A%22Hosono%22%7D%5D%2C%22abstractNote%22%3A%22The%20discovery%20of%20iron%20based%20superconductors%20in%20early%202008%20stimulated%20the%20interest%20of%20researchers%20around%20the%20globe%2C%20including%20physicists%2C%20chemists%20and%20materials%20scientists%20leading%20to%20publication%20of%20more%20than%204000%20papers%20on%20this%20superconductor%20since%20then.%20Since%20the%20major%20player%20in%20the%20superconductor%20is%20iron%2C%20which%20had%20long%20been%20believed%20to%20be%20the%20worst%20element%20suited%20for%20the%20superconductivity%2C%20this%20discovery%20gave%20tremendous%20impact%20on%20the%20superconductivity%20research.%20Furthermore%2C%20this%20material%20has%20favourable%20characteristics%20for%20practical%20applications%20such%20as%20a%20relatively%20high%20critical%20temperature%2C%20high%20upper%20critical%20field%20and%20high%20critical%20current%20density%20with%20low%20anisotropy.%20In%20the%20last%203%20years%2C%20many%20derived%20superconducting%20materials%20have%20been%20discovered%20and%20several%20theoretical%20models%20for%20the%20mechanism%20of%20superconductivity%20have%20been%20proposed.%20In%20this%20review%2C%20the%20research%20topics%20on%20iron%20based%20superconductors%20are%20summarised%20from%20the%20viewpoint%20of%20materials%20science.%22%2C%22date%22%3A%222012-11-01T00%3A00%3A00%5C%2F%5C%2F%5C%2F%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1179%5C%2F1743280412Y.0000000004%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22P5622579%22%5D%2C%22dateModified%22%3A%222022-10-04T00%3A45%3A36Z%22%7D%7D%5D%7D
(1)
Kitano, M.; Inoue, Y.; Yamazaki, Y.; Hayashi, F.; Kanbara, S.; Matsuishi, S.; Yokoyama, T.; Kim, S.-W.; Hara, M.; Hosono, H. Ammonia Synthesis Using a Stable Electride as an Electron Donor and Reversible Hydrogen Store. Nat Chem 2012, 4 (11), 934–940. https://doi.org/10.1038/nchem.1476.
(1)
Liu, X.; Matsuishi, S.; Fujitsu, S.; Hosono, H. MgFeGe as an Isoelectronic and Isostructural Analog of the Superconductor LiFeAs. Phys. Rev. B 2012, 85 (10), 104403. https://doi.org/10.1103/PhysRevB.85.104403.
(1)
Guo, J.; Qi, Y.; Matsuishi, S.; Hosono, H. Tc Maximum in Solid Solution of Pyrite IrSe2–RhSe2 Induced by Destabilization of Anion Dimers. J. Am. Chem. Soc. 2012, 134 (49), 20001–20004. https://doi.org/10.1021/ja309724w.
(1)
Daicho, H.; Iwasaki, T.; Enomoto, K.; Sasaki, Y.; Maeno, Y.; Shinomiya, Y.; Aoyagi, S.; Nishibori, E.; Sakata, M.; Sawa, H.; Matsuishi, S.; Hosono, H. A Novel Phosphor for Glareless White Light-Emitting Diodes. Nat Commun 2012, 3, 1132. https://doi.org/10.1038/ncomms2138.
(1)
Liu, X.; Matsuishi, S.; Fujitsu, S.; Ishigaki, T.; Kamiyama, T.; Hosono, H. Layered Hydride CaNiGeH with a ZrCuSiAs-Type Structure: Crystal Structure, Chemical Bonding, and Magnetism Induced by Mn Doping. J. Am. Chem. Soc. 2012, 134 (28), 11687–11694. https://doi.org/10.1021/ja3026104.
(1)
Matsuishi, S.; Hanna, T.; Muraba, Y.; Kim, S. W.; Kim, J. E.; Takata, M.; Shamoto, S.; Smith, R. I.; Hosono, H. Structural Analysis and Superconductivity of CeFeAsO1-xHx. Phys. Rev. B 2012, 85 (1), 014514. https://doi.org/10.1103/PhysRevB.85.014514.
(1)
Qi, Y.; Matsuishi, S.; Guo, J.; Mizoguchi, H.; Hosono, H. Superconductivity in Defective Pyrite-Type Iridium Chalcogenides IrxCh2 (Ch=Se and Te). Phys. Rev. Lett. 2012, 109 (21), 217002. https://doi.org/10.1103/PhysRevLett.109.217002.
(1)
Tsutsumi, S.; Fujiwara, N.; Matsuishi, S.; Hosono, H. Spin Density Wave and Superconductivity in CaFe1-xCoxAsF Studied by Nuclear Magnetic Resonance. Phys. Rev. B 2012, 86 (6), 060515. https://doi.org/10.1103/PhysRevB.86.060515.
(1)
Takahashi, H.; Tomita, T.; Soeda, H.; Ebata, M.; Okuma, K.; Hanna, T.; Muraba, Y.; Matsuishi, S.; Hosono, H. High-Pressure Studies for Hydrogen Substituted CaFeAsF1-xHx and SmFeAsO1-xHx. J Supercond Nov Magn 2012, 25 (5), 1293–1296. https://doi.org/10.1007/s10948-012-1597-y.
(1)
Mishra, S. K.; Mittal, R.; Sastry, P. U.; Chaplot, S. L.; Matsuishi, S.; Hosono, H. High Temperature Structural Phase Transitions in FeAs Based Compounds. In AIP Conference Proceedings; American Institute of Physics, 2012; Vol. 1447, pp 95–96. https://doi.org/10.1063/1.4709898.
(1)
Ryu, G.; Kim, S. W.; Mizoguchi, H.; Matsuishi, S.; Hosono, H. Superconductivity in a PbFCl-Type Pnictide: NbSiAs. EPL (Europhysics Letters) 2012, 99 (2), 27002. https://doi.org/10.1209/0295-5075/99/27002.
(1)
Iimura, S.; Matuishi, S.; Sato, H.; Hanna, T.; Muraba, Y.; Kim, S. W.; Kim, J. E.; Takata, M.; Hosono, H. Two-Dome Structure in Electron-Doped Iron Arsenide Superconductors. Nature Communications 2012, 3, 943. https://doi.org/10.1038/ncomms1913.
(1)
Mishra, S. K.; Mittal, R.; Chaplot, S. L.; Ovsyannikov, S. V.; Trots, D. M.; Dubrovinsky, L.; Su, Y.; Brueckel, T.; Matsuishi, S.; Hosono, H.; Garbarino, G. Pressure-Driven Phase Transition in CaFeAsF at 40 and 300 K. In Journal of Physics: Conference Series; Mumbai, 2012; Vol. 377, p 012034. https://doi.org/10.1088/1742-6596/377/1/012034.
(1)
Matsuishi, S.; Nakamura, A.; Muraba, Y.; Hosono, H. Hydrogen Substitution Effect on the Superconductivity of LnNiAsO (Ln = La–Nd). Supercond. Sci. Technol. 2012, 25 (8), 084017. https://doi.org/10.1088/0953-2048/25/8/084017.
(1)
Funabiki, F.; Matsuishi, S.; Hosono, H. Elucidation of Codoping Effect in Cu2+-Containing Sodium Borate Glass. In Journal of Non-Crystalline Solids; Proceedings of; Nara, 2012; Vol. 358, pp 2446–2449. https://doi.org/10.1016/j.jnoncrysol.2011.12.059.
(1)
Fujitsu, S.; Matsuishi, S.; Hosono, H. Iron Based Superconductors Processing and Properties. International Materials Reviews 2012, 57 (6), 311–327. https://doi.org/10.1179/1743280412Y.0000000004.